• Title/Summary/Keyword: Extinction Coefficient

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Investigations on Microcrystalline Silicon Films for Solar Cell Application

  • Hwang, Hae-Sook;Park, Min-Gyu;Ruh, Hyun;Yu, Hyun-Ung
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2909-2912
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    • 2010
  • Hydrogenated microcrystalline silicon (${\mu}c$-Si:H) thin film for solar cells is prepared by plasma-enhanced chemical vapor deposition and physical properties of the ${\mu}c$-Si:H p-layer has been investigated. With respect to stable efficiency, this film is expected to surpass the performance of conventional amorphous silicon based solar cells and very soon be a close competitor to other thin film photovoltaic materials. Silicon in various structural forms has a direct effect on the efficiency of solar cell devices with different electron mobility and photon conversion. A Raman microscope is adopted to study the degree of crystallinity of Si film by analyzing the integrated intensity peaks at 480, 510 and $520\;cm^{-1}$, which corresponds to the amorphous phase (a-Si:H), microcrystalline (${\mu}c$-Si:H) and large crystals (c-Si), respectively. The crystal volume fraction is calculated from the ratio of the crystalline and the amorphous phase. The results are compared with high-resolution transmission electron microscopy (HR-TEM) for the determination of crystallinity factor. Optical properties such as refractive index, extinction coefficient, and band gap are studied with reflectance spectra.

Imaging Performance of the Dependence of EUV Pellicle Transmittance (EUV 펠리클 투과도에 따른 이미지 전사 특성 분석)

  • Woo, Dong Gon;Kim, Jung Hwan;Kim, Jung Sik;Hong, Seoungchul;Ahn, Jinho
    • Journal of the Semiconductor & Display Technology
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    • v.15 no.3
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    • pp.35-39
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    • 2016
  • Extreme Ultraviolet Lithography (EUVL) is the most promising technique in the field of Next Generation Lithography (NGL) expected to be used in the 1x-nm node for High Volume Manufacturing (HVM). But there exits remaining challenges for proper defect control of EUV mask. It was considered development of EUV pellicle for protecting the EUV mask has many obstacles due to high extinction coefficient of EUV wavelength. Recently researchers in the industry of semiconductor argue about the necessity of EUV pellicle and make effort to achieve it. In this paper, we investigated that the relationship between imaging performance and transmittance of EUV pellicle quantitatively. We made in-house EUV pellicle and analyzed its imaging performance of the dependence of pellicle transmittance using Coherent Scattering Microscopy(CSM). The imaging performance of EUV mask with pellicle is affected by its transmittance and we found that the performance of EUV mask improved with higher transmittance pellicle.

Canopy Architecture and Radiation Profiles in Natural Typha $\times$ glauca Stand (부들(Typha$\times$glauca) 자연군락의 엽층부 구조와 수광상태)

  • Kim, Joon-Ho
    • Journal of Plant Biology
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    • v.28 no.1
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    • pp.1-8
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    • 1985
  • To verify the cause of high productivity in Typha stand, leaf area index(LAI), leaf orientation and inclination, specific leaf area (SLA), and radiation interception profiles were determined in a natural Typha$\times$glauca stand. Throughout the growing season, the leaf inclination has been kept at near-right angle and leaf orientation has been random. These chracteristics were responsible for an uniform spatial arrangement of the leaves within the canopy and could be explained by the SLA value, which increased in their higher strata. The extinction coefficient (K) of the canopy, 0.12 to 0.20, was one of the smallest value out of terrestrial plant communities. At least more than 25% of full radiation penetrated into the lowest stratum of the canopy. High productivity of the Typha would be attributed to efficient penetration of the radiation in virtue of the stiff and straight leaves even though rather small LAI.

