• Title/Summary/Keyword: Exfoliation

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Alveolar bone necrosis and spontaneous tooth exfoliation associated with trigeminal herpes zoster: a report of three cases

  • Kim, Nam-Kyoo;Kim, Bong-Chul;Nam, Jung-Woo;Kim, Hyung-Jun
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.38 no.3
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    • pp.177-183
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    • 2012
  • Herpes zoster is a viral infection caused by the reactivation of the varicella zoster virus, an infection most commonly affecting the thoracolumbar trunk. Herpes Zoster Infection (HZI) may affect the cranial nerves, most frequently the trigeminal. HZI of the trigeminal nerve distribution network manifests as multiple, painful vesicular eruptions of the skin and mucosa which are innervated by the infected nerves. Oral vesicles usually appear after the skin manifestations. The vesicles rupture and coalesce, leaving mucosal erosions without subsequent scarring in most cases. The worst complication of HZI is post-herpetic neuralgia; other complications include facial scarring, motor nerve palsy and optic neuropathy. Osteonecrosis with spontaneous exfoliation of the teeth is an uncommon complication associated with HZI of the trigeminal nerve. We report several cases of osteomyelitis appearing on the mandible, caused by HZI, and triggering osteonecrosis or spontaneous tooth exfoliation.

Solution-Processed Two-Dimensional Materials for Scalable Production of Photodetector Arrays

  • Rhee, Dongjoon;Kim, Jihyun;Kang, Joohoon
    • Journal of Sensor Science and Technology
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    • v.31 no.4
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    • pp.228-237
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    • 2022
  • Two-dimensional (2D) nanomaterials have demonstrated the potential to replace silicon and compound semiconductors that are conventionally used in photodetectors. These materials are ultrathin and have superior electrical and optoelectronic properties as well as mechanical flexibility. Consequently, they are particularly advantageous for fabricating high-performance photodetectors that can be used for wearable device applications and Internet of Things technology. Although prototype photodetectors based on single microflakes of 2D materials have demonstrated excellent photoresponsivity across the entire optical spectrum, their practical applications are limited due to the difficulties in scaling up the synthesis process while maintaining the optoelectronic performance. In this review, we discuss facile methods to mass-produce 2D material-based photodetectors based on the exfoliation of van der Waals crystals into nanosheet dispersions. We first introduce the liquid-phase exfoliation process, which has been widely investigated for the scalable fabrication of photodetectors. Solution processing techniques to assemble 2D nanosheets into thin films and the optoelectronic performance of the fabricated devices are also presented. We conclude by discussing the limitations associated with liquid-phase exfoliation and the recent advances made due to the development of the electrochemical exfoliation process with molecular intercalants.

Simultaneous Exfoliation and Dispersion of Graphene/Carbon Nanotube via Intercalation Reaction and Its Application as Conductive Composite Film (층간삽입 반응을 이용한 그래핀/탄소나노튜브 동시 개별 분산 및 전도성 복합 필름으로의 응용)

  • Kim, Jungmo;Kim, Jin;Yoon, Hyewon;Park, Minsu;Novak, Travis;Ashraful, Azam;Lee, Jinho;Jeon, Seokwoo
    • Composites Research
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    • v.29 no.3
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    • pp.104-110
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    • 2016
  • This paper reports a novel method for simultaneous exfoliation of graphene and dispersion of carbon nanotube by using intercalation method. In common, graphene flake and carbon nanotubes can be produced through individual exfoliation or debundling process, but the process require significant amount of time. Here, potassium sodium tartrate was thermally intercalated into graphite and carbon nanotube bundle for simultaneous exfoliation and dispersion of graphene and carbon nanotubes. We confirmed expansion of interlayer distance via XRD, and also found that oxidation level of the exfoliated materials were significantly low (below 8.3 at%). The produced materials are fabricated in to conductive composite film via vacuum filtration and spray deposition to show enhancement of conductive properties.

