• Title/Summary/Keyword: F2C

Search Result 6,888, Processing Time 0.037 seconds

$C_{x}F_{y}$ Polymer Film Deposition in rf and dc $C_{7}F_{16}$ Vapor Plasmas

  • Sakai, Y.;Akazawa, M.;Sakai, Yosuke;Sugawara, H.;Tabata, M.;Lungu, C.P.;Lungu, A.M.
    • Transactions on Electrical and Electronic Materials
    • /
    • v.2 no.1
    • /
    • pp.1-6
    • /
    • 2001
  • $C_{x}F_{y}$ polymer film was deposited in rf and dc Fluorinert vapor ($C_{7}F_{16}$) plasmas. In the plasma phase, the spatial distribution of optical emission spectra and the temporal concentration of decomposed species were monitored, and kinetics of the $C_{7}F_{16}$ decomposition process was discussed. Deposition of $C_{x}F_{y}$ film has been tried on substrates of stainless steel, glass, molybdenum and silicon wafers at room temperature in the vapor pressures of 40 and 100 Pa. The films deposited in the rf plasma showed excellent electrical properties as an insulator for multi-layered interconnection of deep-submicron LSI, i.e. the low dielectric constant ∼2.0, the dielectric strength ∼2 MV/cm and the high deposition rate ∼100nm/min at 100W input power.

  • PDF

ON AN ADDITIVE FUNCTIONAL INEQUALITY IN NORMED MODULES OVER A $C^*$-ALGEBRA

  • An, Jong-Su
    • The Pure and Applied Mathematics
    • /
    • v.15 no.4
    • /
    • pp.393-400
    • /
    • 2008
  • In this paper, we investigate the following additive functional inequality (0.1) ||f(x)+f(y)+f(z)+f(w)||${\leq}$||f(x+y)+f(z+w)|| in normed modules over a $C^*$-algebra. This is applied to understand homomor-phisms in $C^*$-algebra. Moreover, we prove the generalized Hyers-Ulam stability of the functional inequality (0.2) ||f(x)+f(y)+f(z)f(w)||${\leq}$||f(x+y+z+w)||+${\theta}||x||^p||y||^p||z||^p||w||^p$ in real Banach spaces, where ${\theta}$, p are positive real numbers with $4p{\neq}1$.

  • PDF

Comparision of Regulatory Action of cAMP and cGMP on the Activation of Neutrophil Responses

  • Han, Chang-Hwang;Yoon, Young-Chul;Shin, Yong-Kyoo;Han, Eun-Sook;Lee, Chung-Soo
    • The Korean Journal of Physiology and Pharmacology
    • /
    • v.1 no.1
    • /
    • pp.97-105
    • /
    • 1997
  • The regulatory role of cyclic nucleotides in the expression of neutrophil responses has been examined. fMLP-stimulated superoxide production in neutrophils was inhibited by dibutyryl adenosine 3',5'-cyclic monophosphate (DBcAMP), histamine, adenosine + theophylline, cAMP elevating agents, and 8-bromoguanosine 3' ,5' -cyclic monophosphate (8-BrcGMP) and sodium nitroprusside, cGMP elevating agents. Staurosporine, a protein kinase C inhibitor, genistein, a protein tyrosine kinase inhibitor and chlorpromazine, a calmodulin inhibitor, inhibited superoxide production by fMLP, but they did not further affect the action of DBcAMP on the stimulatory action of fMLP. DBcAMP, histamine, adenosine+theophylline and genistein inhibited myeloperoxidease release evoked by fMLP, whereas BrcGMP, sodium nitroprusside and staurosporine did not affect it. The elevation of $[Ca^{2+}]_i$ evoked by fMLP was inhibited by genistein and chlorpromazine but was not affected by staurosporine. DBcAMP exerted little effect on the initial peak in $[Ca^{2+}]_i$ response to fMLP but effectively inhibited the sustained rise. On the other hand, BrcGMP significantly inhibited both phases. fMLP-induced $Mn^{2+}$ influx was inhibited by either DBcAMP or BrcGMP. These results suggest that fMLP-stimulated neutrophil responses may be regulated by cAMP more than cGMP. cAMP and cGMP appear not affect stimulated responses by direct protein kinase C activation. Their regulatory action on the stimulated neutrophil responses may be not influenced by other activation processes.