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The preparation of ${SiO_x}{N_y}$ thin films by reactive RF sputtering method (고주파 반응성 스퍼터링법에 의한 ${SiO_x}{N_y}$ 박막의 제작)

  • 조승현;최영복;김덕현;정성훈;문동찬;김선태
    • Korean Journal of Optics and Photonics
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    • v.11 no.1
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    • pp.13-18
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    • 2000
  • The SiOxNy thin films were prepared on Si(lOO) by reactive RF sputtering method. The reactive gas ratio and the power were used as parameters for depositing SiOxNy thin fims. The properties of ${SiO_x}{N_y}$ thin tilms were investigated by XRD, XPS, refractive index and extinction coefficient analyzer (n'||'&'||'k analyzer), and FfIR. It was found by the results of the x-ray diffraction measurement that SiOxNy thin films were grown to an amorphous structure. From the results of the XPS, and the n'||'&'||'k analyzer, it was found that refractive index was intended to increase with the increasement of the relative nitrogen contents of the ${SiO_x}{N_y}$ thin films.

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Purification and characteristics of cadmium-binding protein from hansenula anomala (Hansenula anomala이 생성하는 cadmium-binding protein의 정제 및 특성)

  • 유대식;구본경
    • Korean Journal of Microbiology
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    • v.28 no.3
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    • pp.258-263
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    • 1990
  • A cadmium-binding protein was purified the cell-free extract of extreme cadmium tolerant Hansenula anomala B-7. The molecular weight was determined to be approximately 33, 000 and was composed two kinds of subunits having a molecular weight of 18, 000 and 14, 000, respectively. The extinction coefficient of the cadmium-binding protein was calculated to be 19.58. The amount of cadmium in the cadmium-binding protein was $9.26{\mu}{\textrm{g}}$ per $100{\mu}{\textrm{g}}$ of protein. A total of 14 amino acids were detected in the cadmium-binding protein, including aspartic acid, glycine and alanine that were present in a high quantity, but proline, valine and methionine were not found. The purified cadmium-binding protein contained a high quantity of cysteine and cadmium, and therefore this protein showed clearly the characteristics of metallothionein.

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Improving the Reliability by Straight Channel of As2Se3-based Resistive Random Access Memory (As2Se3 기반 Resistive Random Access Memory의 채널 직선화를 통한 신뢰성 향상)

  • Nam, Ki-Hyun;Kim, Chung-Hyeok
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.6
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    • pp.327-331
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    • 2016
  • Resistive random access memory (ReRAM) of metallic conduction channel mechanism is based on the electrochemical control of metal in solid electrolyte thin film. Amorphous chalcogenide materials have the solid electrolyte characteristic and optical reactivity at the same time. The optical reactivity has been used to improve the memory switching characteristics of the amorphous $As_2Se_3$-based ReRAM. This study focuses on the formation of holographic lattices patterns in the amorphous $As_2Se_3$ thin film for straight conductive channel. The optical parameters of amorphous $As_2Se_3$ thin film which is a refractive index and extinction coefficient was taken by n&k thin film analyzer. He-Cd laser (wavelength: 325 nm) was selected based on these basic optical parameters. The straighten conduction channel was formed by holographic lithography method using He-Cd laser.$ Ag^+$ ions that photo-diffused periodically by holographic lithography method will be the role of straight channel patterns. The fabricated ReRAM operated more less voltage and indicated better reliability.

Application of sensitivity analyses in premixed combustion within a porous ceramic burner (다공 세라믹 연소기 속에서의 예혼합연소에 대한 민감도 해석의 적용)

  • Im, In-Gwon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.2
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    • pp.162-172
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    • 1998
  • A numerical study of premixed combustion within a porous ceramic burner (PCB) is performed to understand flame behavior with respect to various model parameters. Basic flame structure within the porous ceramic burner and species profiles such as NO and CO are examined. Sensitivity analysis of flame speed, gas and solid temperature, NO and CO emission from the burner with respect to reaction steps and various physical properties of the ceramic material is applied to find the most significant parameters in selection of porous materials for the porous ceramic burner. Effects of thermal conductivity, extinction coefficient and scattering albedo on the burner characteristics are studied through the sensitivity analysis. The results of sensitivity study reveal the order of importance in ceramic material properties to get suitable burner performance. Scattering albedo, which governs the ratio of absorbed energy by the ceramic material to total radiative energy transferred, is one of the most important parameters in the material properties since it affects the actual absorbed radiation rate and thus it largely affects the flame structure. Through the study, it is found that the sensitivity study can be used to estimate the flame behavior within the porous ceramic burner more effectively.