Exfoliation of abalone, Haliotis discus hannai using edible plants (식용작물을 이용한 전복 박리)

  • Kim, Wi-Sik;Kim, Jong-Oh;Oh, Myung-Joo
    • Journal of fish pathology
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    • v.30 no.1
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    • pp.63-66
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    • 2017
  • Twenty nine edible plants were selected in order to study their exfoliation effect on abalone Haliotis discus hannai from its substrate. Exfoliation was observed in spearmint Mentha spicata, lemon balm Melissa officinalis, rose flower, onion Allium cepa, wasabi powder, mustard powder, omija Schizandra Chinensis, and hibiscus Hibiscus sabdariffa solutions. In particular, both the omija and hibiscus solutions exfoliated over 90% of the abalone. In field tests, 3% and 4% omija solutions exfoliated 93.6% (850/908) and 97.1% (810/834) of abalone, respectively, whereas 3% and 4% hibiscus solutions exfoliated 96.1% (780/812) and 97.4% (700/719), respectively. The detached abalone were recovered within 1 min 39 seconds. These results indicate that the omija and hibiscus solutions (3% and 4%) may be useful in the exfoliation of abalone.

Mechanical Properties of Organoclay filled NR/BR Blends (Organoclay로 보강된 NR/BR Blends의 기계적 특성)

  • Kim, W.;Kim, S.K.;Kim, S.K.;Chuug, K.H.;Byun, J.Y.
    • Elastomers and Composites
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    • v.39 no.1
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    • pp.51-60
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    • 2004
  • The cure, viscoelastic and mechanical characteristics of organoclay filled NR/BR blends were studied and compared with the properties of carbon black and silica filled NR/BR blends. The nanocomposites with extensive exfoliation state can be fabricated by a solution mixing method. In the composites, the amount of filler content was fixed to 10 phr. Degree of intercalation and exfoliation was characterized by X-ray diffraction (XRD). XRD results indicated exfoliation of the silicate layers into the rubber matrix. While the degree or intercalation and exfoliation is lowered by the conventional mixing method, extensive exfoliation can be obtained by the solution mixing method. It was found that the clay filled NR/BR compound showed better viscoelastic (tan ${\delta}$) and mechanical properties than the carbon black or silica filled NR/BR compounds.

Studies on Interlining -The change of the physical properties based on the weight polyethylene resin of the fusible interlining- (심지에 관한 연구(I) -접착심지의 polyethylene 수지량에 따른 물성변화-)

  • Cho Kyung Aee;Yoo Duk Whan
    • Journal of the Korean Society of Clothing and Textiles
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    • v.6 no.1
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    • pp.17-26
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    • 1982
  • This article aims to determine the interrelation among exfoliation strength, the repeated laundry number, the coefficient of friction and the cover factor about the fusible interlining produced by using different amount resin. The practicality of stiffness and warmth of the fusible interling were examined. The results are summarized as follows: 1) As a factor that affecting the exfoliation strength of fusible interlining, the coefficient of friction and the cover factor about the fusible interlining produced by using different amount resin. (2) Regardless of the weight of the resin, the exfoliation strength of fusible interlining declined gradually as the repeated laundry number increased. This tendency arises much more in the case of the filament yarn fabric than in that of the spun yarn fabric. The stability of the exfoliation strength was better, regardless of the increase of the repeated laundry number, when the weight of the weight of the resin was 10 g/$m^2$. (3) The spun yarn fabric, which has more fuzz than the filament yarn fabric, is more suitable for the fabric of fusible interlining. The smaller the cover factor difference between the face cloth and the interlining cloth, the stronger the exfoliation strength. (4) When the stability of the shape is a necessary factor in the consumption of the fusible interlining, a resin weight of 20 g/$m^2$ is the most suitable; however when stiffness and warmth are necessary factors, a resin weight of 10 g/$m^2$ is the most suitable.

