• Clean Technology
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• 제25권4호
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• pp.316-323
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• 2019

In order to enhance combustion efficiency and reduce atmosphere pollutants, it is essential to measure carbon monoxide (CO) concentration precisely in combustion exhaust. CO is the important gas species regarding pollutant emission and incomplete combustion because it can trade off with NOx and increase rapidly when incomplete combustion occurs. In the case of a steel annealing system, CO is generated intentionally to maintain the deoxidation atmosphere. However, it is difficult to measure the CO concentration in a combustion environment in real-time, because of unsteady combustion reactions and harsh environment. Tunable Diode Laser Absorption Spectroscopy (TDLAS), which is an optical measurement method, is highly attractive for measuring the concentration of certain gas species, temperature, velocity, and pressure in a combustion environment. TDLAS has several advantages such as sensitive, non-invasive, and fast response, and in-situ measurement capability. In this study, a combustion system is designed to control the equivalence ratio. Also, the combustion exhaust gases are produced in a Liquefied Petroleum Gas (LPG)/air flame. Measurement of CO concentration according to the change of equivalence ratio is confirmed through TDLAS method and compared with the simulation based on Voigt function. In order to measure the CO concentration without interference from other combustion products, a near-infrared laser at 4300.6 cm^-1 was selected.

• Journal of the Korean Institute of Gas
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• 제27권3호
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• pp.52-58
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• 2023

With the increasing awareness of the importance of carbon neutrality in response to global climate change, the utilization of hydrogen as a carbon-free fuel source is also growing. Hydrogen is commonly used in fuel cells (FC), but it can also be utilized in internal combustion engines (ICE) that are based on combustion. Particularly, ICEs that already have established infrastructure for production and supply can greatly contribute to the expansion of hydrogen energy utilization when it becomes difficult to rely solely on fuel cells or expand their infrastructure. However, a disadvantage of utilizing hydrogen through combustion is the potential generation of nitrogen oxides (NOx), which are harmful emissions formed when nitrogen in the air reacts with oxygen at high temperatures. In particular, for the EURO-7 exhaust regulation, which includes cold start operation, efforts to reduce exhaust emissions during the warm-up process are required. Therefore, in this study, the characteristics of nitrogen oxides and fuel consumption were investigated during the warm-up process of cooling water from room temperature to 88℃ using a 2-liter direct injection spark ignition (SI) engine fueled with hydrogen. One advantage of hydrogen, compared to conventional fuels like gasoline, natural gas, and liquefied petroleum gas (LPG), is its wide flammable range, which allows for sparser control of the excessive air ratio. In this study, the excessive air ratio was varied as 1.6/1.8/2.0 during the warm-up process, and the results were analyzed. The experimental results show that as the excessive air ratio becomes sparser during warm-up, the emission of nitrogen oxides per unit time decreases, and the thermal efficiency relatively increases. However, as the time required to reach the final temperature becomes longer, the cumulative emissions and fuel consumption may worsen.

• Transactions of the Korean Society of Mechanical Engineers B
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• 제37권3호
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• pp.221-228
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• 2013

An experimental study was carried out to investigate the effects of the injection timing on the spray and combustion characteristics in a spray-guided direct-injection spark-ignition (DISI) engine under lean stratified operation. An in-cylinder pressure analysis, exhaust emissions measurement, and visualization of the spray and combustion were employed in this study. The combustion in a stratified DISI engine was found to have both lean premixed and diffusion controlled flame combustion characteristics. The injection timing condition corresponding to the stratified mixture characteristics was verified to be a dominant factor for these flame characteristics. For the early injection timing, a non-luminous blue flame and low combustion efficiency were observed as a result of the lean homogeneous mixture formation. On the other hand, a luminous sooting flame was shown at the late injection timing because of an under-mixed mixture formation. In addition, the smoke emission and incomplete combustion products were increased at the late injection timing as a result of the increased locally rich area. On the other hand, the NOx emissions decreased and IMEP increased as the injection timing retarded. The combustion phasing produced by the injection timing was verified as the reason for this observation.

