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EDTA Surface Capped Water-Dispersible ZnSe and ZnS:Mn Nanocrystals

  • Lee, Jae-Woog;Lee, Sang-Min;Huh, Young-Duk;Hwang, Cheong-Soo
    • Bulletin of the Korean Chemical Society
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    • v.31 no.7
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    • pp.1997-2002
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    • 2010
  • ZnSe and ZnS:Mn nanocrystals were synthesized via the thermal decomposition of their corresponding organometallic precursors in a hot coordinating solvent (TOP/TOPO) mixture. The organic surface capping agents were substituted with EDTA molecules to impart hydrophilic surface properties to the resulting nanocrystals. The optical properties of the water-dispersible nanocrystals were analyzed by UV-visible and room temperature solution photoluminescence (PL) spectroscopy. The powders were characterized by X-ray diffraction (XRD), high resolution transmission electron microscopy (HR-TEM), and confocal laser scanning microscopy (CLSM). The solution PL spectra revealed emission peaks at 390 (ZnSe-EDTA) and 597 (ZnS:Mn-EDTA) nm with PL efficiencies of 4.0 (former) and 2.4% (latter), respectively. Two-photon spectra were obtained by fixing the excitation light source wavelengths at 616 nm (ZnSe-EDTA) and 560 nm (ZnS:Mn-EDTA). The emission peaks appeared at the same positions to that of the PL spectra but with lower peak intensity. In addition, the morphology and sizes of the nanocrystals were estimated from the corresponding HR-TEM images. The measured average particle sizes were 5.4 nm (ZnSe-EDTA) with a standard deviation of 1.2 nm, and 4.7 nm (ZnS:Mn-EDTA) with a standard deviation of 0.8 nm, respectively.

Influence of Deposition Method on Refractive Index of SiO2 and TiO2 Thin Films for Anti-reflective Multilayers

  • Song, Myung-Keun;Yang, Woo-Seok;Kwon, Soon-Woo;Song, Yo-Seung;Cho, Nam-Ihn;Lee, Deuk-Yong
    • Journal of the Korean Ceramic Society
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    • v.45 no.9
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    • pp.524-530
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    • 2008
  • Anti-Reflective (AR) thin film coatings of $SiO_2$ (n= 1.48) and $TiO_2$ (n=2.17) were deposited by ion-beam assisted deposition (IBAD) with End-Hall ion source and conventional electron beam (e-beam) evaporation to investigate the effect of deposition method on the refractive indicies (n) of the fIlms. Green-light generation using a GaAs laser diode was achieved via excitation of the second harmonic. The latter resulted from the transmission of the fundamental guided-mode wave of 1064 nm through periodically poled $LiNbO_3$. Large differences in the refractive indicies of each of the layers in the multilayer coating may improve AR performance. IBAD of $SiO_2$ reduced its refractive index from 1.45 to 1.34 at 1064 nm. Conversely, e-beam evaporation of $TiO_2$ increased its refractive index from 1.80 to 2.11. In addition, no fluctuations in absorption at the wavelength of 1064 nm were found. The results suggest that films prepared by different deposition methods can increase the effectiveness of multilayer AR coatings.

Luminescence properties of a new $Tb^{3+}$ ion activated long persistent phosphor (새로운 $Tb^{3+}$ 이온 활성 축광성 형광체의 발광 특성)

  • Park, Byeong-Seok;Choi, Jong-Geon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.3
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    • pp.130-134
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    • 2009
  • A new long persistent phosphors of $CaZrO_3$ was synthesized at high temperature with weak reduction atmosphere by a traditional solid state reaction method. Photoluminescence spectra analysis showed that the $CaZrO_3$ doped with $Tb^{3+}$ emitted green-yellow emission caused by the energy level transition from the $^5D_3$ and $^5D_4$ to $^7F_1{\sim}^7F_6$. The main emission spectra of 542 nm peak by the $^5D_4{\rightarrow}^7F_5$ transition was revealed through synthesizing at high temperature in $N_2$ gas atmosphere. The afterglow emission spectra of $CaZrO_3:Tb^{3+}$ long persistent phosphores arise at 546 nm peak of narrow range. After the 254 nm ultraviolet light excitation source was switched off, the green-yellow long persistent phosphor can be observed which could last for 8 h in the limit of light perception of dark-adapted human eyes ($0.32\;mcd/m^2$).

