Browse > Article
http://dx.doi.org/10.3795/KSME-B.2006.30.11.1123

Study on n-Butane Autothermal Reforming for Portable Fuel Cell  

Bae, Gyu-Jong (한국과학기술원 대학원 기계공학과)
Kang, In-Young (한국과학기술원 대학원 기계공학과)
Lim, Sung-Kwang (한국과학기술원 대학원 기계공학과)
Bae, Joong-Myeon (한국과학기술원 기계공학과)
Kim, Ju-Yong (삼성 SDI)
Lee, Chan-Ho (삼성 SDI)
Publication Information
Transactions of the Korean Society of Mechanical Engineers B / v.30, no.11, 2006 , pp. 1123-1130 More about this Journal
Abstract
This study discusses about research efforts of hydrogen generation from hydrocarbon(e.g., diesel, gasoline, natural gas, and LPG), especially, butane reforming by using Autothermal Reforming Reaction (ATR) technology. Several catalysts were selected for butane ATR. Thermodynamic reactor conditions (temperature, $O_2$/C, S/C) are varied and reforming characteristics of 2 catalysts (Pt and Rh on ceramic supports) and 1 commercial catalyst (FCR-HC35) have been examined. To understand reaction behaviors in an ATR reactor comprehensively, temperature profiles of reactor were observed. By mass transfer limitation, fuel conversion decreases when GHSV increases. Significant temperature variation along the reactor was observed and it was mainly due reaction kinetics difference between exothermic oxidation and endothermic reforming reaction.
Keywords
n-Butane; Fuel Cell; ATR;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 Heinzel, A., Volge, B. and Hubner, P., 2002, 'Reforming of Natural Gas-Hydrogen Generation for Small Scale Stationary Fuel Cell System,' J. of power source, Vol. 105, pp. 202-207   DOI   ScienceOn
2 Kang. I. Y., and Bae. J. M, 2006, 'Study on Reaction Characteristics and Catalysts to Reform Diesel for Production of Hydrogen,' J. of the Korean Electrochemical Society, Vol. 8, No. 1, pp. 12-16
3 Andrew L. Dicks, 1996, 'Hydrogen Generation from Natural Gas for the Fuel Cell Systems,' J. of Power Source, Vol. 161, pp. 113-124   DOI   ScienceOn
4 Krumpelt, M., Krause, T., J. Carter D., Mawdsely, J., Bae, J. M., Kopasz, 1. P., Ahmed, S. and Rossignol, C., 2001, 'Catalytic Autothermal Reforming,' Annual Progress Report, U.S. Department of Energy, pp. 90-95
5 Ahmed, S. and Krumpelt, M., 2001, 'Hydrogen from Hydrocarbon Fuels for Fuel Cells,' J. of Hydrogen Energy, Vol. 26, pp. 291-301   DOI   ScienceOn
6 Rostrup-Nielsen, J. R. and Aasberg-Petersen, K., ?2003, 'Handbook of Fuel Cell,' Vol. 3, pp. 159-179