• Korean Chemical Engineering Research
• /
• v.57 no.2
• /
• pp.259-266
• /
• 2019

Tuning of electro-optical properties of nano-structured $SnO_2:Ga$ powders in a micro drop fluidized reactor (MDFR) was highly effective to enhance the activities of powders to be used as sensor materials. The tuning was conducted continuously in a facile one-step process during the formation of powders. The microscopic hydrodynamic forces affected the band gap structure and charge transfer of $SnO_2:Ga$ powders through the oxygen and interfacial tin vacancies by providing plausible pyro-hydraulic conditions, which resulted in the decrease in the electrical resistance of the materials. The analyses of room-temperature photoluminescence (PL) spectra and FT-IR exhibited that the tuning could improve the surface activities of $SnO_2:Ga$ powders by adjusting the excitation as well as separation of electrons and holes, thus maximizing the oxygen vacancies at the surface of the powders. The scheme of photocatalytic mechanism of $SnO_2:Ga$ powders was also discussed.

• Smart Structures and Systems
• /
• v.24 no.3
• /
• pp.361-377
• /
• 2019

The stiffness of shape memory alloy (SMA) spring while in actuation is represented by an empirical model that is derived from the logistic differential equation. This model correlates the stiffness to the alloy temperature and the functionality of SMA spring as active variable stiffness actuator (VSA) is analyzed based on factors that are the input conditions (activation current, duty cycle and excitation frequency) and operating conditions (pre-stress and mechanical connection). The model parameters are estimated by adopting the nonlinear least square method, henceforth, the model is validated experimentally. The average correlation factor of 0.95 between the model response and experimental results validates the proposed model. In furtherance, the justification is augmented from the comparison with existing stiffness models (logistic curve model and polynomial model). The important distinction from several observations regarding the comparison of the model prediction with the experimental states that it is more superior, flexible and adaptable than the existing. The nature of stiffness variation in the SMA spring is assessed also from the Dynamic Mechanical Thermal Analysis (DMTA), which as well proves the proposal. This model advances the ability to use SMA integrated mechanism for enhanced variable stiffness actuation. The investigation proves that the stiffness of SMA spring may be altered under controlled conditions.

• Nuclear Engineering and Technology
• /
• v.54 no.7
• /
• pp.2579-2585
• /
• 2022

Ceramics of quaternary garnets (Gd,Y)₃Al₂Ga₃O₁₂ doped with Ce, Tb have been fabricated and evaluated as prospective materials for indirect energy converters of α-and β-voltaic. Samples were characterized at excitation with an X-ray source and an intense 150 keV electron beam and showed good temperature stability of their emission and tolerance to irradiation. The role of X-rays accompanied the α-particle emitting in the increase of the conversion efficiency is clarified. The garnet-type structure of the matrix in the developed materials allows the production of quality crystalline mass with a light yield exceeding that of the commonly used YAG: Ce scintillator by a factor of two times.

• Progress in Superconductivity and Cryogenics
• /
• v.11 no.1
• /
• pp.16-19
• /
• 2009

Recently, for improvement of the magnetic field of high temperature superconductor (HTS) apparatus, many studies investigating on operating in the range of $20{\sim}65K$ with liquid helium or the conducting method using cryocooler is actively reviewed. Also, the cooling method using solid nitrogen as cryogen is being suggested. Since the nitrogen has very large specific heat in solid state, it is expected that it can enable long time operation without a continuous supply of cooling energy. However, there is still insufficient data on the characteristics of solid nitrogen such as thermodynamic properties and liquid-solid phase change. Especially, there was almost no study done on the electrical insulation properties of solid nitrogen so far. In this study, solid nitrogen to find the electrical characteristics was made by using cryocooler and cryostat, and investigated the flashover discharge and breakdown. The results of this study will be useful as a basic data for electrical insulation design of the HTS system using solid nitrogen as cryogen.

