• Title/Summary/Keyword: F0 Range

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Synthesis and Luminescence Properties of Tb3+-Doped K2BaW2O8 Phosphors (Tb3+ 이온이 첨가된 K2BaW2O8 형광체의 합성 및 형광특성)

  • Jang, Kyoung-Hyuk;Koo, Jae-Heung;Seo, Hyo-Jin
    • Korean Journal of Materials Research
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    • v.22 no.9
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    • pp.489-493
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    • 2012
  • Green phosphors $K_2BaW_2O_8:Tb^{3+}$(1.0 mol%) were synthesized by solid state reaction method. Differential thermal analysis was applied to trace the reaction processes. Three endothermic values of 95, 706, and $1055^{\circ}C$ correspond to the loss of absorbed water, the release of carbon dioxide, and the beginning of the melting point, respectively. The phase purity of the powders was examined using powder X-ray diffraction(XRD). Two strong excitation bands in the wavelength region of 200-310 nm were found to be due to the ${WO_4}^{2-}$ exciton transition and the 4f-5d transition of $Tb^{3+}$ in $K_2BaW_2O_8$. The excitation spectrum presents several lines in the range of 310-380 nm; these are assigned to the 4f-4f transitions of the $Tb^{3+}$ ion. The strong emission line at around 550 nm, due to the $^5D_4{\rightarrow}^7F_5$ transition, is observed together with weak lines of the $^5D_4{\rightarrow}^7F_J$(J = 3, 4, and 6) transitions. A broad emission band peaking at 530 nm is observed at 10 K, while it disappears at room temperature. The decay times of $Tb^{3+}$ $^5D_4{\rightarrow}^7F_5$ emission are estimated to be 4.8 and 1.4 ms, respectively, at 10 and 295 K; those of the ${WO_4}^{2-}$ exciton emissions are 22 and 0.92 ${\mu}s$ at 10 and 200 K, respectively.

Quantitation of fructo- and inulo-oligosaccharides by high performance liquid chromatography (High performance liquid chromatography에 의한 fructo 및 inulo올리고당의 정량)

  • Kang, Su-Il;Han, Jong-In;Kim, Kyoung-Youn;Oh, Sun-Jin;Kim, Su-Il
    • Applied Biological Chemistry
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    • v.36 no.4
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    • pp.310-314
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    • 1993
  • High performance liquid chromatographic method using a TSK-gel amide 80 column and isocratic elution with acetonitrile-water (63 :35 ;v/v) mixture was used for the separation and the quantitation of fructo (GF2-GF7)- and inulo-oligosaccharides (F2-F4). Retention time of each standard carbohydrate was highly reproducible. Standardization curves obtained by plotting the peak areas against the amounts of each carbohydrate showed very high coefficient of determination$({\ge}0.9884)$ and similar slopes, and a wide range of y-intercepts. Our results suggest the use of each Pure oligosaccharide for its own standardization curve instead of using a certain carbohydrate as an internal standard.

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Genetic Relationship between Seed size and Leaf Size in 66 $F_2$ Populations Derived from Mating of 12 Soybean Strains (대두 12 모본의 half diallel cross로부터 생성된 66 $F_2$ 분리집단에서의 종자크기와 잎 크기에 대한 관계)

  • 정종일
    • Journal of Life Science
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    • v.8 no.4
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    • pp.437-442
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    • 1998
  • Seed and leaf size is the important morphological traits considered by plant breeder and is the important yield components in soybean. The objective of this research was to know the relationship between seed size and leaf size in 66 $F_2$ populations derived from half diallel mating system with 12 soybean strains, representing distinct seed and leaf size. The range of seed size for 12 parents used was 6.7 to 43.8 g/100 seed. Leaf width leaf length ranged 5.7 to 8.6 cm and 9.4 to 12.9 cm, respectively. Leaf width was highly correlated with leaf length with an R square of 0.754 in the $F_2$ generation. The $F_2$ regression` coefficient indicated that leaves were, on average 1.4 times greater length than in width . Leaf size (width) was highly correlated (r.0.91) with seed size (g/100 seed) in the $F_2$ generation with an R square of 0.833. Our results indicate postive correlation within seed and leaf size is common in $F_2$ segregating populations derived from crossing with soybean. The strong liner relationship we observed between leaf size and seed size in $F_2$ segragating population is useful in that in that indirect selection for a secondary character may be superior to direct selection for the primary character.