Luminescence properties of novel Sr-Y-Si-Oxynitride yellow phosphor for LED applications (LED용 Sr-Y-Si-계 산질화물 황색 형광체의 발광 특성)

  • Jeong, Ok Geun;Park, Jong Cheon;Ryu, Jeong Ho;Cho, Hyun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.4
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    • pp.195-200
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    • 2013
  • Novel Sr-Y-Si-Oxynitride yellow phosphors were synthesized and the effect of calcination temperature, reduction temperature and $Eu^{2+}$ concentration on their luminescence properties were studied. Optimal temperature conditions were found to be $1400^{\circ}C$ and $1300^{\circ}C$ for solid-state reaction and reduction, respectively. The synthesized $Ba_9Y_{2+y}Si_6O_{24-3y}N_{3y}:Eu^{2+}$ phosphors showed a single intense broadband emission in the range of 571~587 nm for 450 nm excitation light source. The highest luminescence intensity was obtained with Eu concentration of 3 mol% and concentration quenching was observed beyond 5 mol%. FE-SEM and PSA showed that the synthesized phosphors consists of particles with an average size of ${\sim}8.2{\mu}m$.

Characteristic of Vibration in Windturbine System (풍력발전시스템의 진동특성)

  • Kim, Jung-Su;Lee, Hyoung-Woo;Park, No-Gill;Kim, Young-Duk;Kim, Soo-Yum;Lee, Dong-Hwan
    • Journal of Advanced Marine Engineering and Technology
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    • v.35 no.6
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    • pp.786-795
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    • 2011
  • This paper described the characteristic of vibration in wind turbine system including gearbox housing, gear drive, blade, generator. Especially, in planetary gear set, planet gears are supported by flexible pin. So, in planet gear, to consider not only torsional movement but also lateral movement. And include housing movement, because wind turbine system is supported by mount. To find out the characteristic of vibration, take the excitation source and study campbell diagram in operating range. Results of campbell diagram, resonances are occurred at 81.2HZ, 104.7Hz by 2nd tooth passing frequency. And resonance are also occurred at 264.5HZ, 377Hz, 424.6Hz by 3th tooth passing frequency. From the result, take vibration reduced measures.

Development of LabVIEW Program for Lock-In Infrared Thermography (위상잠금 열화상장치 제어용 랩뷰 프로그램 개발)

  • Min, Tae-Hoon;Na, Hyung-Chul;Kim, Noh-Yu
    • Journal of the Korean Society for Nondestructive Testing
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    • v.31 no.2
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    • pp.127-133
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    • 2011
  • A LabVIEW program has been developed together with simple infrared thermography(IRT) system to control the lock-in conditions of the system efficiently. The IR imaging software was designed to operate both of infrared camera and halogen lamp by synchronizing them with periodic sine signal based on thyristor(SCR) circuits. LabVIEW software was programmed to provide users with screen-menu functions by which it can change the period and energy of heat source, operate the camera to acquire image, and monitor the state of the system on the computer screen. In experiment, lock-in IR image for a specimen with artificial hole defects was obtained by the developed IRT system and compared with optical image.

Photoluminescence of willemite ($Zn_2SiO_4$ : Mn) phosphors prepared by the MOD process (MOD법에 의해 합성한 Willemite($Zn_2SiO_4$:Mn) 형광체의 발광 특성)

  • Lee, Byeong-Woo;Lee, Seon-Gil;Cho, Hyun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.2
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    • pp.57-62
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    • 2007
  • Willemite green phosphor powders have been prepared by the metallo-organic decomposition (MOD) method, and the photoluminescence and phase formation were studied as a function of both the firing temperature ($800{\sim}1100^{\circ}C$) and the concentration of Mn activator ($4{\sim}12 mol%$). Under 254 nm excitation source, the emission intensity of the phosphors increased with increasing the firing temperature from 800 to $1000^{\circ}C$. From the XRD analysis, the powders heat-treated above $1000^{\circ}C$ showed willemite crystal structure. The maximum emission intensity was obtained far the phosphors heat-treated at $1000^{\circ}C$ with 8 mol% of Mn content. The concentration quenching was occurred when the Mn concentration exceeded 10 mol%. The phosphor particles showed spherical shapes with the average size of $0.4{\sim}0.5{\mu}m$ by the SEM morphology.

