• Title/Summary/Keyword: Exothermic

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Synthesis and luminescence of silver doped zinc sulfide phosphor

  • Jeong, Young-Ho;Khatkar, S.P.;Park, Jin-Won;Hua, Yang;Han, Sang-Do
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.1013-1016
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    • 2003
  • A new route for the synthesis of silver doped of zinc sulfide phosphor by combustion method has been investigated. Silver nitrate was decomposed with urea or carbohydrazide to give small size particles in presence of alkali metal halides at low temperature compared to the conventional method. The high temperature inherent to the highly exothermic nature of redox reaction leads to well-crystallized powder in short time. The phosphors thus obtained were further heated at $1050^{\circ}C$ in an inert atmosphere for 3hrs to get better luminescence properties.

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Synthesis and luminescence characterization of ZnS:Cu,Al phosphor by combustion method

  • Jeong, Young-Ho;Myung, Kwang-Shik;Park, Jin-Won;Hua, Yang;Han, Sang-Do
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.1009-1012
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    • 2003
  • A novel powder processing technique for the preparation of copper activated zinc sulfide (ZnS:Cu,Al) phosphor by combustion process has been proposed. Exothermic reaction between dissolved copper nitrate and carbohydrazide give small-sized particles in presence of alkali metal halides at lower temperature than the traditional method of preparation. This new route takes less than five minutes and requires much less energy. The optical and luminescence characteristics of ZnS:Cu,Al phosphor thus prepared were found to be enhanced significantly. Carbohydrazide acted as fuel at $500^{\circ}C$ with rapid heating and then the phosphors obtained were heated at $900^{\circ}C$ in an inert atmosphere for 3hrs to get better luminescent properties.

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Dehydrogenation of 2-propanol as a chief reaction for the chemical heat pump (화학적 열 펌프의 주 반응으로서의 2-propanol 반응)

  • 김태경;여영구;송형근
    • 제어로봇시스템학회:학술대회논문집
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    • 1991.10a
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    • pp.1085-1090
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    • 1991
  • Chemical heat pump is a system to upgrade the low level energy such as industrial waste heat and solar energy by using coupled endothermic and exothermic chemical reactions. Dehydrogenation of 2-propanol can absorb heat near 80.deg. C and is transformed into acetone and hydrogen. Hydrogenation of acetone can liberate heat near 200.deg. C. Dehydrogenation of 2-propanol is difficult around 80.deg. C because .DELTA.G has positive value, but dehydrogenation reaction in liquid phase can overcome this problem because vaporized acetone and hydrogen can be rapidly eliminated. In this work, dehydrogenation of 2-propanol was investigated in liquid phase with Raney nickel catalyst. The energy efficiency of the chemical heat pump was estimated by computer simulation.

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The Interaction of Vortex and Premixed Flame with Consideration of Volume Expansion Effect (체적팽창효과를 고려한 예혼합화염과 와동의 상호작용에 관한 연구)

  • Jeong Ui-Heon;Gwon Se-Jin
    • 한국전산유체공학회:학술대회논문집
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    • 1998.11a
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    • pp.204-210
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    • 1998
  • A method is developed to include the effect of volume expansion in the description of the flame dynamics using G-equation. Line volume-source is used to represent the effect of the exothermic process of combustion with source strength determined by the density difference between the burned and the unburned region. Volume expansion adjusts the flow field to accommodate the increased volume flow rate crossing the flame front. Test result predicted the measured velocity field qualitatively. The method was applied to study the interaction of vortex and premixed flame. Increased volume expansion did not change the initial growth rate of flame area. However, the residence time and flame surface area increased with higher expansion ratios.

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Study on n-Butane Autothermal Reforming for Portable Fuel Cell (휴대용 연료전지를 위한 부탄 자열개질에 관한 연구)

  • Bae, Gyu-Jong;Kang, In-Young;Lim, Sung-Kwang;Bae, Joong-Myeon;Kim, Ju-Yong;Lee, Chan-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.11 s.254
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    • pp.1123-1130
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    • 2006
  • This study discusses about research efforts of hydrogen generation from hydrocarbon(e.g., diesel, gasoline, natural gas, and LPG), especially, butane reforming by using Autothermal Reforming Reaction (ATR) technology. Several catalysts were selected for butane ATR. Thermodynamic reactor conditions (temperature, $O_2$/C, S/C) are varied and reforming characteristics of 2 catalysts (Pt and Rh on ceramic supports) and 1 commercial catalyst (FCR-HC35) have been examined. To understand reaction behaviors in an ATR reactor comprehensively, temperature profiles of reactor were observed. By mass transfer limitation, fuel conversion decreases when GHSV increases. Significant temperature variation along the reactor was observed and it was mainly due reaction kinetics difference between exothermic oxidation and endothermic reforming reaction.