  • PDF

Synthesis of Fe­Garnet for tile Immobilization of High Level Radioactive Waste (고준위 방사성폐기물의 고정화를 위한 Fe­석류석 합성 연구)

  • ;;;Yudintsev, S. V.
    • Journal of the Mineralogical Society of Korea
    • /
    • v.16 no.4
    • /
    • pp.307-320
    • /
    • 2003
  • Garnet has been considered as a possible matrix for the immobilization of radioactive actinides. It is expected that Fe­based garnet be able to have the high substitution ability of actinide elements because ionic radius of Fe in tetrahedral site is larger than that of Si of Si­based garnet. Accordingly, we synthesized Fe­garnet with the batch composition of $Ca_{2,5}$C $e_{0.5}$Z $r_2$F $e_3$ $O_{12}$ and $Ca_2$CeZrFeF $e_3$ $O_{12}$ and studied their phase relations and properties. Mixed samples were fabricated in pellet forms under the pressure of 400 kg/$\textrm{cm}^2$ and were sintered in the temperature range of 1100∼140$0^{\circ}C$ in atmospheric conditions. Phase identification and chemical composition of synthesized samples were analyzed by XRD and SEM/EDS. In results, where the compounds were sintered at 130$0^{\circ}C$, we optimally obtained Fe­garnets as the main phase, even though some minor phases like perovskite were included. The compositions of Fe­garnets synthesized from the batch compositions of $Ca_{2,5}$C $e_{0.5}$Z $r_2$F $e_3$ $O_{12}$ and $Ca_2$CeZrFeF $e_3$ $O_{12}$, are $Ca_{2.5­3.2}$C $e_{0.3­0.7}$Z $r_{1.8­2.8}$F $e_{1.9­3.2}$ $O_{12}$ and $Ca_{2.2­2.5}$C $e_{0.8­1.0}$Z $r_{1.3­1.6}$ F $e_{0.4­.07}$ F $e_{3­3.2}$ $O_{12}$, respectively. Ca contents were exceeded and Ce contents were exceeded or depleted in 8­coodinated site, comparing to the initial batch composition. These results were caused by the compensation of the difference of ionic radius between Ca and Ce.

Synthesis of Zeolite Using Discharged Fly Ash in an Industrial Complex in Ulsan (울산지역 공단에서 발생되는 비산재를 이용한 제올라이트 합성)

  • Lee, Chang-Han;Park, Jong-Won
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.33 no.5
    • /
    • pp.301-306
    • /
    • 2011
  • In this study, zeolite was synthesized by hydrothermal, fusion, and fusion/hydrothermal methods with fly ash, coal fly ash, and a waste catalyst discharged from thermal power plants and incinerator in Ulsan area. Coal fly ashes (CFAs) and a waste catalyst containing amounts of $SiO_2$ and $Al_2O_3$ ranging from 60.29 to 89.62 wt%. CFAs were mainly composed of quartz and mullite which were assayed by a XRD pattern. Zeolite could be synthesized by CFAs and the waste catalyst when all methods were used. Na-A zeolite (Z-C1, Z-C2, and Z-W5) are mainly synthesized by the fusion method from CFAs and the waste catalyst. Z-C1 and Z-C2 formed by-products, calcite peaks, which is caused by the content of CaO in CFAs and the addition of $Na_2CO_3$ for a synthetic process.

Molecular and Crystal Structure of' Metalaxyl, $C_{15}H_{21}NO_4$ (Metalaxyl, $C_{15}H_{21}NO_4$의 분자 및 결정구조)

  • Keun Il Park;Young Kie Kim;Sung Il Cho;Man Hyung Yoo
    • Korean Journal of Crystallography
    • /
    • v.13 no.3_4
    • /
    • pp.148-151
    • /
    • 2002
  • The molecular and crystal structure of metalaxyl C/sub15/H/sub21/NO₄, was determined by single crystal x-ray diffraction study. Crystallographic data for, title compound P2₁/c, a=7.849(4) Å, b=13.081(5) Å, c=15.100(3) Å, β=101.8(2)°, V= 1517.6(3) ų, Z=4. The molecular. Structure model was solved by direct method and refined by full-matrix least- squares. The final reliable factor, R, is 0.067 for 1694 independent reflections (F/sub o//sup 2/>4σ(F/sub o//sup 2/)). The molecular structure of title compound shows an intramolecular hydrogen bond: Cl2-Hl2A…O1.