• Journal of Energy Engineering
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• 제23권3호
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• pp.211-220
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• 2014

This study reports the formation characteristics of tar, ash and clinker due to a wood pellet grade and the performance analysis of wood pellet boiler in terms of the moisture contents change of the wood pellet. Tar was accumulated on the heating surface according to combustion of wood pellet, the ash was yielded on the floor of combustion chamber in a wood pellet boiler and the clinker was solidified at the burner due to combustion of the 3rd grade wood pellet. Especially, the moisture contents is important factor to define the grade. Wood of logging residues has a non-uniform moisture contents after the field process, yields of tar, ash and clinker are increased in case of combustion due to the high ash contents. For these reasons, emission of harmful compounds in the exhaust gas, decrease of boiler efficiency and the system operating errors are observed. In the performance analysis of wood pellet boiler in terms of the moisture contents change of the 1st grade wood pellet, the boiler efficiency was reduced by 27.08% with 6.6% moisture contents increase. The optimum moisture contents of wood pellet is needed to improve the boiler performance and efficiency.

• Transactions of the Korean Society of Mechanical Engineers B
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• 제36권3호
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• pp.251-257
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• 2012

This work presents an experimental investigation of NOx emissions according to inlet air temperature (550-660 K), stoichiometric air ratio (${\lambda}$, 1.4-2.1), and elevated pressure (2-5 bar) in a High Press Combustor (HPC) equipped with a double cone burner, which was designed by Pusan Clean Coal Center (PC3). The exhaust-gas temperature and NOx emissions were measured at the end of the combustion chamber. The NOx emissions generally decreased as a function of increasing ${\lambda}$. On the other hand, NOx emissions were influenced by ${\lambda}$, inlet air temperature and pressure of the combustion chamber. In particular, when the inlet air temperature increased, the flammability limit was extended to leaner conditions. As a result, a higher adiabatic temperature and lower NOx emissions could be achieved under these operation conditions. The NOx emissions that were governed by thermal NOx were greatly increased under elevated pressures, and slightly increased at sufficiently low fuel concentrations (${\lambda}$ >1.8).

• Journal of the Korea Academia-Industrial cooperation Society
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• 제19권3호
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• pp.112-118
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• 2018

In order to meet the strict emission regulations for internal combustion engines based on fossil fuel, the proportion of after-treatments for vehicles and vessels is gradually increasing. Diesel engines have high power, good fuel economy, and lower $CO_2$ emissions, and their market shares are increasing in commercial vehicles and passenger cars. However, NOx is generated in the localized high-temperature combustion regions, and particulate matter is formed in the zones of diffusion combustion. LNT and urea-SCR catalysts have been developed for after-treatment of the exhaust gas to reduce NOx in diesel vehicles. This study aims to improve the NOx reduction performance of Cu SCR catalyst, which is widely used in light, medium, and heavy-duty diesel engines. The de-NOx performance of $5Cu-2ZrO_2$/93Zeolyst(Si/Al=13.7) SCR catalyst was about 5-50% higher than that of $5Cu-2ZrO_2$/93Zeolite(Si/Al=2.9) at catalyst temperatures of $300^{\circ}C$ or higher. The zeolite had lower metal dispersion than zeolyst, and the reaction rate of the catalyst decreased as the average particle size increased. The $10Cu-2ZrO_2$/88Zeolyst catalyst loaded with 10wt% Cu had the highest NOx conversion rate of 40% at $200^{\circ}C$ and about 65% at $350^{\circ}C$. The ion exchange rate of Cu ions increased with that of Al, the crystalline compound of zeolite, and the de-NOx performance was improved by 20-40% compared to other catalysts.