A Study on Multi-Pulse Speech Coding Method by Using V/S/TSIUVC (V/S/TSIUVC를 이용한 멀티펄스 음성부호화 방식에 관한 연구)

  • Lee See-Woo
    • Journal of Korea Multimedia Society
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    • v.7 no.9
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    • pp.1233-1239
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    • 2004
  • In a speech coding system using excitation source of voiced and unvoiced, it would be involved a distortion of speech qualify in case coexist with a voiced and an unvoiced consonants in a frame. This paper present a new multi-pulse coding method by using V/S/TSIUVC switching, individual pitch pulses and TSIUVC approximation-synthesis method in order to restrict a distortion of speech quality. The TSIUVC is extracted by using the zero crossing rate and individual pitch pulse. And the TSIUVC extraction rate was 91% for female voice and 96.2% for male voice respectively. The important thing is that the frequency information of 0.347kHz below and 2.813kHz above can be made with high quality synthesis waveform within TSIUVC. I evaluate the MPC use V/UV and the FBD-MPC use V/S/TSIUVC. As a result, I knew that synthesis speech of the FBD-MPC was better in speech quality than synthesis speech of the MPC.

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Piezoelectric Energy Harvesting from Bridge Vibrations under Railway Loads (철도하중에 의한 교량 진동을 이용한 압전 에너지 수확)

  • Kwon, Soon-Duck;Lee, Hankyu
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.4A
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    • pp.287-293
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    • 2011
  • This paper investigates the applicability of a piezoelectric cantilever for energy supply of wireless sensor node used in structural health monitoring of bridges. By combining the constitutive equation of piezoelectric material and the dynamic equation of cantilever structure, the coupled governing equation for cantilever equipped piezoelectric patches has been addressed in matrix form. Forced excitation tests were carried out to validate the numerical model and to investigate the power output characteristics of the energy harvester. From the numerical simulation based on the measured bridge accelerations under KTX, Saemaul, Mugunghwa trains, the peak powers generated from the device were found to be 28.5 mW, 0.65 mW, 0.51 mW respectively. It is revealed from the results that bridge vibrations caused by moving loads is not a practical source for energy harvesting because of its low acceleration level, low frequency and short duration.

Experimental Evaluation of Direct Measurement for Excitation Forces Acting on the Hard-points of Suspension System to Predict Road-noise Performance (로드노이즈 성능 예측을 위한 현가장치 하드포인트의 가진력 직접 측정법에 대한 실험적 평가)

  • Kang, Yeon June;Kim, Heesoo;Song, David P.;Ih, Kang-Duck;Kim, HyoungGun
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.25 no.3
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    • pp.184-190
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    • 2015
  • NVH engineering has become a hot issue due to radical technology changes and development in automotive industry since customers' expectations and needs for their vehicle is taken to a higher level. However, the source identification and quantification of the road noise within a vehicle is still not at the level where it needs to be to meet their expectations due to its' complex transfer path and difficulties in path optimization. The primary focus of this research is on direct force obtaining method at suspension hard points using suspension test rig. Directly obtained forces at suspension to body mounting points are critical and crucial for determining the effects of design changes of the suspension has on road noise performance. Direct force obtaining method has its limitation in sensor installation within an actual vehicle therefore, many has been indirectly calculating forces using full matrix inversion method or dynamic stiffness method. In this study, to circumvent this limitation, a suspension rig is used. Then, the suspension rig is verified through a comparative analysis of its dynamic behavior between the actual vehicle by cleat test on chassis dynamometer.