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AN ELECTROCHEMICAL STUDY ON THE CORROSION BEHAVIOUR OF AMALGAMS IN THE SALINE SOLUTIONS WITH FLUORIDE COMPOUNDS (불소화합물을 첨가한 생리식염수에서 아말감의 부식거동에 관한 전기화학적 연구)

  • Yun, Chong-Hun;Kwon, Hyuk-Choon;Um, Chung-Moon
    • Restorative Dentistry and Endodontics
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    • v.22 no.1
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    • pp.396-412
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    • 1997
  • The purpose of this study is to observe the corrosion characteristics of five dental amalgams(CAULK FINE CUT, OPTALLOY II, DISPERSALLOY, TYTIN, and VALIANT) in the solutions with fluoride compound through the anodic polarization curve obtained by using a potentiostat. After each amalgam alloy and Hg being triturated, the triturated mass was inserted into the cylindrical metal mold, and condensed by hydraulic pressure(160 kg/$cm^2$). Each specimen was removed from the metal mold. Specimens were polished with the silicone carbide grinding paper 24 hours after condensation and stored at room temperature for 1 week. The anodic polarization curves were employed to compare the corrosion behaviours of the amalgams in 0.9 % saline solution and in the saline solutions with 2.2 ppm, 0.05 %, 2 % NaF, and 8 % $SnF_2$ at $37^{\circ}C$ with 3-electrode potentiostat. After the immersion of specimen in electrolyte for 30 minutes, the potential scan was begun. The potential scan range was -1500m V to + 800m V(vs. S.C.E.) in the working electrode and the scan rate was 50 mV/sec. The results were as follows, 1. The corrosion potential, the potential of anodic current peak, and transpassive potential in the saline solutions with NaF shifted to lower direction than those in normal saline solution, and the current density in the saline solutions with NaF was higher than that in normal saline solution. The differences were increased as the concentrations of NaF became higher. 2. The corrosion potential and transpassive potential in the saline solution with $SnF_2$ shifted to higher direction than those in normal saline solution, and the current density in the saline solution with $SnF_2$ was higher than that in normal saline solution after the corrosion potential. The anodic polarization curves in the saline solution with $SnF_2$ had no outstanding anodic current peak. 3. The corrosion potentials for high-copper amalgams were much higher than those for CAULK FINE CUT and OPTALLOY II in normal saline solution, but, as the concentrations of fluoride compound became higher, the differences in corrosion potentials between them were decreased. The corrosion potentials had the similarity in the saline solution with 2% NaF or 8% $SnF_2$. 4. The current density for TYTIN was the lowest among the others in normal saline solution and in the saline solution with 2.2 ppm or 0.05 % NaF. 5. There was no significant difference in current density between Pd-enriched VALIANT and other high-copper amalgams.

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Fabrication and Characteristics of Oxygen Gas Sensor using Fluoride Compaunds (불화물을 이용한 산소센서의 제조및 특성)

  • 이재현;홍영호;장동근;이병택;김태훈;이덕동
    • Proceedings of the Materials Research Society of Korea Conference
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    • 1993.11a
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    • pp.69-71
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    • 1993
  • Fluoride compound potentiometric cell oxygen sensors were fabricated for the measurement of oxygen pressure in the low temperature range (300。K-500。K). The disk type sensors consist of a reference Air(0$_2$):Ag, a solid electrolyte SrF$_2$, and a sensing metel Ag electrode. And the buried reference electrode type sensor have a NiO/Ni reference electrode. The open circuit emf of the cell showed high sensivity to oxygen gas (60mv) at the measuring temperature 20$0^{\circ}C$. Also, The buried reference electrode type sensor showed 30mv from 1% to 10% oxygen pressure range.

