• 한국식품과학회지
• /
• 제44권6호
• /
• pp.658-665
• /
• 2012

본 연구는 시중 유통되고 있는 곡류가공품 중 zearalenone을 immunoaffinity column 및 LC-MS/MS를 이용해 분석하였다. 표준용액의 검량선은 1, 10, 50, 100, 250 ng/mL농도 범위에서 상관계수($r^2$) 0.999 이상으로 양호한 직선성을 보였고, 검출한계 및 정량한계는 각각 0.3, $1.0{\mu}g/kg$이었다. 회수율은 77.2-107.8%였고, RSD는 1.5-12.8이었다. Product ion 283 m/z으로 정량하여 분석한 결과 과자류 21건 중 1건(4.8%) $2.3{\mu}g/kg$, 옥수수가공품 9건 중 2건(22.2%) $1.6-8.5{\mu}g/kg$, 기타곡류가공품 14건 중 선식 1건(7.1%)에서 $3.4{\mu}g/kg$이 검출되었다. 미숫가루가 19건 중 6건(31.6%)이 검출되어, 최고 검출율을 나타냈으며, $1.1-29.7{\mu}g/kg$의 검출농도를 나타내어 다른 곡류가공품에 비해 높은 수준이었다. 총 시료 89건 중 10건에서 제랄레논이 검출되어 11.2%의 검출율을 보였고, 오염수준은 $1.1-29.7{\mu}g/kg$이었다. 검출시료 12건은 product ion 187 m/z으로 모두 제랄레논임을 확인하였다. 제랄레논을 측정하는 과정 중 불확도 인자를 파악하여 측정 불확도를 추정 한 결과 41.7, $166.7{\mu}g/kg$일때 보리차는 각각 $44.9{\pm}5.0{\mu}g/kg$(95% 신뢰수준 약 k=2), $128.7{\pm}7.9{\mu}g/kg$(95% 신뢰수준 약 k=2), 미숫가루는 각각 $30.7{\pm}5.8{\mu}g/kg$(95% 신뢰수준 약 k=2), $173.7{\pm}14.9{\mu}g/kg$(95% 신뢰수준 k=2.26), 과자는 $37.2{\pm}7.4{\mu}g/kg$(95% 신뢰수준 k=2.31), $151.0{\pm}10.4{\mu}g/kg$(95% 신뢰수준 약 k=2)를 나타내었다.

• 한국수자원학회논문집
• /
• 제44권10호
• /
• pp.843-851
• /
• 2011

수문학 분야에서 중장기 유출량 예측은 입력변수의 불확실성 등으로 인하여 확률론적 방법을 사용하는 것이 바람직한 것으로 알려져 왔다. 본 연구에서는 금강유역을 대상으로 구성된 바 있는 RRFS-ESP 시스템에 PDF-ratio 방법을 기반으로한 사전처리기능을 장착하여 보다 효율적인 중장기 예측시스템으로의 확장을 시도하여 보았다. 이를 위하여 기상청에서 제공하는 확률기상정보를 이용하여 가중치를 산정하고 이를 기반으로 시나리오별 예측확률을 갱신하였다. 예측결과에 대하여 각 기법별 예측점수를 산정하여 본 결과 우선 ESP 기법에 의한 예측점수의 평균이 초보예측 점수를 상회하여 본 연구에서 구성한 RRFS-ESP 시스템의 적용성을 확인할 수 있었다. 또한 확률기상전망을 이용하여 갱신한 유입량 시나리오의 예측점수가 ESP 기법에 의한 예측점수를 상회하고 있음을 확인할 수 있어 ESP 기법에 의한 예측결과를 확률기상전망을 이용하여 갱신할 경우 예측 정확도를 보다 개선시킬 수 있음을 확인할 수 있었다.

• 유통과학연구
• /
• 제18권2호
• /
• pp.99-108
• /
• 2020

Purpose: This paper investigated the relationship between market competition and firm valuation error. Furthermore, Additional analyses were made according to the quality of financial reports and the listed market. Through the process we confirm to the impact of competition on the capital market. The purpose of this study is to analyze the impact of competition on valuation errors. The preceding studies did not provide a consistent results of the effects of competing functions on the capital market. One view is that the competition could mitigate the information asymmetry, and the other is that monopolistic lessens the manager's involvement in financial reporting. This study is intended to expand the prior study by analyzing the impact of competition on the capital market and on the valuation of investors. Research design, data, and methodology: The analysis was conducted on 12,031 samples over 11 years from 2008 to 2018 using data from market in Korea. Here the valuation error was measured by the research methodology of Rhodes-Kropf, Robinson and Viswanathan (2005), and competition measured by Herfindahl-Hirschman Index multiplied by (-1), and Concentration Ratio by (-1). Results: We confirm that the positive relationship between competition and the valuation error. In addition, we also found that the positive relation between competition and valuation error was in cases of low discretionary accruals and the KOSDAQ market. This means that the net function of competition does not mitigate valuation errors. Conclusions. This study has the following contributions when compared to prior research. First, the relevance between the level of competition and the valuation of the entity was confirmed. The study by Haw, Hu and Lee (2015) suggested that monopolistic industry of analysts' forecast is more accurate due to lower the variability in earnings. This study magnified it to confirm that monopolistic lessen information uncertainty in valuation. Second, the study on valuation errors was expanded. While the study on the effect of valuation errors on the capital market is generally relatively active, it is different that competition degree has analyzed the effect on valuation errors amid the lack of research on the effect on valuation errors.

