• Advances in concrete construction
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• v.13 no.1
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• pp.71-81
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• 2022

Aluminosilicate materials as precursors are heterogenous in nature, consisting of inert and partially reactive portion, and have varying proportions depending upon source materials. It is essential to assess the reactivity of precursor prior to synthesize geopolymers. Moreover, reactivity may act as decisive factor for setting molar concentration of NaOH, curing temperature and setting proportion of different precursors. In this experimental work, the reactivities of two precursors, low calcium (fly ash (FA)) and high calcium (ground granulated blast furnace slag (GGBS)), were assessed through the dissolution of aluminosilicate at (i) three molar concentrations (8, 12, and 16 M) of NaOH solution, (ii) 6 to 24 h dissolution time, and (iii) 20-100℃. Based on paratermeters influencing the reactivity, different proportions of ternary binders (two precursors and ordinary cement) were activated by the combined NaOH and Na2SiO3 solutions with two alkaline activators to precursor ratios, to synthesize the geopolymer. Reactivity results revealed that GGBS was 20-30% more reactive than FA at 20℃, at all three molar concentrations, but its reactivity decreased by 32-46% with increasing temperature due to the high calcium content. Setting time of geopolymer paste was reduced by adding GGBS due to its fast reactivity. Both GGBS and cement promoted the formation of all types of gels (i.e., C-S-H, C-A-S-H, and N-A-S-H). As a result, it was found that a specified mixing proportion could be used to improve the compressive strength over 30 MPa at both the ambient and hot curing conditions.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.1
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• pp.48-55
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• 2022

This study uses the recovered water as mixing water and artificial lightweight aggregate pre-wetting water as part of a study to increase the recycling rate and reduce greenhouse gas of the ready-mixed concrete recovered during the concrete transport process, and cement fine powder of blast furnace slag(BFS) and fly ash(FA). The engineering characteristics of the three-component lightweight aggregate mortar used as a substitute were reviewed. For this purpose, the flow, dry unit mass, compressive strength, drying shrinkage, neutralization depth, and chloride ion penetration resistance of the three-component lightweight aggregate mortar were measured. When used together with the formulation, when 15 % of BFS and 5 % of FA were used, it was found to be positive in improving the compressive strength and durability of the mortar.

• Advances in concrete construction
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• v.16 no.3
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• pp.155-167
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• 2023

The penetrated chloride in concrete has different behavior with mix proportions and local exposure conditions, even in the same environments, so that it is very important to quantify surface chloride contents for durability design. As well known, the surface chloride content which is a key parameter like external loading in structural safety design increases with exposure period. In this study, concrete samples containing OPC (Ordinary Portland Cement), GGBFS (Ground Granulated Blast Furnace Slag), and FA (Fly Ash) had been exposed to submerged, tidal, and splash area for 5 years, then the surface chloride contents changing with exposure period were evaluated. The surface chloride contents were obtained from the chloride profile based on the Fick's 2nd Law, and the regression analysis for them was performed with exponential and square root function. After exposure period of 5 years in submerged and tidal area conditions, the surface chloride content of OPC concrete increased to 6.4 kg/m³ - 7.3 kg/m³, and the surface chloride content of GGBFS concrete was evaluated as 7.3 kg/m³ - 11.5 kg/m³. In the higher replacement ratio of GGBFS, the higher surface chloride contents were evaluated. The surface chloride content in FA concrete showed a range of 6.7 kg/m³ to 9.9 kg/m³, which was the intermediate level of OPC and GGBFS concrete. In the case of splash area, the surface chloride contents in all specimens were from 0.59 kg/m³ to 0.75 kg/m³, which was the lowest of all exposure conditions. Experimental constants available for durability design of chloride ingress were derived through regression analysis over exposure period. In the concrete with GGBFS replacement ratio of 50%, the increase rate of surface chloride contents decreased rapidly as the water to binder ratio increased.

• Journal of the Korea institute for structural maintenance and inspection
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• v.11 no.6
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• pp.143-151
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• 2007

This study presents the experimental results of frost durability including resistance to freezing-thawing and surface scaling of concrete. Mixing design was proportioned with the various water-binder ratio between 0.37 and 0.47 and three different binder compositions corresponding to Type I cement without any supplementary cementitious materials(OPC), Type II cement with 50% blast-furnace slag replacement(BFS50), and ternary cement with Type III cement, 15% fly ash, and 35% slag replacement (BFS35%+FA15%). Test results showed that the mixing design with BFS50% and BFS35%+FA15% exhibited higher durability factor than that made with OPC only. Finally, the use of blend cement containing slag can be used effectively in terms of frost durability of the concrete exposed to severe condition under coastal environment like as flying salt, sea water spray, etc.

• Corrosion Science and Technology
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• v.6 no.4
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• pp.177-185
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• 2007

The purpose of this study is to evaluate freezing-thawing and surface scaling resistance in order to examine the frost durability of concrete in a chloride-inherent environment. The mixing design for this study is as follows: 3 water binder ratios of 0.37, 0.42, and 0.47; 2-ingredient type concrete (50% OPC concrete and 50% ground granulated blast-furnace slag), and 3-ingredient type concrete (50% OPC concrete, 15% fly ash, and 35% ground granulated blast-furnace slag). As found in this study, the decrease of durability was much more noticeable in combined deterioration through both salt damage and frost damage than in a single deterioration through either ofthese; when using blast-furnace slag in freezing-thawing seawater, the frost durability and surface deterioration resistance was evaluated as higher than when using OPC concrete. BF 50% concrete, especially, rather than BFS35%+FA15%, had a notable effect on resistance to chloride penetration and freezing/expansion. It has been confirmed that surface deterioration can be evaluated through a quantitative analysis of scaling, calculated from concrete's underwater weight and surface-dry weight as affected by the freezing-thawing of seawater.