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Hematologic Changes by Experimental Administration of Prednisolone Acetate in Horse (Prednisolone acetate의 실험적 투여로 인한 말의 혈액학적 변화)

  • 정병현;김정환;이병한;김진영
    • Journal of Veterinary Clinics
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    • v.15 no.2
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    • pp.267-273
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    • 1998
  • The study was carried out to investigate the changes of total WBC, neutrophil, lymphocyte, monocite, eosinophil in the horses'blood of 3 groups which randomly assigned 3 heads to each group. In group A(daily therapy), each horse was iniected, intramuscularly, 100 mg of prednisolone acetate/day for 3 days, consecutively. In group B(alternate-day therapy), each horse was injected, 100 mg of prednisolone acetate/day 4 times on alternate days, intramuscularly. In control group, each horse was injected, intramuscularly, the equivalent volumes/day of saline solution fur 3 days, consecutively. The results were summarized as fellows: 1. Total WBC counts in group A rapidly increased until day 4th, which the counts reached the $maximum(13.10{\pm}0.13{\times}10^{3}/{\mu}l$)(p<0.05), and decreased into control group range until day loth. In group B rapidly increased until day 1st, and gradually increased until day 71% which the counts reached the maximum ($12f3{\pm} 0.20$)0<0.05), and decreased into control group range until day 16th. 2. Neutrophil counts in group A rapidly increased until day 4HL which the coun% reached the maxi um($10.85{\pm} 0.08$)0<0.05), and decreased into control group range until day loth. In group B rapidly increased until day 1st and slowly increased until day 7th, which the counts reached the maximum$(9.76{\pm}0.22)0<0.05)$, and decreased into control group range until day 16th. 3. Lymphocyte counts in group A and B rapidly decreased until day 4th, which the counts reached the minimum(2.14{\pm}0.12 and 2.09{\pm}0.20$, respectively) (p<0.05), and increased into control group range until day 10th. Group A and B, however, had no significant effects each other on Iymphocyte counts during the study. 4. Monocite and eosinophil counts in group A and B remained in the range of control group during the study. Eosinophil in group A and B slightly decreased on day 4th, significantly%<0.05), but we could not generally be reliable the result because of severe standard deviations. In conclusion, we fecund that group A had more rapidly increase and decrease than group B on hematologic counts of WBC, but group B had longer period than group A on the hematologic effects of WBC, and found not differences between daily therapy and alternate-day therapy.

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Abnormal Water Temperature Prediction Model Near the Korean Peninsula Using LSTM (LSTM을 이용한 한반도 근해 이상수온 예측모델)

  • Choi, Hey Min;Kim, Min-Kyu;Yang, Hyun
    • Korean Journal of Remote Sensing
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    • v.38 no.3
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    • pp.265-282
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    • 2022
  • Sea surface temperature (SST) is a factor that greatly influences ocean circulation and ecosystems in the Earth system. As global warming causes changes in the SST near the Korean Peninsula, abnormal water temperature phenomena (high water temperature, low water temperature) occurs, causing continuous damage to the marine ecosystem and the fishery industry. Therefore, this study proposes a methodology to predict the SST near the Korean Peninsula and prevent damage by predicting abnormal water temperature phenomena. The study area was set near the Korean Peninsula, and ERA5 data from the European Center for Medium-Range Weather Forecasts (ECMWF) was used to utilize SST data at the same time period. As a research method, Long Short-Term Memory (LSTM) algorithm specialized for time series data prediction among deep learning models was used in consideration of the time series characteristics of SST data. The prediction model predicts the SST near the Korean Peninsula after 1- to 7-days and predicts the high water temperature or low water temperature phenomenon. To evaluate the accuracy of SST prediction, Coefficient of determination (R2), Root Mean Squared Error (RMSE), and Mean Absolute Percentage Error (MAPE) indicators were used. The summer (JAS) 1-day prediction result of the prediction model, R2=0.996, RMSE=0.119℃, MAPE=0.352% and the winter (JFM) 1-day prediction result is R2=0.999, RMSE=0.063℃, MAPE=0.646%. Using the predicted SST, the accuracy of abnormal sea surface temperature prediction was evaluated with an F1 Score (F1 Score=0.98 for high water temperature prediction in summer (2021/08/05), F1 Score=1.0 for low water temperature prediction in winter (2021/02/19)). As the prediction period increased, the prediction model showed a tendency to underestimate the SST, which also reduced the accuracy of the abnormal water temperature prediction. Therefore, it is judged that it is necessary to analyze the cause of underestimation of the predictive model in the future and study to improve the prediction accuracy.