Thermal Characteristics Of Car Interior Materials Using Cone Calorimeter (콘칼로리미터를 이용한 자동차 내장재의 열적 특성)

  • Kim, Young-Tak;Kim, Hae-Rim;Park, Young-Joo;Lee, Hae-Pyeong
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2009.04a
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    • pp.557-563
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    • 2009
  • FMVSS 302 수평 연소 시험법을 통과한 자동차 내장재의 열적 특성을 평가하기 위해서 콘칼로미터를 이용하여 시험을 수행하였다. 화재 위험과 관련된 착화시간(time to ignition), 열방출률(heat release rate), 질량감소율(specific mass loss rate), 감쇠계수(extinction coefficient) 그리고 연기요소(smoke factor)와 같은 여러 가지 요소들을 분석하였다. 최대 열방출률값은 시험편에 따라 232${\sim}$635kW/$m^2$으로 큰 편차를 보였으며, 연기요소 또한 99${\sim}$551MW/$m^2$로 큰 편차를 보였다. 보조매트의 최대 열방출률은 다른 시험편에 비해서 상대적으로 낮은 값을 보였지만, 총연기 발생이 다른 시험편에 비해서 상당히 높았다. 따라서 최대 열방출률과 총 연기발생을 함께 고려한 연기요소값은 상대적으로 다른 시험편에 비해서 높게 나타났다.

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Hydrothermal Growth and Characteristics of ZnO Nanorods on R-plane Sapphire Substrates

  • Kim, Min-Su;Kim, So-A-Ram;Nam, Gi-Ung;Park, Hyeong-Gil;Yun, Hyeon-Sik;Im, Jae-Yeong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.236-237
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    • 2012
  • ZnO nanorods were grown on R-plane sapphire substrates with the seed layers annealed at different temperature. The effects of annealing temperature for the seed layers on the properties of the ZnO nanorods were investigated by scanning electron microscopy, X-ray diffraction, UV-visible spectroscopy, and photoluminescence. For the as-prepared seed layers, the ZnO nanorods and the ZnO nanosheets were observed. Only the ZnO nanorods were grown as the annealing temperature was above $700^{\circ}C$. The optical transmittance in the UV region was almost zero while that in the visible region was gradually increased as the annealing temperature increased to $700^{\circ}C$. The optical band gap of the ZnO nanorods was increased as the annealing temperature increased to $700^{\circ}C$. In the visible region, the refractive index was decreased with increasing the wavelength, and the extinction coefficient was decreased as the annealing temperature increased to $700^{\circ}C$. The non-linear exciton radiative life time of the FX emission peak was established by cubic equation. The values of Varshni's empirical equation fitting parameters were ${\alpha}=4{\times}10^{-3}eV/K$, ${\beta}=1{\times}10^4K$, and $E_g(0)=3.335eV$ and the activation energy was found to be about 94.6 meV.

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Purification of Cellulase from Trichoderma viride and properties of Its Component Enzymes

  • Dong Won Kim;Tae Seung Kim
    • Bulletin of the Korean Chemical Society
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    • v.15 no.9
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    • pp.719-724
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    • 1994
  • Major cellulase components, such as three endoglucanases (endoglucanases I, II, and III) and one exoglucanase (exoglucanase II), were isolated from a commercial cellulase (Meicelase TP 60) derived from the fungus Trichoderma viride by a series of chromatography procedures. These procedures were the gel filtration on Bio-Gel, the anion exchange on DEAE-Bio-Gel A, the cation exchange on SP-Sephadex C50, and the affinity chromatography on Avicel cellulose. The average molecular weights determined by SDS-polyacrylamide gel electrophoretic analysis were 51,000, 59,000, 41,000 and 62,000 Da for endoglucanases I, II and III and exoglucanase II, respectively. The extinction coefficients, ${\varepsilon}^{1%}$ 280 nm, of these enzymes were 11.7, 3.3, 7.2 and 11.3, respectively. Among them, the endoglucanase II showed the very low value of the coefficient compared with the others. On the other hand, it was found that endoglucanase II and III were of more random hydrolytic mode on carboxymethylcellulose as compared with those of endoglucanase I and exoglucanase II. Especially, endoglucanase I showed less random action than that of exoglucanase II. In the hydrolysis of insoluble cellulose by the enzyme components, cellobiose was the major product, but glucose was the major product by endoglucanase III.