Cure simulation and Consolidation for a Thick Glass/Epoxy Laminate (유리섬유/에폭시 후판 복합재료의 경화공정 및 압밀해석)

  • O, Je-Hun;Lee, Dae-Gil
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.11
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    • pp.2853-2865
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    • 2000
  • During the curing process of thick glass/epoxy laminates, a substantial amount of temperature lag and overshoot at the center of the laminates is usually experienced due to the large thickness and low thermal conductivity of the glass/epoxy composites. Also, it takes a longer time for full and uniform consolidation. In this work, temperature, degree of cure and consolidation of a 20 mm thick unidirectional glass/epoxy laminate were investigated using an experiment and a 3-dimentional numerical analysis. From the experimental and numerical results, it was found that the experimentally obtained temperature profile agreed well with the numerical one, and the cure cycle recommended by the prepreg manufacturer should be modified to prevent a temperature overshoot and to obtain full consolidation.

Structure, Spectroscopic Properties and Reactions of Interstellar Molecule HC2N and Isomers :Ab initio Study

  • Park, Sung-Woo;Lee, Seong-Yul
    • Bulletin of the Korean Chemical Society
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    • v.23 no.11
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    • pp.1553-1559
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    • 2002
  • Calculations are presented for the molecule HC2N and its geometrical isomers. The structures, harmonic frequencies and dipole moments are reported. The potential energy surface of the [H,C,C,N] system is investigated in detail, and the transition states, intermediate complexes, and the energies of barrier for the isomerization and dissociation reactions are computed in order to determine the reaction paths and to estimate the stability of the isomers. The barriers of isomerization among HCCN, HCNC and HNCC are computed to be rather large and dissociations of these molecules are highly endothermic, indicating that these molecules are kinetically stable. The association reactions HC + CN→HCCN, HC + NC→HCNC, and HN + CC →HNCC are barrierless and very exothermic, suggesting that they may be considered as efficient means of producing the HCCN and the isomers in the laboratory and in interstellar space.

THERMAL INSTABILITY IN REACTIVE VISCOUS PLANE POISEUILLE / COUETTE FLOWS FOR TWO EXTREME THERMAL BOUNDARY CONDITIONS

  • Ajadi, Suraju Olusegun
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • v.13 no.2
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    • pp.73-86
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    • 2009
  • The problem of thermal stability of an exothermic reactive viscous fluid between two parallel walls in the plane Poiseuille and Couette flow configurations is investigated for different thermal boundary conditions. Neglecting reactant consumption, the closed-form solutions obtained from the momentum equation was inserted into the energy equation due to dissipative effect of viscosity. The resulting energy equation was analyzed for criticality using the variational method technique. The problem is characterized by two parameters: the Nusselt number(N) and the dynamic parameter($\Lambda$). We observed that the thermal and dynamical boundary conditions of the wall have led to a significant departure from known results. The influence of the variable pre-exponential factor, due to the numerical exponent m, also give further insight into the behavior of the system and the results expressed graphically and in tabular forms.

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A Study on the Application of Thermoelectric Module in the Air Conditioner System Using Automotive (차량용 냉방시스템에의 열전소자 적용에 관한 연구)

  • Kim, S.H.
    • Journal of Power System Engineering
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    • v.12 no.4
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    • pp.32-38
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    • 2008
  • The improvement of cooling ability for the air conditioner is the most efficient method of application of its system. Therefore, this study has been investigated the improvement of cooling ability for the air conditioner using automotive by attached of a thermoelectric module. According to the result of test, capacity of the thermoelectric module make temperature range from $-75^{\circ}C$ to $+300^{\circ}C$ possible to cooling and exothermic. In addtion to, the reduction effect of energy revealed and the effect of liquid hammer remained with safety by attached the thermoelectric module. It was found that the air conditioner system by attached thermoelectric module have better cooling ability than the air conditioner system of existing vehicle.

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Study on Soyinin symptons and signs at DongYeuSuSebowon (동의수세보원중 소음인 병증에 대한 고찰)

  • Ko, Heung
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.20 no.2
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    • pp.312-319
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    • 2006
  • Lee je-ma emphasis human constitution and write DongYeuSuSebowon(東醫壽世保元). He describe Sasang constitution diseases with Treatise on Febrile Diseases(傷寒論). Exogenous febrile disease(傷寒) is a pyrexia disease. Therefor this paper is focus on the pyrexia at Soyinin(少陰人) among DongYeuSuSebowon. Soyinin(少陰人) is consider that body water loss is more important than fever in pyrexia disease. And body water loss is happens easily at exothermic reaction (sweating, diarrhea) and sequela of Purgative Prescription(瀉下法), Inducing Diaphoresis(發汗法), Diuresis(利小便法).