• Journal of Energy Engineering
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• v.23 no.4
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• pp.169-175
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• 2014

For the safe handling of ethylbenzene, this study was investigated the explosion limits of ethylbenzene in the reference data. And the lower flash points, upper flash points and AITs(auto-ignition temperatures) by ignition delay time were experimented. The lower flash points of ethylbenzene by using Setaflash closed-cup and Pensky-Martens closed-cup testers were experimented $20^{\circ}C$ and $22^{\circ}C$, respectively. The lower flash points ethylbenzene by using Tag and Cleveland open cup testers were experimented $25^{\circ}C$ and $28^{\circ}C$, respectively. Also, this study measured relationship between the AITs and the ignition delay times by using ASTM E659 tester for ethylbnezene. The experimental AIT of ethylbenzene was $430^{\circ}C$. The calculated LEL and UEL by using the measured lower flash point and upper flash point were 0.93 Vol.% and 7.96 Vol.%, respectively.

• Journal of the Korean Institute of Gas
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• v.4 no.4 s.12
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• pp.50-57
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• 2000

Past accidents have shown that vapor cloud explosions are the predominant cause of the largest losses in the chemical and petrochemical industries due to the generation of significant overpressures. Prediction of such overpressure is of great concern and a knowledge of the likely overpressure is needed for the design of equipment, safety cases and emergency planning. For these reasons, risk assessment for vapor cloud explosion is crucial and this assessment can be carried out using the different models including TNT-Equivalency, TNO Hemispherical, TNO Multi-Energy and CFD models. Accordingly, in this paper, the published VCE prediction models are reviewed to provide a critical comparison of the different models used for the quantification of explosion hazards, in terms of the fundamental assumptions employed, and their predictive accuracy

• Korean System Dynamics Review
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• v.16 no.3
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• pp.5-29
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• 2015

The importance of the concept of safety culture has increased in the security of high-risk facility after Chernobyl accident in 1986. This paper elaborated the concept of safety culture and its main factors by Causal Loop Diagram. Due to the decline of safety culture, the occurrence of incidents and accidents require more and more corrective actions to the members of high-risk facilities and thereby increasing their workloads. Employees who must complete the task within the given time have to have time pressures and don't comply with the rules and procedures. Also, a schedule pressure is a big stress for employees, causing mistakes in precision work. In order to improve these problems, CLD of the safety culture in this paper suggests hiring more workers, re-allocation of given workloads and strengthen the learning, communication capabilities and safety leadership. In addition, the two real accident cases were analyzed to test the feasibility of the System Dynamic simulation model through the process of structuring the fault trees on the stationary black out accident in Kori unit 1 in South Korea and Kleen Energy power station explosion in US. The simulation results show that the various safety factors cause the serious accident combined with mechanical failure and safety culture will reduce the possibility of the accidents in these high-risk organizations. This simulation model can contribute to analyzing the impact of the organizational and human factors of safety culture and can provide the alternatives in high-risk facilities.

• Journal of the Korean Society of Safety
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• v.26 no.3
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• pp.15-22
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• 2011

Explosion and fire cause about 30 reported industrial major accidents a year by ignition source which discharge of electrostatic generated to flammable gas, vapor, dust and mixtures. It brings economically and humanly very large loss that accident was caused by fire and explosion from electrostatic discharge. Thus, it is very important that electrostatic discharge energy is to be control below not to be igniting flammable mixtures. There are two kinds of analysis model for electrostatic discharge, human body model and machine model. Human body model is available the parameter of human's electrical equivalent that capacitance is 100 pF, resistance is $1.5k{\Omega}$. To simulate and visualize the electrostatic discharge from human body need a very expensive and high voltage simulator. In this paper, we measured the value of capacitance and resistance concerned with test materials and sizing of specimen and the value of charged voltage concerned with test specimen and distance to develop an electrostatic charge/discharge simulating tool for teaching with which concerned industrial employee and students. The result of experiments, we conformed that the minimum ignition energy of methane-oxygen mixtures meets well the equation $W=1/2CV^2$, and found out that the insulating material and sizing of equivalent value having human body mode are the poly ethylene of 200 mm and 300 mm of diameter. Developed electrostatic charge/discharge simulating tool has many merits; simple mechanism, low cost, no need of electric power and so on.

• Proceedings of the KIEE Conference
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• 2007.07a
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• pp.93-94
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• 2007

An essential step for SERGI is to show the TRANSFORMER PROTECTOR (TP) efficacy for all transformers and all types of rupture of insulation. Its research program philosophy is thus to maintain a strong connection between experiments and the theoretical developments. Up to now, two TP test campaigns have been performed, both under the worst conditions by creating low impedance faults leading to electrical arcs inside the transformer tank dielectric oil. In 2002, Electricite de France performed 28 TP tests. Then, in 2004, a second campaign of 34 TP tests was carried out by CEPEL, the Brazilian independent High Voltage Laboratory. For the 62 tests, each transformer was equipped with the TP, which reacts directly to the moving dynamic pressure peak, shock wave, caused by the low impedance fault. When an electrical arc occurs, only one pressure peak is generated. The initial energy transfer is almost instantaneous, and so is the phase change. Because of the oil inertia, the gas is very quickly pressurised. As it is more difficult to vaporise a liquid than to crack oil-vapour into smaller molecules, the arc location would mainly remain in the gaseous phase after and less gas will be produced. As a result, when comparing tests for which pressure peaks are respectively equal to 8 bar (116 psi) and 8.8 bar (127 psi), the corresponding arc energies vary by an order 10 of magnitude (0.1 MJ and 1 MJ respectively). The correlation of the results obtained between arc energy and dynamic pressure demonstrates that the arc energy is not the key parameter during transformer tank explosion, which is in opposition with the common electrical engineers belief.