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Acoustic Emission Characteristics of Ceramic Coated Steel by Plasma Spraying (플래즈머용사에 의한 세라믹 코팅 강재의 음향방출 특성)

  • Kim, G.S.
    • Journal of Power System Engineering
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    • v.2 no.3
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    • pp.49-54
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    • 1998
  • This paper is investigated of hardness and adhesiveness of plasma sprayed coating steels by AE(Acoustic Emission) testing when loading a tensile. AE Parameters used are Event, Count, Energy and Amplitude. Test specimens are carbon steel(S45C) with sprayed coating layers of Ni-4.5wt.%Al(bond coating) and $TiO_2$(top coating), and carry out heat treatment at $800^{\circ}C\;and\;1000^{\circ}C$, respectively. The micro-hardness of the heat treatment specimen have been improved more than that of non-heat treatment. On the tensile test, the process and occurence of the exfoliation of the sprayed coating layer can be estimated by AE Characteristics of AE parameters, such as event, count, amplitude and energy, on the layer exfoliation are shown the similar aspects. The exfoliation of bond coating occure at about 20% of strain and top coating is about 5% of strain.

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Preparation of graphene by chemical exfoliation for application to the photoelectrochemical cell (광전기화학 셀 적용을 목적으로 하는 화학적 박리법을 통한 그래핀의 제조)

  • Yoon, Sang-Hyeok;Lee, Dae-Won;Kim, Kyo-Seon
    • Journal of Industrial Technology
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    • v.35
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    • pp.59-65
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    • 2015
  • As the fossil fuels are depleted nowadays, development of alternative energies is absolutely required in the world. Efficient production of hydrogen by water-splitting using solar energy can be one of the methods to solve the global energy and environmental problems. But this method has a problem of low conversion efficiency. The application of graphene can be one method to help increase the conversion efficiency. For this reason, mass production of high quality graphene is required. In this study, we prepared graphene using the chemical exfoliation method. We applied the Hummer's method and Tour's method to oxidize the graphite and could get the different Graphene Oxide(GO) from different process conditions. We also tried to convert the GO to graphene by thermal reduction and could remove functional group of GO effectively. The control of oxidation conditions was quite important to obtain the high quality graphene.

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Changing the sp2 Carbon Clusters in Graphene Oxide During Exfoliation

  • Ahn, Sung Il
    • Transactions on Electrical and Electronic Materials
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    • v.16 no.1
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    • pp.49-52
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    • 2015
  • The change of the chemical structure of graphene oxide (GO) was investigated by periodical sampling of GO during exfoliation by using a sonicator. A significant amount of GO was exfoliated during up to 10 hr of sonication. Raman and Fourier transform infrared spectroscopy revealed a continuous increase of the G/D or C=C/C=O peak ratio of GO, as the sonication time increases. The photoluminescence (PL) intensity of each GO sample also decreased as a function of the sonication time. PL excitation spectra with three major peaks indicate that the sizes of $sp^2$ carbon clusters were enlarged by longer sonication. In addition, new excitation at around 300 nm proves the existence of newly developed small clusters of $sp^2$ carbons as the sonication time increased.

Effect of Matrix Viscosity on Clay Dispersion in Preparation of Polymer/Organoclay Nanocomposites

  • Ko, Moon-Bae;Jho, Jae-Young;Jo, Won-Ho;Lee, Moo-Sung
    • Fibers and Polymers
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    • v.3 no.3
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    • pp.103-108
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    • 2002
  • The viscosity effect of matrix polymer on melt exfoliation behavior of an organoclay in poly($\varepsilon$-caprolactone) (PCL) was investigated. The viscosity of matrix polymer was controlled by changing the molecular weight of poly($\varepsilon$-eaprolactone), the processing temperature, and the rotor speed of a mini-molder. Applied shear stress facilitates the diffusion of polymer chains into the gallery of silicate layers by breaking silicate agglomerates down into smaller primary particles. When the viscosity of PCL is lower, silicate agglomerates are not perfectly broken into smaller primary particles. At higher viscosity, all of silicate agglomerates are broken down into primary particles, and finally into smaller nano-scale building blocks. It was also found that the degree of exfoliation of silicate layers is dependent upon not only the viscosity of matrix but thermodynamic variables.