• Nuclear Engineering and Technology
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• v.54 no.9
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• pp.3580-3585
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• 2022

The thermal stability of carbohydrazide, hydrazine nitrate, acetohydroxamic acid in nitric acid solutions has been studied at atmospheric pressure and above atmospheric pressure. The volumes of gaseous products of thermolysis and the maximum rate of gas evolution have been determined at atmospheric pressure. It has been shown that, despite the high rate of gas evolution and large volumes of evolved gases, the conditions for the development of autocatalytic oxidation are not created. Exothermic processes are observed in a closed vessel in the temperature range of 50-250 ℃. With an increase in the concentration of nitric acid, the temperatures of the onset of exothermic effects for all mixtures decrease, and the values of the total thermal effects of reactions increase, to the greatest extent for solutions with carbohydrazide.

• Journal of the Korean Society of Safety
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• v.19 no.1
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• pp.66-71
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• 2004

This paper describes that the improved effects on the ignition limit are studied by parallel safety components for propane-air 5.25vol.% mixture gas in low voltage inductive circuits. The experimental devices are used in the IEC type spark ignition test apparatus. The improved effects on the ignition limit are respectively obtained as the maximum rising rate of 650%, 1,080% by composing parallel circuits between inductance and safety components (condenser and diode) as compared with disconnecting inductance with the safety components. The more values of inductance the higher improved effects of ignition limit rise. This improving method for the ignition limit is not concerned with the safety components. Diode appears to effect greatly better than condenser. It is considered that the result can be used for not only data for researches and development of intrinsically safe explosion-proof machines which are applied equipment and detectors used in hazardous areas but also for data for its equipment tests.

• International Journal of Advanced Culture Technology
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• v.11 no.3
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• pp.346-357
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• 2023

The purpose of this study is to suggest improvement plans for prevention regulations by reflecting the toxicity, fire and explosion effects of hazardous materials factories and surrounding areas using an off-site consequence assessment program. Regarding the effects of the hydrogen cyanide leak accident, which is the 1st petroleum of the 4th class flammable liquid, Areal Locations of Hazardous Atmospheres (ALOHA) program was used to compare and analyze the extent of damage effects for toxicity, overpressure, and radiation. As a result, the toxicity was analyzed to exceed 5km in the area with Acute exposure guideline level (AEGL)-2 concentration or higher, the overpressure was 103m in the range of 1 psi or more, and the radiant heat was analyzed to be 724m in the range of 2kw/m² or more. Toxicity and radiation affected the area outside the hazardous material storage area, but the overpressure was limited to the inside of the hazardous material storage area. Therefore, we propose to improve the safety management of hazardous materials by conducting a risk assessment for hazardous materials and reflecting the results in internal and external emergency response plans to prepare prevention regulations.

• Clinical and Experimental Pediatrics
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• v.46 no.2
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• pp.198-202
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• 2003

Of all toxic inhalant exposures, chlorine is one of the most common toxic chemical inhalants. When acutely inhaled, it can be responsible for symptoms ranging from upper air way irritation to more serious respiratory effects. It can also deteriorate lung function and lead to death. Chlorine and its compounds such as chlorinated cyanurates and hypochlorites are commonly used in water disinfection. The chemical agents discussed in this article are sodium dichloroiso cyanurate and calcium hypochlorite which are the two most popular products for swimming pool chlorination. They are both strong oxidizing agents which are soluble in water. Between the above two alkali agents, acid-base interaction occurred and generated heat. And the acid drove the combination of hypochlorous and chloride ions to form chlorine gas. We have experienced, two boys who had inhalation injuries caused by an accidental explosion which occurred in a swimming pool by mixing two different chlorinating agents : sodium dichloroiso cyanurate and calcium hypochlorite. The children suffered from respiratory difficulties after the exposure. They both required intensive care management and one needed the support of mechanical ventilation.

• Journal of the Korean Wood Science and Technology
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• v.45 no.6
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• pp.809-827
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• 2017

Steam explosion was applied to extract phenolic compounds from oak wood (Quercus mongolica). The effects of three independent factors (ethanol concentration, extraction temperature and extraction time) on the total phenolic content, DPPH radical scavenging activity, and antimicrobial activity from the steam exploded oak wood were optimized using response surface methodology (RSM). The independent variables were coded at three levels and their actual values were selected on the basis of preliminary experimental results. The following optimal extraction conditions were selected: ethanol concentration 82.0%, extraction temperature $71.7^{\circ}C$, and extraction time 60.5 min for total phenolic content; ethanol concentration 78.3%, extraction temperature $70.3^{\circ}C$, and extraction time 57.6 min for DPPH radical scavenging activity; ethanol concentration 80.6%, extraction temperature $68.4^{\circ}C$, and extraction time 59.0 min for antimicrobial activity. The experimental values agreed with those were predicted within confidence intervals indicating the suitability of RSM in optimizing the ethanol extraction of phenolic compounds from the steam exploded oak wood. Under the optimized conditions, the experimental value of the total phenolic content was 111.8 mg GAE/g dry steam exploded oak wood, DPPH free radical scavenging activity was 65.7%, and antimicrobial activity was 17.0 mm, and those are reasonably close to the predicted values (109.2 mg GAE/g dry steam exploded oak wood, 62.3% and 15.9 mm, respectively).