• Nuclear Engineering and Technology
• /
• 제52권7호
• /
• pp.1511-1516
• /
• 2020

The Korea Research Institute of Standards and Science (KRISS) established a new standard of the absorbed dose to water in LINAC X-ray beams. To confirm the equivalence of the new standard with other national metrology institutes (NMIs), a bilateral comparison study of the absorbed dose to water in high energy X-ray beams was performed between the KRISS and the National Metrology Institute of Japan (NMIJ). The comparison was made in-directly. Three transfer chambers were calibrated in the high energy X-ray beams by both laboratories and the calibration coefficients were compared. The average ratios of the calibration coefficients of the three transfer chambers obtained by the KRISS to those obtained by the NMIJ were 1.004, 1.006, 1.006, 1.007 for 6, 10, 15 and 18 MV X-ray beams, respectively. The calibration coefficients obtained at the KRISS were higher than those at the NMIJ but they were in good agreement within the expanded uncertainty of 1.0% (k = 2). The results of this study will be used as the evidence for the KRISS standard being comparable with those of other NMIs, temporarily, in the interim period up to finalizing a key comparison study, BIPM.RI(I)-K6 managed by the Consultative Committee for Ionizing Radiation.

• 전기학회논문지
• /
• 제59권5호
• /
• pp.972-980
• /
• 2010

In this study, we introduce the design methodology of an optimized type-2 fuzzy cascade controller with the aid of hierarchical fair competition-based genetic algorithm(HFCGA) for ball & beam system. The ball & beam system consists of servo motor, beam and ball, and remains mutually connected in line in itself. The ball & beam system determines the position of ball through the control of a servo motor. Consequently the displacement change of the position of the moving ball and its ensuing change of the angle of the beam results in the change of the position angle of a servo motor. The type-2 fuzzy cascade controller scheme consists of the outer controller and the inner controller as two cascaded fuzzy controllers. In type-2 fuzzy logic controller(FLC) as the expanded type of type-1 fuzzy logic controller(FLC), we can effectively improve the control characteristic by using the footprint of uncertainty(FOU) of membership function. The control parameters(scaling factors) of each fuzzy controller using HFCGA which is a kind of parallel genetic algorithms(PGAs). HFCGA helps alleviate the premature convergence being generated in conventional genetic algorithms(GAs). We estimated controller characteristic parameters of optimized type-2 fuzzy cascade controller applied ball & beam system such as maximum overshoot, delay time, rise time, settling time and steady-state error. For a detailed comparative analysis from the viewpoint of the performance results and the design methodology, the proposed method for the ball & beam system which is realized by the fuzzy cascade controller based on HFCGA, is presented in comparison with the conventional PD cascade controller based on serial genetic algorithms.

• Bulletin of the Korean Chemical Society
• /
• 제26권3호
• /
• pp.440-446
• /
• 2005

A method is described for the determination of dibutyltin (DBT) in sediment by isotope dilution using liquid chromatography inductively-coupled plasma/mass spectrometry (LC-ICP/MS). To achieve the highest accuracy and precision, special attentions are paid in optimization and evaluation of overall processes of the analysis including extraction of analytes, characterization of the standards used for calibration and LC-ICP/MS conditions. An approach for characterization of natural abundance DBT standard has been developed by combining inductively-coupled plasma/optical emission spectrometry (ICP/OES) and LC-ICP/MS for the total Sn assay and the analysis of Sn species present as impurities, respectively. An excellent LC condition for separation of organotin species was found, which is suitable for simultaneous DBT and tributyltin (TBT) analysis as well as impurity analysis of DBT standards. Microwave extraction condition was also optimized for high efficiency while preventing species transformation. The present method determines the amount contents of DBT in sediments with expanded uncertainty of less than 5% and its result shows high degree of equivalence with reference values of an international inter-comparison and a certified reference material (CRM) within stated uncertainties.

• 한국측량학회지
• /
• 제22권4호
• /
• pp.367-374
• /
• 2004

대형 구조물의 측량에 널리 사용되는EDM(Electro-optical distance meter,광파 거리 측정기)의 측정값이 신뢰성을 가지기 위해서는 반드시 EDM의 교정이 필요하다. 본 연구에서는 EDM의 교정을 위한 소급체계를 확립하였는데, 이는EDM이 미터 정의로 부터의 소급성을 가지게 하는 것을 의미한다. 미터 정의에 따라 길이 표준기로 사용되는 요오드 안정화 헬륨­네온 레이저로 레이저 간섭계를 교정하고, 이 레이저 간섭계로 기준 EDM을 교정한 후, 기준 EDM과 기선장에 의해 교정 대상 EDM이 교정됨으로써 미터 정의로의 소급성을 유지한다. 레이저 간섭계를 이용한 EDM의 배율과 길이 측정값에 대한 교정 불확도는 각각 6$\times$$10^{-6}$과 0.2 mm이다. 기선장을 이용한 교정법과 EDM의 변조 주파수를 교정하는 교정법을 병행하여 그 결과를 비교하였다.

