• Title/Summary/Keyword: Exfoliation

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Membrane Application of Polymer/Layered Silicate Nanocomposite (고분자/층상실리케이트 나노복합체의 분리막에의 응용)

  • Park, Ji-Soon;Rhim, Ji-Won;Goo, Hyung-Seo;Kim, In-Ho;Nam, Sang-Yong
    • Membrane Journal
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    • v.15 no.4
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    • pp.255-271
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    • 2005
  • polymer/layered silicate nanocomposite (PLSNs) is new type of materials, based on clays usually rendered hydrophobic through ionic exchange of the sodium interlayer cation with an onium cation. It could be prepared via various synthetic routes comprising exfoliation adsorption, in situ intercalative polymerization and melt intercalation. The whole range of polymer is used, i.e. thermoplastics, thermosets and elastomers as a matrix. Two types of structure may be obtained, namely intercalated nanocomposites where the polymer chains are sandwiched in between silicate layers and exfolicate nanocomposites where the separated, individual silicate layers are more or less uniformly dispersed in the polymer matrix. This new family of materials exhibits enhanced properties at very low filer level, usually inferior to 5wt$\%$, such as increased mechanical properties, increase in thermal stability and gas barrier properties and good flame retardancy. Gas permeability through the PLSNs films decreased due to increased tortuosity made by intercalation or exfoliation of clay in polymer.

Characteristics of Rock Phase and Phenomena of Exfoliation, Breakout and Cracks Developed on the Rocks Constituting the Soongryemoon (숭례문의 육축을 이루는 석재의 암상 특징과 박리, 박락 및 균열현상)

  • Lee, Sang Hun
    • Journal of Conservation Science
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    • v.11 no.1 s.14
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    • pp.1-14
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    • 2002
  • After the construction (1398 year at first, secondarily reconstructed at 1448 year), the Soongryemoon (South Gate) had been preserved to late 19c without large damages. The present shape of the gate have been kept after the repairments of two times (1953, 1963). However, the rocks constituting the walls of the gate have been strongly weathered, exfoliated and cracked due to severe changes in the environment as traffic increase, air pollution and the subway which may seem also to cause the structural unstability. The rocks composed of the walls of the gate are almost of granites. On the rocks such deteriorations as onion structure, surface exfoliation, cracks, and edge breakout are developed. These deteriorations may be caused genetically by strong weathering, differential load due to possibly structural unstability, impact and unknown reasons. For the establishment of conservation plan, the factors of these deterioration phenomena and structural unstability must be quantitatively analyzed and diagnosed in detail.

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Field Experiments of Consolidant and Filler for Stone Cultural Heritage: Primary Verification Using Ultrasonic Velocity (석조문화재 적용을 위한 강화제 및 충전제 현장실험 : 초음파 속도를 이용한 일차검증)

  • Song, Chi-Young;Jun, Byung-Kyu;Han, Min-Su;Lee, Jang-Jon;Kim, Sa-Dug
    • Journal of Conservation Science
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    • v.25 no.1
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    • pp.87-100
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    • 2009
  • We carried out the effect verification of conservation treatment focusing on basement rock of alkali granite at the Yukjonbul (two-pairs of Buddha Triads) carved on rock cliff of Samneung valley in Namsan mountain of Gyeongju. The conservation treatments were used to ethylsilicate-type rock consolidant and epoxy-type resin. It is treatment method that the epoxy-type resin have been applied one time into the exfoliation area, after rock consolidation treatment have been worked for three times. As the result of measuring ultrasonic velocity, P-wave velocity of the exfoliation area was relatively increased after applied the conservation treatments. The ultrasonic velocity of all area was increased as 27.8%. This result has been proved with consolidation effects by consolidant and filler for stone cultural heritages. The treatment method should be worked about three time to consolidate sufficiently for rocks.