• The Bulletin of The Korean Astronomical Society
• /
• v.44 no.2
• /
• pp.40.3-40.3
• /
• 2019

Our recent observations of the Sun through strong spectral lines have revealed several important properties of the three-minute umbral oscillations inside sunspots -- the oscillations of intensity and Doppler velocity with periods of 2 to 3 minutes. The oscillations usually occur in the form of a time series of oscillation packets each of which lasts 10 to 20 minutes, not as continuous trains. Each oscillation packet is characterized by a singly peaked power spectrum of velocity oscillation. The oscillations propagate in the vertical direction from the photosphere to the corona. In the upper chromosphere, they develop into shocks that eventually collide with the transition region. When shocks propagate along a highly inclined direction, the merging of two successive shocks can take place. Once they enter the corona, they change to linear compressional waves. In the image plane, the three-minute oscillations propagate with high speeds in the transverse direction as well, usually propagating radially outwards from a point, and sometimes accompanying spiraling patterns of Doppler velocity. These observational properties can be theoretically explained by postulating the spatio-temporally localized source of fast MHD waves at a depth of about 2000 km below the surface, the excitation of slow MHD waves via mode conversion near the photosphere, and the resonance of the slow waves in the photospheric layer below the temperature minimum, and the nonlinear development of slow waves in the chromosphere.

• The Bulletin of The Korean Astronomical Society
• /
• v.45 no.1
• /
• pp.58.4-59
• /
• 2020

We present preliminary results of 1.1 and 1.3 mm dust continuum and 12CO (J=2-1) line data obtained with the Submillimeter Array toward six cores harboring Class 0/I objects in the λ Orionis cloud. They are located in bright rimmed clouds, which are exposed to the far-ultraviolet radiation field by the O-type star λ Ori. Compact dust continuum emission is observed from all six cores. Among the six cores, only one core G196.92-10.37 shows a signature of binarity with separation of 4000 AU. The numbers of singles and binaries in our sample are five and one, respectively and the derived multiplicity frequency (MF) is 0.17. This value is lower than those found in the binary surveys toward Class 0/I objects, which may be a hint for negative feedback by the nearby massive star, lambda Ori. The derived excitation temperature (Tex) using 12CO emission shows a lower median value (20 K) than those of triggered star-forming regions (30 K). The lower MF and Tex support our previous study that star formation was not triggered in the λ Orionis cloud. We aim to further investigate whether the Class 0/I YSOs in the λ Orionis cloud have less circumstellar materials and smaller accretion rates than in other filamentary clouds (e.g., Orion A & B), which might be attributed to negative feedback from the massive star in limiting accretion of protostars.

• Journal of the Korean Magnetics Society
• /
• v.16 no.1
• /
• pp.28-33
• /
• 2006

La substituted perovskite $BiFeO_3$ have been prepared by a sol-gel method. Magnetic and structural properties of the powders were characterized with Mossbauer spectroscopy, XRD, SEM, and TG-DTA. The crystal structure is found to be a rhombohedrally distorted perovskite structure with the lattice constant $\alpha=3.985{\AA}\;and\;\alpha=89.5^{\circ}.\;Bi_{2/3}La_{1/3}FeO_3$ powders that were annealed at and above $600^{\circ}C$ have a single-phase perovskite structure. However, powders annealed at $900^{\circ}C$ have a typical perovskite structure with small amount of $Bi_2O_3$ phase. The Neel temperature of $Bi_{2/3}La_{1/3}FeO_3$ is found to be $680\pm3K$. The isomer shift value at room temperature is found to be 0.27 mm/s relative to the Fe metal, which is consistent with high-spin $Fe^{3+}$ charge states. Debye temperature far$Bi_{2/3}La_{1/3}FeO_3$ is found to be $305\pm5K$. The average hyperfine field $H_{hf}(T)$ of the $Bi_{2/3}La_{1/3}FeO_3$, shows a temperature dependence of $[H_{hf}(T)-H_{hf}(0)]/H_{hf}(0)=-0.42(T/T_N)^{3/2}-0.13(T/T_N)^{5/2}$ for $T/T_N<0.7$ indicative of spin-wave excitation.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2016.02a
• /
• pp.179-179
• /
• 2016