• Structural Engineering and Mechanics
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• v.65 no.2
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• pp.163-171
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• 2018

Plain concrete is a brittle material with a very low tensile strength compared to compressive strength and critical tensile strain. This study analyzed the dynamic characteristics of high-performance fiber-reinforced cementitious composites based on slurry-infiltrated fiber concrete (SIFCON-based HPFRCC), which maximizes the steel-fiber volume fraction and uses high-strength mortar to increase resistance to loads, such as explosion and impact, with a very short acting time. For major experimental variables, three levels of fiber aspect ratio and five levels of fiber volume fraction between 6.0% and 8.0% were considered, and the flexural strength and toughness characteristics were analyzed according to these variables. Furthermore, three levels of the aspect ratio of used steel fibers were considered. The highest flexural strength of 65.0 MPa was shown at the fiber aspect ratio of 80 and the fiber volume fraction of 7.0%, and the flexural strength and toughness increased proportionally to the fiber volume fraction. The test results according to fiber aspect ratio and fiber volume fraction revealed that after the initial crack, the load of the SIFCON-based HPFRCC continuously increased because of the high fiber volume fraction. In addition, sufficient residual strength was achieved after the maximum strength; this achievement will bring about positive effects on the brittle fracture of structures when an unexpected load, such as explosion or impact, is applied.

• Fire Science and Engineering
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• v.33 no.5
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• pp.1-6
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• 2019

The recent development of biofuel production technology facilitates the widespread use of bioethanol and biodiesel by mixing them with fossil fuels. However, the use of these new blended fuels in combustion could result in severe safety problems, such as fire and explosion. In this study, numerical simulation was performed on the well-stirred reactor (WSR) to simulate the autoignition temperature (AIT) in homogeneous combustion and clarify the effect of ethanol addition on the AIT, the most important property for assessing the potential for fire and explosion. Response surface methodology (RSM) was introduced as a design of experiment (DOE), enabling the AIT to be predicted and optimized systematically with respect to three independent variables: ethanol mole fraction, equivalence ratio, and pressure. The results show that the autoignition temperature primarily depends on the ethanol mole fraction and pressure, while the effects of the equivalence ratio are independent of the AIT. RSM accurately predicted the experimental AIT, indicating that this method can be used to effectively predict the key properties involved in fires and explosions.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.28 no.2
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• pp.187-195
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• 2015

The gas explosions in offshore installations are known to be very severe according to its geometry and environmental conditions such as leak locations and wind directions, and a dynamic response of structures due to blast loads depends on the load profile. Therefore, a parametric study has to be conducted to investigate the effects of the dynamic response of structural members subjected to various types of load shapes. To do so, a series of CFD analyses was performed using a full-scale FPSO topside model including detail parts of pipes and equipments, and the time history data of the blast loads at monitor points and panels were obtained by the analyses. In this paper, we focus on a structural dynamic response subjected to blast loads changing the magnitude of positive/negative phase pressure and time duration. From the results of linear/nonlinear transient analyses using single degree of freedom(SDOF) and multi-degree-of freedom(MDOF) systems, it was observed that dynamic responses of structures were significantly influenced by the magnitude of positive and negative phase pressures and negative time duration.

• Journal of the Korean Geophysical Society
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• v.3 no.1
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• pp.25-36
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• 2000

3-D Spectrograms for 22 events are drawn to discern about whether those are earthquakes or explosions. Generally, in case of explosions relative to the case of earthquakes, amplitude of P phase is more dominantly shown. According to the results on logarithm of spectral ratio of P (Pn, Pg)/Lg after removing free-surface effects from 3-D (U-D, N-S, E-W) seismogram, $-1.2{\sim}-0.9$ is shown for earthquakes and $-0.7{\sim}-0.1$ if shown for explosions. This result is consistent with previous researches (Kim Park, 1997) that -0.6 of spectral ratio between P and Lg after taking logarithm may be the criterion for the discrimination between earthquakes and explosions in Korea. In addition, Complexity is applied to two events as another discrimination method. The value of Complexity of explosion is much smaller than that of earthquake. This may be due to well-developed P-wave in explosion compared to that in earthquake. This result is in accordance with that of 3-D Spectrogram.

• Journal of Power System Engineering
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• v.9 no.2
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• pp.40-44
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• 2005

A great deal of exhaust gas inside a combustion room goes out through exhaust pipe but residual gas, is called "Blowby gas", enters the crankcase through a small gap between the piston and the cylinder wall. Here, if the crankcase isn't vented, this causes many bad effects such as lubricant oil contamination, corrosion by that and crankcase explosion by rising pressure. So, most automobiles are constituted with a PCV (Positive Crankcase Ventilation) system to prevent previous problems. PCV valve is the most important part in this ventilation system. When companies are manufacturing new engines, engineers are designing it depending on their experiments than theoretical knowledge. Mush efforts and times are needed for new development. This study will show quantitative results to increase the possibilities of reduction of developing time.