• 한국콘텐츠학회논문지
• /
• 제17권1호
• /
• pp.728-739
• /
• 2017

이 연구는 노인계층의 재정적 자립과 지속적 사회생활을 통해 그들이 주체적 삶을 살도록 하기 위해서는 그들의 직업능력개발이 필요하다고 보고, 이를 지원하기 위한 직업능력개발 평생교육프로그램의 지향 방향을 제안하고자 하는 목적을 가지고 시행되었다. 이 연구에서는 노인계층의 직업능력개발 평생교육프로그램과 일자리 간 연계가, 노인들이 안정적인 일자확보와 더불어 고령화로 인한 사회적 문제 해결을 위해 중요하게 확인되어야 할 것으로 보고, 이에 대한 탐색을 통해 향후 프로그램이 지향해야 할 방향을 제시하고자 하였다. 분석결과, 노인의 일자리 기회가 비숙련직 중심으로 열려있으므로 표준화된 정규 편성된 프로그램과 연계되지 못하였고, 이는 프로그램의 전문성 및 지속성의 부족으로 인한 고용불안으로 이어졌다. 또한 노년층의 직업능력개발이 경제활동 목적 이상의 의미를 가진다는 것에 대한 사회적 합의가 부족하여, 직업능력개발 관련 프로그램들이 취업과 직접 연계되지 않고 있었다. 따라서 본 연구는 향후 노인의 신체적 사회적 문제를 공감할 수 있는 기회를 줄 연계프로그램을 확대하고, 노인직업능력개발을 위한 프로그램을 확대 및 표준화하여 프로그램의 전문성 및 지속성을 확보해야 한다고 보았다. 이를 통해 노인의 고용가능성을 향상시킬 수 있는 직업능력개발 평생교육프로그램을 관리 지원하여 교육기관과 일자리 간 연계가 이뤄지도록 해야 할 것이다.

• 분석과학
• /
• 제30권5호
• /
• pp.226-233
• /
• 2017

In general, quantitative chemical analysis in various areas including food, the environment, in vitro diagnostics, etc., requires traceability in order to increase the reliability of the measurements. Measurement traceability is a property of an unbroken chain of comparisons relating an instrument's measurements to SI units. Purity analysis is the first process for establishing traceability to SI units in chemical measurements. The purpose of this study is to develop and validate a method of purity assignment for establishing the traceability of $17{\beta}$-estradiol measurements in an in vitro diagnostics field. The establishment of this method is very important as it can be applied to the development of CRM and to the analysis of the purity of other hormones. The method of assignment of the purity of $17{\beta}$-estradiol was developed using the mass balance method and was validated through participation in an International comparison. In the mass balance method, impurities are categorized into four classes as follows: total related structure impurities, water, residual organic solvents, and nonvolatiles/inorganics. In this study, total related structure impurities were characterized by a gas chromatography-flame ionization detector (GC-FID) and a high-performance liquid chromatography-ultraviolet (HPLC-UV) detector, water content was determined by a Karl-Fisher coulometer, and total residual solvents and nonvolatiles/inorganics were checked simultaneously by thermogravimetric analysis (TGA). The purity of the $17{\beta}$-estradiol was 985.6 mg/g and the expanded uncertainty was 2.1 mg/g at 95% confidence. The developed method can be applied to the development of certified reference materials, which play a critical role in traceability.

• 천문학회보
• /
• 제41권1호
• /
• pp.38.2-38.2
• /
• 2016

The mapping of dark matter clustering from real to redshift spaces introduces the anisotropic property to the measured density power spectrum in redshift space, known as the Redshift Space Distortion (hereafter RSD) effect. The mapping formula is intrinsically non-linear, which is complicated by the higher order polynomials due to the indefinite cross correlations between the density and velocity fields, and the Finger-of-God (hereafter FoG) effect due to the randomness of the peculiar velocity field. Furthermore, the rigorous test of this mapping formula is contaminated by the unknown non-linearity of the density and velocity fields, including their auto- and cross-correlations, for calculating which our theoretical calculation breaks down beyond some scales. Whilst the full higher order polynomials remains unknown, the other systematics can be controlled consistently within the same order truncation in the expansion of the mapping formula, as shown in this paper. The systematic due to the unknown non-linear density and velocity fields is removed by separately measuring all terms in the expansion using simulations. The uncertainty caused by the velocity randomness is controlled by splitting the FoG term into two pieces, 1) the non-local FoG term being independent of the separation vector between two different points, and 2) the local FoG term appearing as an indefinite polynomials which is expanded in the same order as all other perturbative polynomials. Using 100 realizations of simulations, we find that the best fitted non-local FoG function is Gaussian, with only one scale-independent free parameter, and that our new mapping formulation accurately reproduces the observed power spectrum in redshift space at the smallest scales by far, up to k ~ 0.3 h/Mpc, considering the resolution of future experiments.