• Title/Summary/Keyword: External Carbon

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Utilization as External Carbon Source of TVFAs Fermentation with Sludge (슬러지를 이용한 유기산 발효공정의 외부 탄소원으로 활용)

  • 김영규;김인배;김민호
    • Journal of Environmental Health Sciences
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    • v.27 no.4
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    • pp.79-83
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    • 2001
  • The sludge wastes fermentation process reactors were operated to produce the VFAs(volatile fatty acids) as supplemental carbon sources and to determine the optimum operating conditions. The experiment was carried out by varied mixture ration of 400:0 350:30 300:100 200:200 and operating temperature 2$0^{\circ}C$ 3$0^{\circ}C$ and 4$0^{\circ}C$ The results were as follows: Higher VFAs production rate observed at higher mixed ratio of primary sludge. When the mixed ratio of primary sludge and return sludge were 400:0 350:50 300:100 200:200 respectively. VFAs production are were 829.6mg/l 944.2 mg/l 597.9mg/ml an d441.6 mg/l , respectively. the yield of VFAs increased with temperature, but decreased with initial TSS concentration Because fermented sludge has relatively low nitrogen and phosphorus and relatively high VFAs it can be used as a substitute for external carbon in biological nutrient removal process.

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Development and Full-scale Application of the Alternative Carbon Source Based on the Substrate Compatibility (미생물 순응 호환성에 기반한 대체탄소원 개발 및 실용화 사례)

  • Jung, In-Chul;Jo, Hyeon-Gil;Lee, Du-Ho;Kang, Dong-Hyo;Lim, Keun-Taek;Lee, Sung-Hak;Kim, Chang-Won
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.5
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    • pp.491-498
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    • 2005
  • J sewage treatment plant (WWTP) in Busan has used methanol as an external carbon source for the biological denitrification process. Methanol is widely used. but rather expensive and very dangerous in handling. Therefore, it has been required that the economic alternative carbon source must be developed. By-product from a fine chemical industry can be Purified by removing high molecular weight substances using the ultrafilter membrane separation process and RBDCOD fraction becomes $98{\sim}99%$ of COD substances in the purified by-product. The purified by-product containing three types of alcohols, methanol, prophylenglycol and methoxypropanol; showed similar chemical characteristics to the methanol, a main external carbon source, in biodegradation pathway. Shown above, the compatibility between main and alternative carbon sources has been achieved. Also very short or no adaptation period is necessary in the case of exchanging these carbon sources. The compatibility between external carbon sources is an essential element for stabilizing WWTP operations. During the full-scale application test of the by-product, the alternative carbon source line got on par with the treatment efficiency of the methanol line. With the test result, J-WWTP changed methanol to a fine chemical by-product, in two out of three J-WWTP lines. Moreover, it is expected that 55.4% of the external carbon source cost reduction can be achieved in the alternative carbon source applied lines.

ASSESSMENT OF SUBSTRATE REMOVAL CHARACTERISTICS ACCORDING TO ACCLIMATION PERIODS BY OUR AND NUR TESTS

  • Jung, Jung-Eun;Lee, Sung-Hak;Im, Jeong-Hoon;Poo, Kyoung-Min;Kim, Jong-Rock;Kim, Chang-Won
    • Environmental Engineering Research
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    • v.11 no.3
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    • pp.156-163
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    • 2006
  • In this study, substrate removal characteristics were analyzed to reduce the cost of external carbon dosage at Sudokwon Landfill Site Management Corporation in Korea by utilizing oxygen uptake rate (OUR) and nitrate uptake rate (NUR) tests. To estimate and evaluate the substrate removal characteristics obtained by the batch tests, the lab-scale MLE process was operated. By-products of J Co. (sugar manufactory) and S Co. (fine chemical industry) were selected as the concerned carbon sources through a comparison of carbon and nitrogen contents. MeOH was tested as a control experiment. Until the steady state, the fraction of $RBDCOD_{OUR}$ concentration to COD concentration of J Co., S Co. by-products and MeOH increased and reached levels of 98%, 82%, and 100%, respectively. During the 20th operating day, the fraction of $RBDCOD_{NUR}$ concentration to COD concentration was 95%, 81%, and 83%, respectively. These fractions of $RBDCOD_{NUR}$ concentration to $RBDCOD_{OUR}$ concentration increased according to acclimation periods and reached levels of 99%, 97%, and 81%, respectively, on the 20th day. The results obtained from the lab-scale MLE process operation using the concerned carbon sources as external carbon were similar to that observed by OUR and NUR tests.