• Journal of Advanced Marine Engineering and Technology
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• 제38권7호
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• pp.877-882
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• 2014

The reduction of CO2 emission has been discussed in the Marine Environment Protection committee in the International Maritime Organization as the biggest causes of GHG for the purpose of indexing CO2 amounts released into the atmosphere from ships. Accordingly, various methods including the change in the hull design to improve energy efficiency, the coating development to reduce friction resistances, the additives development for improving thermal efficiency in an engine, the low-speed operation to reduce fuel consumptions, and etc. have been applied. The main engine of a ship is an electronic engine for improving the efficiency of the whole load area. However, marine generator engines still use mechanical drive engines in intake, exhaust, and fuel injection valve drive cams. In addition, most of marine generator engines in ships apply a part-load operation of less then 80% due to an overload protection system. Therefore, marine auxiliary diesel engine set at 100% load is necessary to readjust in order to efficient operation because of part-load operation. The objective of this study is to report the results of the part-load fuel consumption improvement by injection timing readjust to identifying the operational characteristics of a marine generator engine currently operated in a ship.

• Journal of Korean Society of Environmental Engineers
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• 제22권12호
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• pp.2255-2261
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• 2000

To eliminate $NO_x$ in diesel emission. selective catalyst reduction (SCR) was used in real diesel engine. Among the SCR methods, metal oxide and perovskite catalysts were introduced in this paper. The removal efficiencies with various major, promoter catalysts on ${\gamma}-Al_2O_3$ at different reaction temperature were investigated, and $LaCuMnO_x$ catalyst which has high removal efficiency at the temperature of real diesel exhaust gas was selected. $NO_x$ reduction was carried out over these catalysts in the flow-through type reactor using by-pass ($SV=3,300h^{-1}$). Under the given condition to this study, perovskite catalysts showed considerably high removal efficiency and $LaCuMnO_x$ was the best one among these catalysts in the temperature range of $150{\sim}450^{\circ}C$.

• Journal of the Korea Institute of Building Construction
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• 제16권6호
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• pp.497-503
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• 2016

Flue gas desulfurization gypsum is produced from emission process of fossil fuel power plant to remove sulfur dioxide ($SO_2$) from exhaust gas. Production of flue gas desulfurization gypsum in Republic of Korea has been increasing due to the enforced regulations by government agency. Since flue gas desulfurization gypsum has characteristic that is similar to that of natural gypsum, there is a strong possibility for flue gas desulfurization gypsum to replace the role of natural gypsum. However, consumption of such material is still limited, only used for agricultural purposes or to make gypsum boards, it is necessary to expand the use of this material more aggressively. In this research, the chemical and mineralogical properties of flue gas desulfurization gypsum were investigated, and flue gas desulfurization gypsum with heat treatment was used to make cement paste. According to the results, it was found that flue gas desulfurization gypsum used in this experiment was a very high purity gypsum, and shown to have similar property to that of natural gypsum. Heat treating flue gas desulfurization gypsum above $100^{\circ}C$ was shown to bring beneficial effect on both compressive strength and drying shrinkage

• Transactions of the Korean Society of Mechanical Engineers B
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• 제35권6호
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• pp.577-583
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• 2011

To meet the requirements of the Tier 4 interim regulations for off-road vehicles, emissions of particulate matter (PM) and nitrogen oxides (NOx) must be reduced by 95% and 30%, respectively, compared to current regulations. In this research, both the DPF and HPL EGR systems were investigated, with the aim of decreasing the PM and NOx emissions of a 56-kW off-road vehicle. The results of the experiments show that the DOC-DPF system is very useful for reducing PM emissions. It is also found that the back pressure is acceptable, and the rate of power loss is less than 5%. By applying the HPL EGR system to the diesel engine, the NOx emissions under low- and middle-load conditions are reduced effectively because of the high differential pressure between the turbocharger inlet and the intake manifold. The NOx emissions can be decreased by increasing the EGR rate, but total hydrocarbon (THC) emission increases because of the increased fuel consumption needed to compensate for the power loss caused by EGR and DPF.