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Geomorphic Development of Tucson and Chiricahua in Arizona, U.S.A (미국 아리조나 투산과 치리카와 지역의 지형발달)

  • PARK, Heui Doo
    • Journal of The Geomorphological Association of Korea
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    • v.15 no.2
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    • pp.1-9
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    • 2008
  • This studied area is divided into the mountains and the valleys. The former is nearly consisted of the badland, the latter is consisted of alluvial plains in the valley, fluvial terrace at the side of the river, alluvial fans between mountains and river terrace. There are many tors, mushroom rocks, sugarloaves, weathering pits, castle coppies, columnar rocks, pinnacles, balanced rocks carved on tuff by means of erosion in the Chiricahua Nat'l Monument. Willcox Playa is alkalic crust where was lake in pleistocene epoch at the time wetter than present. Alkalic crust was made of Ca, Na, K etc. There are sand dunes around here where was lake side in the past. We found many kinds of fossils at the 2,000ft thick horizons of valley alluvium. Pediment and alluvium bordered at the base of Mt. Dragoon wavily. Exfoliation and spalling and sheeting resulted in boulders around here. Tucson is alluvial plain filled in thick 7,0000ft valley. Volcano, fault, erosion, alluvium were and are processing in this area.

The exfoliation of irradiated nuclear graphite by treatment with organic solvent: A proposal for its recycling

  • Capone, Mauro;Cherubini, Nadia;Cozzella, Maria Letizia;Dodaro, Alessandro;Guarcini, Tiziana
    • Nuclear Engineering and Technology
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    • v.51 no.4
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    • pp.1037-1040
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    • 2019
  • For the past 50 years, graphite has been widely used as a moderator, reflector and fuel matrix in different kinds of gas-cooled reactors. Resulting in approximately 250,000 metric tons of irradiated graphite waste. One of the most significant long-lived radioisotope from graphite reactors is carbon-14 ($^{14}C$) with a half-life of 5730 years, this makes it a huge concern for deep geologic disposal of nuclear graphite (NG). Considering the lifecycle of NG a number of waste management options have been developed, mainly focused on the achievement the radiological requirements for disposal. The existing approaches for recycling depend on the cost to be economically viable. In this new study, an affordable process to remove $^{14}C$ has been proposed using samples taken from the Nuclear Power Plant in Latina (Italy) which have been used to investigate the capability of organic and inorganic solvents in removing $^{14}C$ from exfoliated nuclear graphite, with the aim to design a practicable approach to obtain graphite for recycling or/and safety disposed as L& LLW.

The Research of Condition for Mural Tomb in Goa-ri, Goryeong in Gaya period (대가야 시기 고령 고아리 벽화 고분의 보존 상태 연구)

  • Lee, Kyeong Min;Lee, Hwa Soo;Han, Kyeong Soon
    • Korean Journal of Heritage: History & Science
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    • v.48 no.4
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    • pp.44-61
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    • 2015
  • Mural tomb in Goa-ri(Goryeong) built in the 6th Century Gaya period investigated precisely by the scientific method. They were used to optical equipments for investigation and made a damage map according to the damaging types. The mortar layer was mostly exfoliated from the rest of the wall except for the burial chamber ceiling and corridor ceiling. Also painting layers rarely not observed. Most of the paintings were damaged except lotus painting in burial chamber ceiling. Various damage types that exfoliation, earthen dirt, film coating were found in murals. Damage factors of mural were the porous characteristics of mortar layer and the movement of moisture in the murals. They were caused physical damage such as crack, exfoliation. It was getting worse and causing to secondary damage like earthen dirt, film coating.

A study on the improvement of concrete defect detection performance through the convergence of transfer learning and k-means clustering (전이학습과 k-means clustering의 융합을 통한 콘크리트 결함 탐지 성능 향상에 대한 연구)

  • Younggeun Yoon;Taekeun Oh
    • The Journal of the Convergence on Culture Technology
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    • v.9 no.2
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    • pp.561-568
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    • 2023
  • Various defects occur in concrete structures due to internal and external environments. If there is a defect, it is important to efficiently identify and maintain it because there is a problem with the structural safety of concrete. However, recent deep learning research has focused on cracks in concrete, and studies on exfoliation and contamination are lacking. In this study, focusing on exfoliation and contamination, which are difficult to label, four models were developed and their performance evaluated through unlabelling method, filtering method, the convergence of transfer learning based k-means clustering. As a result of the analysis, the convergence model classified the defects in the most detail and could increase the efficiency compared to direct labeling. It is hoped that the results of this study will contribute to the development of deep learning models for various types of defects that are difficult to label in the future.