Removal Characteristics of Nitrogen and Phosphorus in swine wastewater by Using Acetic acid on the SBR Process (SBR에서 아세트산을 이용한 양돈폐수의 질소·인 제거 특성)

  • Huh, Mock;Kang, Jin-Young
    • Journal of the Korea Organic Resources Recycling Association
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    • v.12 no.1
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    • pp.84-93
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    • 2004
  • This study was performed : 1) to find the suitable HRT(hydralic retention time), 2) to evaluate the effects of the ratio of mixing/aeration time and injection time of external carbon source, for the removal of organics, nitrogen and phosphorus in swine wastewater by SBR(sequencing batch reactor process), which is one of the biological treatment process. The result of this study were summarized as follows : (1) As the ratio of mixing/aeration time was higher, $NH_4{^+}-N$ removal efficiency was increased and it was increased with increasing injection time of external carbon source because nitrification was affected by denitrification microbes propagation when injection time of external carbon soruce was shorted. T-N removal efficiency was increased with increasing the ratio of mixing/aeration time and injection time of external carbon source. (2) The T-P removal efficiency showed a great difference in each operating condition, and it was increased with increasing the ratio of mixing/aeration time increased and when the injection time of external carbon source was shorted because denitrification was done with effect by denitrification microbes propagation. (3) The highest removal efficiency of organic and nitrogen were obtained by the operating condition of Run 4-1(the ratio of mixing/aeration time : 16.5/5.5, injection time of external carbon source : 15hours) and T-P were obtained by the operation condition of Run 4-2(the ratio of mixing/aeration time : 16.5/5.5, injection time of external carbon source : 3hours), and efficiency(effluent concentration)of $BOD_5$, $COD_{Mn}$, $COD_{Cr}$, T-N and T-P in the treated water was 96.1%, 87.7%, 90.6%, 86.6% and 84.5%, respectively.

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A Study on the Recycling of Foodwaste Leachate as External Carbon Sources Using Microbubble (마이크로버블을 이용한 음폐수의 외부탄소원으로서의 재활용 가능성 연구)

  • Lim, Ji-Young;Park, Soo-Young;Kim, Jin-Han
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.36 no.4
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    • pp.651-657
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    • 2016
  • The purpose of this research was to examine the possibility on the recycling of foodwaste leachate as external carbon sources using microbubble. The following operating conditions were selected: pressurizing tank 3 bar, circulation flow rate 3.65 LPM, and air flow rate 0.3 LPM with batch type. Microbubble contact time of 18 hours is optimal time to satisfy the recycling of foodwaste leachate as external carbon sources with batch type. HRT 18 hours came up to standard for external carbon sources, except for T-P concentration with continuous type. Coagulants need to be used for removal of dissolved phosphorus concentration by more than 88.5% of the total phosphorus concentration. The VFA was influenced by the organic decomposition rate and the concentration in the aerobic condition. It was considered that the VFA was needed for selection the optimal HRT or the addition of acid fermentation process in order to meet recycling standard of foodwaste leachate.

A Study on Autocontrolled SBR for Biological Nutrient Removal with External Carbon Sources (외부탄소원 주입시 영양염류의 생물학적 제거를 위한 자동제어 SBR 공정에 관한 연구)

  • Lee, Byung-hun;Kang, Seong-jae;Lim, Sung-il;Yoo, Pyung-jong
    • Journal of Korean Society on Water Environment
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    • v.18 no.4
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    • pp.371-377
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    • 2002
  • The purpose of this study is to develop effective operating process in order to achieve more suitable conditions of Anoxic-Oxic-Anoxic-Stripper(AOAS) SBR through real-time control. To improve the removal efficiency, glucose, methanol and synthetic food waste acid fermentant were added as an external carbon source, In the case of glucose and synthetic food waste acid fermentant, TN, TP were removed to average 86.9%, 73.0% respectively. Methanol was removed to average 64.6%, 55.4% respectively. The synthetic food waste acid fermentant proved to be the most efficient and allowed for the substitution of an external carbon source. The removal rate of $COD_{Cr}$, was approximately 90% at all cases. The results of the study that a correlation between ORP (Oxidation-Reduction Potential), pH and DO and nitrification or denitrification when an external carbon source is added and when it isn't was showed that ${\Delta}ORP$ is suitable parameter. ORP reacted properly to denitrification (${\Delta}ORP<-10$) and nitrification (${\Delta}ORP<0$). The use of real-time control saved anywhere between 61 and 67 minutes at the anoxic(1) stage and 26 to 52 minutes at the oxic(1) stage. When the time saved from the anoxic(1) and oxic(1) was added to the anoxic(2) stage for the removal efficiency of TN and TP increased from 0.7 to 13.9% and 12 to 35 % respectively.