• Explosives and Blasting
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• v.37 no.3
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• pp.13-24
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• 2019

This paper was prepared to investigate the behavior of fragments in underwater torpedo explosion beneath a frigate or surface ship by using an explicit finite element analysis. In this study, a fluid-structure interaction (FSI) methodology, called the multi-material arbitrary Lagrangian-Eulerian (MM-ALE) approach in LS-DYNA, was employed to obtain the responses of the torpedo fragments and frigate hull to the explosion. The Euler models for the analysis were comprised of air, water, and explosive, while the Lagrange models consisted of the fragment and the hull. The focus of this modeling was to examine whether a worst-case fragment could penetrate the frigate hull located close (4.5 m) to the exploding torpedo. The simulation was performed in two separate steps. At first, with the assumption that the expanding skin of the torpedo had been torn apart by consuming 30% of the explosive energy, the initial velocity of the worst-case fragment was sought based on a well-known experimental result concerning the fragment velocity in underwater bomb explosion. Then, the terminal velocity of the worst-case fragment that is expected to occur before the fragment hit the frigate hull was sought in the second step. Under the given conditions, the possible initial velocities of the worst-case fragment were found to be very fast (400 and 1000 m/s). But, the velocity difference between the fragment and the hull was merely 4 m/s at the instant of collision. This result was likely to be due to both the tremendous drag force exerted by the water and the non-failure condition given to the frigate hull. Anyway, at least under the given conditions, it is thought that the worst-case fragment seldom penetrate the frigate hull because there is no significant velocity difference between them.

• Journal of the Korean Geotechnical Society
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• v.40 no.4
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• pp.169-178
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• 2024

While stable mid- to large-scale underground hydrogen storage infrastructures are needed to meet the rapidly increasing demand for hydrogen energy, evaluating the safety of explosion vibrations in adjacent buildings is becoming important because of gas explosions in underground hydrogen storage facilities. In this study, a numerical analysis of vibration safety effects on nearby building structures was performed assuming a hydrogen gas explosion disaster scenario in a low-depth underground hydrogen storage facility. A parametric study using a meta-model was conducted to predict changes in ground dynamic behavior for each combination of ground properties and to analyze sensitivity to geotechnical influencing factors. Directly above the hydrogen storage facility, the unit weight of the ground had the greatest influence on the change in ground vibration due to the explosion, whereas, farther away from the facility, the sensitivity of dynamic properties was found to be high. In addition, in evaluating the vibration stability of ground building structures based on the predicted ground vibration data and blasting vibration tolerance criteria, in the case of large reinforced concrete building structures, the ground vibration safety was guaranteed with a separation distance of about 10-30 m.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.6
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• pp.753-763
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• 2016

High temperature sodium/sulfur battery(Na/S battery) has good electrochemical properties, but, the battery has some problems such as explosion and corrosion at al. because of using the liquid electrodes at high temperature and production of high corrosion. Room temperature sodium/sulfur batteries (NAS batteries) is developed to resolve of the battery problem. To recently, room temperature sodium/sulfur batteries has higher discharge capacity than its of lithium ion battery, however, cycle life of the battery is shorter. Because, the sulfur electrode and electrolyte have some problem such as polysulfide resolution in electrolyte and reaction of anode material and polysulfide. Cycle life of the battery is improved by decrease of polysulfide resolution in electrolyte and block of reaction between anode material and polysulfide. If room temperature sodium/sulfur batteries (NAS batteries) with low cost and high capacity improves cycle life, the batteries will be commercialized batteries for electric storage, electric vehicle, and mobile electric items.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1998.05a
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• pp.145-152
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• 1998

실내에서 가스폭발시 피해를 예측하기 위해서 폭발 화염면의 전파를 수치해석을 통해 해석했다. 확산방정식에 의해 가스누출에 의한 실내의 가스확산분포를 구했으며 문헌에서 선택한 누출의 초기조건을 사용했다. 화염온도를 계산하기 위해 각 가스 혼합비에 따른 엔탈피와 화학식에 대한 reduced mechanism을 사용했으며 문헌에서 찾은 각 가스의 농도별 층류 연소속도를 혼합가스의 층류연소속도에 적용시켰다. k-$\varepsilon$ 모델에서 turbulance energy를 층류연소속도와 결합시켜 난류화염 전파속도를 모델링 했다. 화염면의 전파를 분석하기 위해 실내의 위치에는 직각, 화염면의 전파에는 원통좌표계를 사용했다. 유리창의 파손에 의한 화염전파면의 변화에 따른 압력상승 요인을 해석하였으며 창문의 크기에 따라서 점화위치에 따른 실내 압력상승의 영향이 서로 다르게 나타나는 결과를 얻었다.

• Fire Science and Engineering
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• v.10 no.1
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• pp.3-9
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• 1996

Electrostatic charge is generated in large scale or high speed processes dealing with materials with large resistance, or under complicated condition. Fire and explosion often occur due to electrostatic charge accumulated in flammable gases, vapor, liquids and powder. It is usually very difficult to verify the cause of accidents as well as the prevention. In this study, it is shown that the needle electrode needs the electrode gap from 1.8mm to 3.8mm, sphere electrode and plate electrodes need the electrode gap of 1.9mmfor the minimum ignition energy. The sphere electrode and the plate electrode requires 12.8mJ and 3.2mJ of minimum ignition energy respectively with the electrode gap of 1.1mm. The ignition voltage rises to very large value as the ground resistance increases.