Clinical Usefulness of the Jones Jig Appliance for Alignment of Premolars and Molars: Case Reports

  • Wonkyu Shin;Hyuntae Kim;Ji-Soo Song;Teo Jeon Shin;Young-Jae Kim;Jung-Wook Kim;Ki-Taeg Jang;Hong-Keun Hyun
    • Journal of the korean academy of Pediatric Dentistry
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    • v.51 no.1
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    • pp.99-108
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    • 2024
  • Early loss of the primary maxillary second molar can lead to complications in which mesial drift of the adjacent first molar (M1) can disturb eruption of the succedaneous second premolar (P2). This study reports two cases of space loss for P2 caused by early exfoliation of its predecessor. After the eruption of the first premolar, the Jones jig appliance was used to distalize M1 and regain space for the eruption of P2. The appliance was further utilized to align the palatally erupted P2 into the dental arch. In both cases, the space and corrected position of P2 were well maintained. Early exfoliation of the primary second molar caused by mesial encroachment of M1 is a common phenomenon, and pediatric dentists should attend to this during routine examinations. An appropriate intervention should be initiated when the primary second molar is lost during the mixed dentition period. If used with careful anchorage control, the Jones jig appliance can effectively resolve this problem.

Hyphae and organic acids of Aspergillus Niger promote uranium recovery by destroying the ore surface and increasing the porosity and permeability of ores

  • Yongdong Wang;Jinhua Wang;Dexin Ding;Guangyue Li;Jing Sun;Nan Hu;Feng Li;Jianhong Ma;Hui Zhang;Yang Ding;Zhongran Dai
    • Nuclear Engineering and Technology
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    • v.56 no.5
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    • pp.1880-1886
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    • 2024
  • To elucidate the mechanism of damage caused by hyphae and organic acids produced by Aspergillus Niger on the surface and internal structure of uranium ore, direct uranium leaching, indirect uranium leaching and semidirect uranium leaching were conducted, and the surface morphology, strength, mineral crystallinity, porosity, and permeability of the ore were analyzed. The results demonstrated that the combination of biomechanical forces exerted by hyphae and the complexation effects of organic acids led to the dissolution of SiO2 and other substances on the surface of ore, resulting in exfoliation from the exterior to the interior, thereby promoting uranium recovery. Furthermore, the proton exchange involving H+ and the complexation of organic acids resulted in the dissolution of cations within the ore, causing destruction to the crystal lattice structure of minerals and increasing the porosity and permeability inside the ore. The dominant factor contributing to ore damage during recovery was organic acids.

Studies on the Resorption of Mandibular First Deciduous Molar (하악제1유구치의 흡수에 관한 연구)

  • Hahn, Se-Hyun
    • The Journal of the Korean dental association
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    • v.17 no.7 s.122
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    • pp.525-528
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    • 1979
  • 958 healthy Korean children aged from 2 to 11 years old (male: 500 female:458) were studied on the root resorption of the mandibular first deciduous molar. The Results were as follows: 1. The resorption of mandibular first deciduous molar in female was earlier than male. 2. The patterns of the initial resorption of mandibular first deciduous molar were as follows Distal root is resorbed by the Successor ; 55.92% Both roots are resorbed by the Successor simultaneously ; 30.51% Mesial root is resorbed by successor ; 6.33% Mesial root is resorbed by the mandibular first bicuspid and canine ; 4.08% Bifurcation area is resorbed by the successor; 3.16% 3. The Exfoliation period of mandibular first deciduous molar was 10 years 1month in female and 10 years 4 months in male.

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