A Study on the Effective Stress of RC Beams in Applying the Adhesion Reinforced and the External Post-Tensioning Method (RC보의 부착보강공법과 외부강선보강공법의 유효응력에 관한 연구)

  • Park, Yong-Gul;Choi, Jung-Youl;Choi, Jun-Hyeok
    • Journal of the Korean Society for Railway
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    • v.10 no.2 s.39
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    • pp.186-194
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    • 2007
  • This study was performed to compare the load-carrying capacities of the reinforced concrete structure between the carbon fiber adhesion reinforcement method and the external post-tensioning method and further estimate the effective stress of the reinforced material by analyzing the experimental reinforcing effect of each method and the behavior resulting from each method. As a result, it was found out that the effective stress of the carbon fiber reinforcement according to the carbon fiber adhesion reinforcement method had an unexpected value, and also, bearing of the stress was found to be far from sharing thereof. That is to say, while the carbon fiber was bearing the whole stress to some limits, it got to be momentarily ruptured as soon as it went beyond such limits. On the other hand, the external post-tensioning method has the advantage of inducing an initial effective stress by introducing a strain, and thus, it was found that behavior or bearing of the stress was also found to be a solid behavior of the steel wire. This method was also found to be more efficient and excellent than the carbon fiber adhesion reinforcement method in the reinforcing effect or securing the effective stress. Accordingly, we were to discuss the effective stress as comparatively examined, focusing on deriving of the more enhanced reinforcing effect on the basis of the experiment to which the field characteristic is added.

An Experimental Guide to Predictable Fuel Cell Operations by Controlling External Gas Supply (외부 유입 가스 조절을 통한 연료전지 구동 성능 안정화)

  • Jang, Hansaem;Park, Youngeun;Lee, Jaeyoung
    • Applied Chemistry for Engineering
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    • v.29 no.5
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    • pp.626-629
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    • 2018
  • Fuel cell is one of the promising electrochemical technologies enabling power production with various fuel sources such as hydrogen, hydrocarbon and even solid carbon. However, its long-term performance is often unstable and unpredictable. In this work, we observed that gasification-driven hydrocarbons were the culprit of unpredictability. Therefore, we controlled the presence of hydrocarbons with the help of external gas supply, i.e. argon and carbon dioxide, and suggested the optimal amount of carbon dioxide required for predictable fuel cell operations. Our optimization strategy was based upon the following observations; carbon dioxide can work as both an inert gas and a fuel precursor, depending on its amount present in the reactor. When deficient, the carbon dioxide cannot fully promote the reverse Boudouard reaction that produces carbon monoxide fuel. When overly present, the carbon dioxide works as an inert gas that causes fuel loss. In addition, the excessive carbon monoxide may result in coking on the catalyst surface, leading to the decrease in the power performance.

- Analysis of Likelihood of Failure for the External Corrosion of Carbon and Low Alloy Steels through the Quantitative Risk Based Inspection using API-581 - (API-581에 의한 정량적 위험기반검사에서 탄소강 및 저합금강의 외부부식에 치한 사고발생 가능성 해석)

  • Lee Hern Chang;Kim Hwan Joo;Jang Seo Il;Kim Tae Ok
    • Journal of the Korea Safety Management & Science
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    • v.6 no.4
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    • pp.239-248
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    • 2004
  • Likelihood of failure for the external corrosion of carbon and low alloy steels, which affect to a risk of facilities, was analyzed quantitatively through the risk based inspection using API-581 BRD. We found that the technical module subfactor (TMSF) decreased as the inspection number increased and it increased as the Inspection effectiveness and the used year increased. In this condition, the TMSF showed high value for the case of the marine/cooling tower drift area as a corrosion driver, poor quality of coating, no insulation, and low insulation condition.

Buckling characteristics of multiwalled carbon nanotubes under external pressure

  • Sato, Motohiro;Shima, Hiroyuki
    • Interaction and multiscale mechanics
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    • v.2 no.2
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    • pp.209-222
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    • 2009
  • This article describes recent work on mechanics of carbon nanotubes, one of the most fundamental and amazing man-made nanostructures. The noteworthy point is that "nano"-scale mechanics of carbon nanotubes can be well described by the continuum elastic theories for "macro"-scale thin shells. This provides an efficient means to elucidate mechanical deformation effects of carbon nanotubes on their physical and chemical properties, which is significant to develop new-generation nanomaterials based on nanotubes and their composites. Potential applications of the mechanical deformation of nanotubes in nano-electronics and nano-biology are also commented. In addition, theoretical investigations regarding external pressure buckling is carried out here and we have numerically confirmed that larger N (the number of layers) and a smaller D (the innermost diameter) make "corrugation modes" with a larger mode-index k be energetically favored.