Characterization of PVdF/Laponite Reinforced Composite Membranes for PEMFC Surpport (PEMFC 지지체용 PVdF/Laponite 강화 복합막의 특성평가)

  • Oh, Seul-Gi;Hwang, Hae-Young;Kim, Hyoung-Juhn;Nam, Sang-Yong
    • Membrane Journal
    • /
    • v.20 no.2
    • /
    • pp.159-168
    • /
    • 2010
  • In this study, high porous PVdF flat sheet membranes were prepared to obtain reinforced membrane support for polymer electrolyte membrane fuel cell. Nano-size laponite was randomly dispersed in the membranes to improve mechanical property which lowered by the high porosity. The morphology and porosity of prepared PVdF/Laponite composite membranes were examined using the SEM analysis and the weight method and all membranes showed over 60% porosity. The membrane thermal stability depending on the laponite contents in the composite membranes was evaluated by membrane heat shrinkage at $105^{\circ}C$ and $135^{\circ}C$. MD and TD heat shrinkage of the PVdF composite membrane containing 5 wt% laponite was 2~3% and 2~3.5% at $135^{\circ}C$, respectively. The mechanical strength was enhanced after incorporating laponite particles and 30% increase in the modulus compared to pure PVdF membrane was obtained.

Analysis of Spin Exchange Interactions in (C2N2H10)[Fe(HPO3)F3] on the Basis of Electronic Structure Calculations

  • Koo, Hyun-Joo
    • Bulletin of the Korean Chemical Society
    • /
    • v.32 no.2
    • /
    • pp.467-471
    • /
    • 2011
  • Spin exchange interactions of $(C_2N_2H_{10})[Fe(HPO_3)F_3]$ were examined by performing a spin dimer analysis based on extended Huckel tight binding method and a mapping analysis based on first principles density functional theory. Spin exchange interactions occur through the super-superexchange paths $J_1$ and $J_2$ in $(C_2N_2H_{10})[Fe(HPO_3)F_3]$. In the super-superexchange path $J_2$ magnetic orbital interactions between eg-block levels are much stronger than those from $t_{2g}$-block levels. Both electronic structure calculations show that the spin exchange interaction through the super-superexchange path $J_2$ is much stronger than that of $J_1$.

Microstructure and Strength Property of Liquid Phase Sintered $SiC_f$/SiC Composites (액상소결 $SiC_f$/SiC 복합재료의 미세조직 및 강도특성)

  • Lee, Moon-Hee;Cho, Kyung-Seo;Lee, Sang-Pill;Lee, Jin-Kyung
    • Proceedings of the KSME Conference
    • /
    • 2008.11a
    • /
    • pp.234-238
    • /
    • 2008
  • The efficiency of fiber reinforced CMC(ceramic matrix composite) on the SiC materials have been investigated, in conjunction with the fabrication process by liquid phase sintering and the characterization. LPS-$SiC_f$/SiC composites was studied with the detailed analysis such as the microstructure, sintered density, flexural strength and fracture behavior. The applicability of carbon interfacial layer has been also investigated in the LPS process. Submicron SiC powder with the constant total amount and composition ratio of $Al_2O_3,\;Y_2O_3$ as sintering additives was used in order to promote the performance of the SiC matrix material. LPS-$SiC_f$/SiC composites were fabricated with hot press under the sintering temperature and applied pressure of $1820^{\circ}C$ and 20MPa for 1hr. The typical property of monolithic LPS-SiC materials was compared with LPS-$SiC_f$/SiC composites.

  • PDF

PULSATIONAL CHARACTERISTICS OF $\delta$ SCUTI VARIABLE HR1170

  • Kim, Seoung-Li;Lee, See-Woo
    • Journal of The Korean Astronomical Society
    • /
    • v.23 no.1
    • /
    • pp.1-13
    • /
    • 1990
  • New uvby photoelectric photometry was carried out for a $\delta$ Scuti variable, HR1170. By applying the Fourier method and the linear least square method, three frequencies were derived: $f_1=10.06134c/d$ ($P_1=0.^d0994$). $f_2=11.91754c/d$ ($P_2=0.^d0839$). $f_3=18.96776c/d$ ($P_3=0.^d0527$). From the observed pulsational constants and from the phase difference and amplitude ratios for color(b-y) and magnitude y. three different pulsation modes (n, l) of $f_1(0,0)$, $f_2(1,2)$, $f_3(3,2)$ are deduced, indicating the existence of nonradial mode in HR1170. Some physical parameters indicate that HR1170 is evolving at the stage of H-shell burning.

  • PDF