Resistivity-Temperature Properties of Mn-Mg-Fe Oxide Systems (Mn-Mg-Fe 계 산화물 조성의 저항-온도 특성)

  • 이승관;김종령;오영우
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.407-410
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    • 2000
  • (M $n_{l-x}$M $g_{l-x}$)F $e_{2+x}$ $O_4$(x=0.0, 0.025, 0.1, 0.2) for NTC(negative temperature coefficient) thermistor was prepared by calcining at 80$0^{\circ}C$ and sintering at from 1100 to 130$0^{\circ}C$ with 5$0^{\circ}C$ intervals while x was varied from 0.0 to 0.025, 0.1 and 0.2. The best linear property was obtained in the based specimen sintered at 120$0^{\circ}C$ with x=0.1 composition. Thermistor parameter, $B_{25~85^{\circ}C}$, was in the range of 5000~ 7300 [K]. Temperature coefficient of resistance, $\alpha$$_{25^{\circ}C}$, was -5.2 %/$^{\circ}C$. The results showed the possibility that Mn-Ni-Co based thermistor could be substituted by the composition used in this study was confirmed.med.d.

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Preparation of Silicon Oxide Thin Film using Hydrofluorosilicic Acid (규불화수소산을 이용한 실리콘 산화물 필름 제조에 관한 연구)

  • Park, Eun-Hui;Jeong, Heung-Ho;Im, Heon-Seong;Hong, Seong-Su;No, Jae-Seong
    • Korean Journal of Materials Research
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    • v.9 no.4
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    • pp.414-418
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    • 1999
  • Typical metal oxide thin films having optical and electrical properties are widely used as inorganic functional materials. Liquid phase deposition(LPD) method, a new low temperature process, has been developed for the several advantages of no vacuum system, low cost, high throughput, and low processing temperature(<$50^{\circ}C$). Silica powder was added to 40wt% hydrofluoro-silicic acid($H_2$SiF\ulcorner) to obtain an immersing solution of silica-saturated hydrofluorosilicic acid solution. Boric acid solution was continuously added in the range from 0 to 0.05M to prepare supersaturated hydrofluorosilicic acid solution. LPD $SiL_2$film was formed with the variation of added amount of $H_2$O. The SiO$_2$thin film could be prepared from hydrofluorosilicic acid by LPD method. The thickness of LPD $_SiO2$film was influenced by the boric acid concentration and added amount of $H_2$O. Silicon in thin film existed as SiF\ulcorner by Raman spectrum.

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Evaluation of gamma-ray and neutron attenuation properties of some polymers

  • Kacal, M.R.;Akman, F.;Sayyed, M.I.;Akman, F.
    • Nuclear Engineering and Technology
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    • v.51 no.3
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    • pp.818-824
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    • 2019
  • In the present work, we determined the gamma-ray attenuation characteristics of eight different polymers(Polyamide (Nylon 6) (PA-6), polyacrylonitrile (PAN), polyvinylidenechloride (PVDC), polyaniline (PANI), polyethyleneterephthalate (PET), polyphenylenesulfide (PPS), polypyrrole (PPy) and polytetrafluoroethylene (PTFE)) using transmission geometry utilizing the high resolution HPGe detector and different radioactive sources in the energy range 81-1333 keV. The experimental linear attenuation coefficient values are compared with theoretical data (WinXCOM data). The linear attenuation coefficient of all polymers reduced quickly with the increase in energy, at the beginning, while decrease more slowly in the region from 267 keV to 835 keV. The effective atomic number of PVDC and PTFE are comparatively higher than the $Z_{eff}$ of the remaining polymers, while PA-6 possesses the lowest effective atomic number. The half value layer results showed that PTFE ($C_2F_4$, highest density) is more effective to attenuate the gamma photons. Also, the theoretical results of macroscopic effective removal cross section for fast neutrons ($\sum_{R}$) were computed to investigate the neutron attenuation characteristics. It is found that the $\sum_{R}$ values of the eight investigated polymers are close and ranged from $0.07058cm^{-1}$ for PVDC to $0.11510cm^{-1}$ for PA-6.