• Title/Summary/Keyword: F-gas

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An Environmental Evaluation of Copper and Aluminum Metal Resources Circulation by Life Cycle Assessment (LCA기법을 적용한 구리 및 알루미늄 금속자원 순환의 환경성 평가)

  • Shin, Woochul;Hwang, Yongwoo;Moon, Jinyoung;Kong, Chanhwi
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.2
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    • pp.139-146
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    • 2014
  • In this research, we quantified the environmental load while using and not using secondary resources. During the process of primary processed product of metal resources (copper, aluminum), we applied LCA technique and analyzed by dividing into 8 environmental impact categories that affect the environment. Furthermore, we analyzed the greenhouse gas that occur during the process of primary processed product domestically and globally according to the changes of each metal resource's recycling rate. Consequently, when producing 1 ton of copper using secondary resources, the environmental effects were found to be 6.09E + 01 person-yr/f.u. and 7.23E + 01 person-yr/f.u. Additionally, as the recycling rate increased both globally and domestically, the amount of greenhouse gas decreased. Producing 1 ton of Aluminum using secondary resources, the environmental effects were found to be 2.34E + 02 person-yr/f.u. and 3.01E + 02 person-yr/f.u. Moreover, as the recycling rate domestically decreased, the amount of greenhouse gas increased, however the globally was decreased.

Effects of $C_2F_{6}$ Gas on Via Etching Characteristics ($C_2F_{6}$ 가스가 Via Etching 특성에 미치는 영향)

  • Ryu, Ji-Hyeong;Park, Jae-Don;Yun, Gi-Wan
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.39 no.1
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    • pp.31-38
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    • 2002
  • In order to improve the 0.35 $mutextrm{m}$-via hole etching process the etching characteristic of the gas $C_2F_{6}$ has been analyzed. The samples were triple-layer films(TEOS/SOG/TEOS) on 8-inch wafers and the orthogonal array matrix technique was used for the process. The equipment for etching was the transformer coupled plasma (TCP) source which is a type of high density plasma(HDP). This experiment showed the etching rate for $C_2F_{6}$ was 0.8 $mutextrm{m}$/min-1.1 $mutextrm{m}$/min and the measured uniformity was under $pm$6.9% in the matrix window. The CD skew comparison between pre and post-etching was under 10% which is an outstanding results in the window of profile in anisotropic etching. There was no problem in C2F6 with the flow rate of 20sccm, but when 14sccm of $C_2F_{6}$ was supplied there was a recess problem on the inner wall of SOG film. Consequently the etching characteristic of $C_2F_{6}$ shows a fast etching rate and a very wide process window in HDP TCP.

Characteristic Classification of Aroma Oil with Gas Sensors Array and Pattern Recognition (가스센서 어레이와 패턴인식을 활용한 아로마 오일의 특성 분류)

  • Choi, Il-Hwan;Hong, Sung-Joo;Kim, Sun-Tae
    • Journal of Sensor Science and Technology
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    • v.27 no.2
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    • pp.118-125
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    • 2018
  • An evaluation system for an electronic-nose concept using three types of metal oxide gas sensors that react similarly to the human olfactory cells was constructed for the quantitative and qualitative evaluation of aroma fragrances. Four types of aroma fragrances (lavender, orange, jasmine, and Roman chamomile), which are commonly used in aromatherapy, were evaluated. All the gas sensors reacted remarkably to the aroma fragrances and the good correlation of r=0.58-0.88 with the aromatic odor intensities by olfaction was confirmed. From the results of the analysis of an electronic-nose concept for classifying the characteristics of aroma oil fragrances, aroma oils could be classified using the fragrance characteristics and oil extraction methods with the cumulative variability contribution rate of 95.65% (F1: 69.65%, F2: 26.03%) by principal component analysis. In the pattern recognition based on the artificial neural network, the four aroma fragrances were 100% recognized through the training data of 56 cases (70%) out of 80 cases, and the pattern recognition rate was 57.1%-71.4% through the validation and testing data of 24 cases (30%). The pattern recognition success rate through all confusion matrices was 82.1%, indicating that the classification of aroma oil fragrances using the three types of gas sensors was successful.

A Research for Assessment Fire Toxic Gas of Construction Material Using FT-IR and FED (FT-IR과 FED를 이용한 건축 재료의 연소독성평가에 관한 연구)

  • Kim, Sung-Soo;Cho, Nam-Wook;Rie, Dong-Ho
    • Fire Science and Engineering
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    • v.25 no.6
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    • pp.27-31
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    • 2011
  • In this study, combustion toxicity evaluation for building interior materials and study for toxicity as using FT-IR analysis. this experiment for the calculation of toxicity index, it using a cone calorimeter model in KS F ISO/TR 9122-4 as a fire model. It is following ISO 19702 procedure for assessing fire toxic gas using FT-IR. This experiment used calculation method for toxicity index (FED) among the international standards. $LC_{50}$ is a concentration that it can cause death to 50 % of experimental animal in 30 minutes - exposure gas test. comparison with the three kinds of toxicity fire gas of construction materials using toxicity index.