• Computers and Concrete
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• v.19 no.6
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• pp.717-724
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• 2017

In this paper, four formulas are proposed via gene expression programming (GEP)-based models and regression analysis (RA) to predict the flexural strength ($f_s$) values of mortars containing different mineral admixtures that are ground granulated blast-furnace slag (GGBFS), silica fume (SF) and fly ash (FA) at different ages. Three formulas obtained from the GEP-I, GEP-II and GEP-III models are constituted to predict the $f_s$ values from the age of specimen, water-binder ratio and compressive strength. Besides, one formula obtained from the RA is constituted to predict the $f_s$ values from the compressive strength. To achieve these formulas in the GEP and RA models, 972 data of the experimental studies presented with mortar mixtures were gathered from the literatures. 734 data of the experimental studies are divided without pre-planned for these formulas achieved from the training and testing sets of GEP and RA models. Beside, these formulas are validated with 238 data of experimental studies un-employed in training and testing sets. The $f_s$ results obtained from the training, testing and validation sets of these formulas are compared with the results obtained from the experimental studies and the formulas given in the literature for concrete. These comparisons show that the results of the formulas obtained from the GEP and RA models appear to well compatible with the experimental results and find to be very credible according to the results of other formulas.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2014.05a
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• pp.146-147
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• 2014

In this study, as the resistance of the carbonation for high volume admixture incorporating concrete, coating effect of using refined cooking oil in the surface of high volume admixture incorporating concrete has been tested. The following results could be made as the conclusion. For the fresh concrete, the slump and air content has been identified as satisfying the target range. For the hardened concrete, comparing with specimen of Plain, specimen with coating showed better long age compressive strength. For the carbonation speed, the specimen of FA30 showed highest speed and the specimen of BS60 showed higher speed than specimen of Plain. For all the specimens coated with RCO, as the decrease of capillary pores inside the concrete, the carbonation speed has been obviously decreased and with even better effect than using PEP coating. It could be identified that specimens with coating by RCO showed good effect on refrain the speed of carbonation.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2005.11a
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• pp.57-61
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• 2005

Cement paste is originally the basic material and crucial factor consisting concrete. This study investigates the relationship between flow apparatuses, which are ring flow(R-F), flow cone(F-C) and mini slump(M-S), in order to estimate the fluidity of cement Paste. For quantitatively evaluating the measured data this study also investigated the calibration of the rheology consistent, such as yield value and plastic viscosity, of cement paste using viscometer For this purpose the present work discussed the influence of 3 type of ordinary portland cement with different companies, affecting the fluidity of cement paste. and it also demonstrated the influence of the various kinds of mineral admixtures, such as fly ash(FA), blast furnace slag(BS) and silica fume(SF) and that of incorporating ratio. The author concluded that using R-F apparatus is the most effective flow test method of cement paste and it is exactly proportional to other apparatus' rheological properties.

• Corrosion Science and Technology
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• v.15 no.1
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• pp.18-27
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• 2016

In this study, the accelerated corrosion test by combined deteriorating action of salt damage and freeze-thaw was investigated. freeze-thaw cycle is one method for corrosion testing; corrosion initiation time was measured in four types of concrete samples, i.e., two samples mixed with fly ash (FA) and blast furnace slag (BS), and the other two samples having two water/cement ratio (W/C = 0.6, 0.35) without admixture (OPC60 and OPC35). The corrosion of rebar embedded in concrete occurred most quickly at the $30^{th}$ freeze-thaw cycle. Moreover, a corrosion monitoring method with a half-cell potential measurement and relative dynamic elastic modulus derived from resonant frequency measures was conducted simultaneously. The results indicated that the corrosion of rebar occurred when the relative dynamic elastic modulus was less than 60%. Therefore, dynamic elastic modulus can be used to detect corrosion of steel bar. The results of the accelerated corrosion test exhibited significant difference according to corrosion periods combined with each test condition. Consequently, the OPC60 showed the lowest corrosion resistance among the samples.

• Computers and Concrete
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• v.19 no.2
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• pp.121-126
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• 2017

This paper presents the effect of aggregate type on high temperature resistance of self-compacting mortars (SCM) produced with normal and lightweight aggregates like expanded perlite and pumice. Silica fume (SF) and fly ash (FA) were used as mineral additives. Totally 13 different mixtures were designed according to the aggregate rates. Mini slump flow, mini V-funnel and viscometer tests were carried out on the fresh mortar. On the other hand, bulk density, porosity, water absorption and high temperature tests were made on the hardened SCM. After being heated to temperatures of 300, 600 and $900^{\circ}C$, respectively, the tensile strength in bending and compressive strength of mortars determined. As a result of the experiments, the increase in the use of lightweight aggregate increased total water absorption and porosity of mortars. It is observed that, the increment in the usage of lightweight aggregate decreased tensile strength in bending and compressive strengths of mortar specimens exposed to high temperatures but the usage of up to 10% expanded perlite in mortar increased the compressive strength of specimens exposed to $300^{\circ}C$.