A radio-frequency (RF) Inductively Coupled Plasma (ICP) torch system was used for boron-nitride nano-tube (BNNT) synthesis. Because of electrodeless plasma generation, no electrode pollution and effective heating transfer during nano-material synthesis can be realized. For stable plasma generation, argon and nitrogen gases were injected with 60 kW grid power in the difference pressure from 200 Torr to 630 Torr. Varying hydrogen gas flow rate from 0 to 20 slpm, the electrical and optical plasma properties were investigated. Through the spectroscopic analysis of atomic argon line, hydrogen line and nitrogen molecular band, we investigated the plasma electron excitation temperature, gas temperature and electron density. Based on the plasma characterization, we performed the synthesis of BNNT by inserting 0.5~1 um hexagonal-boron nitride (h-BN) powder into the plasma. We analysis the structure characterization of BNNT by SEM (Scanning Electron Microscopy) and TEM (Transmission Electron Microscopy), also grasp the ingredient of BNNT by EELS (Electron Energy Loss Spectroscopy) and Raman spectroscopy. We treated bundles of BNNT with the atmospheric pressure plasma, so that we grow the surface morphology in the water attachment of BNNT. We reduce the advancing contact angle to purity bundles of BNNT.

• Journal of the Korean Applied Science and Technology
• /
• v.23 no.3
• /
• pp.207-214
• /
• 2006

$Y_{2-x}Gd_xO_3:Eu$, phosphors for plasma display panel(PDP), were prepared by Pechini method which use yttriun chloride, gadolinium chloride, and europium oxide as starting materials. This method is a different way to the synthesis of europium(Eu)-doped phosphors, and it consists of the formation of a polymeric resin obtained by polyesterification between metal chelate compounds and a polyfunctional alcohol. This needs lower temperature than solid-state synthetic method. The prepared $Y_{2-x}Gd_xO_3:Eu$ phosphor particles had spherical shape and coherence. The luminescence intensity of $Y_{2-x}Gd_xO_3:Eu$ phosphor particles increased according to the increase of gadolinium(Gd) content(to 0.8mol%), and $Y_{1.2}Gd_{0.8}O_3:Eu$ phosphors had the highest luminescence intensity under vacuum ultra violet(VUV) excitation. The optimum concentration of Eu in the phosphor and optimum calcination temperature was 3wt% and $1100^{\circ}C$. The prepared phosphors were consist of particle, and its size was between 100nm and 150nm. Among the different polyfunctional alcohols, diethylene glycol(DEG) improved the luminescence intensities of phosphors more than other additives. The Pechini method proved that it is demonstrated to be suitable for the synthesis of phosphors used in PDP.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.19 no.3
• /
• pp.130-134
• /
• 2009

A new long persistent phosphors of $CaZrO_3$ was synthesized at high temperature with weak reduction atmosphere by a traditional solid state reaction method. Photoluminescence spectra analysis showed that the $CaZrO_3$ doped with $Tb^{3+}$ emitted green-yellow emission caused by the energy level transition from the $^5D_3$ and $^5D_4$ to $^7F_1{\sim}^7F_6$. The main emission spectra of 542 nm peak by the $^5D_4{\rightarrow}^7F_5$ transition was revealed through synthesizing at high temperature in $N_2$ gas atmosphere. The afterglow emission spectra of $CaZrO_3:Tb^{3+}$ long persistent phosphores arise at 546 nm peak of narrow range. After the 254 nm ultraviolet light excitation source was switched off, the green-yellow long persistent phosphor can be observed which could last for 8 h in the limit of light perception of dark-adapted human eyes ($0.32\;mcd/m^2$).