The Effect of Substrate Bias Voltage during the Formation of BN film by R. F. Sputtering Method (RF 스퍼터링법에 의한 BN박막 증착시 기판 바이어스전압의 영향에 관한 연구)

  • 이은국;김도훈
    • Journal of Surface Science and Engineering
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    • v.29 no.2
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    • pp.93-99
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    • 1996
  • In this work BN thin films were deposited on Si substrate by R. F. sputtering method at $200^{\circ}C$ and in Ar + $N_2$ mixed gas atmosphere. In order to investigate the effect of ion bombardment on substrate for c-BN bonding, substrate bias voltage was applied. The optimum substrate bias voltage for c-BN bonding was determined by FTIR analysis on specimens which were deposited with various bias voltages. Then BN thin film was deposited with this optimum condition and its phase, morphology, chemical composition, and refractive index were compared with those of BN film which was deposited without bias voltage. FTIR results showed that BN films deposited with substrate bias voltage were composed of mixed phases of c-BN and h-BN, while those deposited without bias voltage were h-BN only. When pure Ar gas was used for sputtering gas, BN films were delaminated easily from substrate in air, while when 10% $N_2$ gas was added to the sputtering gas, although c-BN specific infrared peak was reduced, delamination did not occur. GXRD and TEM results showed that BN films were amorphous phases regardless of substrate bias voltage, and AES results showed that the chemical compositions of B/N were about 1.7~1.8. The refractive index of BN film deposited with bias voltage was higher than that without bias voltage. The reason is believed to be the existence of c-BN bonding in BN film and the higher density of film that deposited with the substrate bias voltage.

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Pipe Network Analysis for Liquid Rocket Engine with Gas-generator Cycle (액체로켓엔진 가스발생기 사이클의 배관망 해석)

  • Lim, Tae-Kyu;Lee, Sang-Bok;Roh, Tae-Seong
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2012.05a
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    • pp.52-57
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    • 2012
  • A liquid rocket system consists of a combustion chamber, a gas generator, a turbo pump, and a turbine, etc. Each component is connected by supply components such as valves, pipes, and orifices. Since each component has a combined effect on engine performance, preliminary analysis for overall system must be required before the conceptual design stage. Comprehensive analysis program considered the supply system has not been developed yet. In this paper, a supply component model of the liquid rocket engine has been designed after verification of each component. The gas generator cycle with supply components has been composed. The results of the cycle has been compared to those of the F-1 engine with the representative gas generator cycle.

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Conceptual Design and Manufacturing Scheme of a Gas Generator for 7 tonf Class Rocket Engine (7톤급 로켓엔진 가스발생기 개념설계 및 제작계획)

  • Lim, Byoung-Jik;Kim, Moon-Ki;Kang, Dong-Hyuk;Choi, Hwan-Seok
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2012.05a
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    • pp.451-453
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    • 2012
  • Conceptual design and manufacturing scheme of a gas generator for 7 tonf class rocket engine were described. The combustion chamber pressure, O/F ratio, and total flow rate were decided to be 6 MPa, 0.321, and 1 kg/s respectively in consequence of the engine system design. Based on the parameters conceptual design of the gas generator was carried out and its outer dimension was about ${\Phi}100{\times}250mm$. Most parts of the gas generator to be jointed together by brazing or TIG welding and, if possible, the strength and leakproof tests are to be conducted in every step for checking the welding section.

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A Study on the Homogeneity and Stability for HCNG mixing gas (HCNG 혼합가스 균질성 및 안정성 연구)

  • Kim, Young-Gu;Kang, Seung-Gyu;Ahn, Jung-Jin
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.319-321
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    • 2014
  • The homogeneity and the long term stability for HCNG(CNG composed of about 20 % hydrogen) have been studied. The homogeneity by using ANOVA shows that the HCNG mixing gas is homogeneous ; the relative uncertainty of homogeneity is 0.0375 %. The long term stability for HCNG mixing gas by using F-test and t-test shows that HCNG mixing gas is stable ; the relative uncertainty of the long term stability is 0.0682 % for seven months.

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Microquantitative Analysis of Quercetin by Gas Chromatography (Gas Chromatography법에 의한 Quercetin의 미량분석에 관한 연구)

  • 이숙연;김성경
    • YAKHAK HOEJI
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    • v.26 no.2
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    • pp.117-121
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    • 1982
  • This investigation was intended to develope the quantitative gas liquid chromatographic method for quercetin. The method involves derivatization of the sample with trimethylsilylimidazole containing cholesterol as an internal standard and injection into a gas chromatograph with 3% OV-17 column. The calibration curve for the quercetin was linear over a sample in the range of 4-16.mu.g. The minimum detectable amount using FID in $1.6{\times}10^{-10}$ a.f.s. was determined to be $6.64{\times}10^{-10}mol$.

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Reaction Rates for the Oxidation of Pitch based Carbon Fibers in Air and Carbon Dioxide Gas

  • Roh, Jae-Seung
    • Carbon letters
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    • v.4 no.4
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    • pp.185-191
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    • 2003
  • Two types of carbon fiber based high modulus- and isotropic-pitch were exposed to isothermal oxidation in air and $CO_2$ gas and the weight change was measured by TGA apparatus. The kinetic equation was introduced $f=1-{\exp}(-at^b)$ and the constant b was obtained in the range of 1.02~1.68 for the isotropic fiber and obtained 0.91~1.93 for the high modulus fiber respectively. In considering the effect of the atmosphere for isothermal oxidation, the value of the constant b obtained in the carbon dioxide was higher than that obtained in the air. Therefore, it was found that the pitch based carbon fiber shows sigmoidal characteristic when it is oxidized in the carbon dioxide. In addition, it was also found that $k_f = 0.5$, which was reaction constant at f = 0.5, was a very useful parameter for evaluation of the oxidation reactivity of pitch based carbon fibers. According to the consideration, it is suggested that the conversion-time curves of the pitch based carbon fibers are correlated by normalized equation $f=1-{\exp}(-A{\tau}^B)$, where ${\tau}=t/t_f= 0.5$.

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