• 폴리머
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• 제31권3호
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• pp.247-254
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• 2007

본 연구에서는 폐수 중에 함유된 황산이온을 전기투석 방법으로 회수하기 위하여 불균질 음이온교환막을 압출성형 방법으로 제조하였다. 불균질 음이온교환 막의 함수율, 이온교환용량 및 이온수송수는 이온교환 수지의 함량이 증가함에 따라 증가하였고 전기저항은 감소하였다. 또한 불균질 음이온교환막의 인장강도는 이온교환 수지의 함량이 증가함에 따라 감소하였으며 LLDPE막의 경우 인장강도는 수지의 함량이 30 wt%일 때 가장 높게 나타났다. 함수율은 이온교환 수지의 함량이 증가함에 따라 증가하였으며, 불균질 이온교환막의 이온수송수는 최대 0.86 이었고, 전기저항 값은 50 wt% 수지 함량의 LDPE 막이 $46.5{\Omega}{\cdot}cm^2$로 가장 높게 나타났다. 한편 제조한 막의 황산이온에 대한 전기투석 운전 결과 전류효율은 황산농도 0.5 mol/L, 전류밀도 $125 mA/cm^2$에서 가장 높게 나타났다.

• Bulletin of the Korean Chemical Society
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• 제24권9호
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• pp.1324-1328
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• 2003

The simultaneous determination of anions ($SO_4 ^{2-},\;Cl^-,\;and\;NO_3^-$) and cations ($Na^+,\;NH^{4+},\;K^+,\;Mg^{2+},\;and\;Ca^{2+}$) in natural water obtained by Nakdong River waters system in Korea were performed by ion-exclusion/cationexchange chromatography with conductimetric detection. The stationary phase was a polymethacrylate-based weakly acidic cation-exchange resin column in the $H^+$-form and a weak-acid eluent. When using only a 1.4 mM sulfosalicylic acid/6 mM 18-crown-6 ether as an eluent, good resolution of both anions and cations, minimum time required for the separation, and satisfactory detection sensitivity were obtained in a reasonable time. The method was successfully applied to the simultaneous determination of anions and cations in natural waters.

• 대한화학회지
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• 제41권11호
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• pp.612-638
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• 1997

모나자이트광 속에 포함되어 있는 회토류 원소들을 이온교환수지를 이용하여 분리 회수 하는 방법에 관해 연구하였다. 이온교환수지로는 양이온교환수지와 음이온교환수지를 사용하고, 용리액으로는 EDTA, DTPA, IMDA, Ln-EDTA 용액을 사용하였으며, 양이온교환수지는 retaining 이온 곧 $H^+, Zn^{2+}, Fe^{3+}, Al^{3+}, Cu^{2+}, NH^+_4$으로 치환된 수지를 사용하였다. 음이온교환수지는 EDTA로 치환된 수지에 Ln-EDTA착물을 흡착시켜 분리하였다. 여러 가지 회토류 원소 중에서 선택적으로 한 원소만 분리하기 위해 용리액으로 Ln-EDTA를 사용하였으며, 수지통의 크기 변화와 여러 가지 용리형태의 메카니즘, 그리고 다량의 회토류 원소를 분리 회수하는 방법 등에 관해 연구하였다.

• 한국응용과학기술학회지
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• 제36권4호
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• pp.1088-1095
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• 2019

CKD 추출액은 시멘트공정에서 발생한 폐기물인 CKD를 시멘트 원료로 재사용하기 위해 공정 방해물질로 작용하는 KCl을 추출한 폐수이며, 폐수처리시설 증설 등의 문제로 추출액 무방류 및 이를 재이용하고자 하였다. 이온교환법을 적용하여 KCl을 제거한 결과, 이온교환 후 추출액의 pH는 12.7에서 pH 2 미만으로 감소하였으며 양이온교환수지의 H⁺가 이온교환을 거쳐 추출액에 용해되었음을 확인하였다. 이온교환의 선택성에 의해 Ca²⁺, K⁺ 순서로 제거되었으며, K⁺ 이온을 제거하기 위해 접촉시간의 증가가 필요함을 판단하였다. 이온교환수지와 직접접촉시간이 약 6배 높은 접촉시간을 갖는 회분식장치에서 연속흐름식장치 대비 4배 높은 K⁺ 제거 효율을, 7배 높은 Cl^- 제거 효율을 확인하였다. 양이온교환수지의 H⁺가 음이온교환수지의 OH^- 대비 1.2배 빠른 교환속도를 가짐을 추출액 pH 변화를 통해 확인하였다.

• Korean Chemical Engineering Research
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• 제56권3호
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• pp.361-369
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• 2018

A manufacturing method has been devised to prepare novel heterogeneous cation exchange membranes by mixing ethylene vinyl acetate (EVA) copolymers with a commercial cation exchange resin. Optimum material characteristics, mixture ratios and manufacturing conditions have been worked out for achieving favorable membrane performance. Ion exchange capacity, electrical resistance, water uptake, swelling ratio and tensile strength properties were measured. SEM analysis was used to monitor morphology. Effects of vinyl acetate (VA) content, melt index (MI) and ion exchange resin content on properties of heterogeneous cation exchange membranes have been discussed. An application test was carried out by mounting a selected membrane in a membrane capacitive deionization (MCDI) system to investigate its desalination capability. 0.92 meq/g of ion exchange capacity, $8.7{\Omega}.cm^2$ of electrical resistance, $40kgf/cm^2$ of tensile strength, 19% of swelling ratio, 42% of water uptake, and 56.4% salt removal rate were achieved at best. VA content plays a leading role on the extent of physical properties and performance; however, MI is important for having uniform distribution of resin grains and achieving better ionic conductivity. Overall, manufacturing cost has been suppressed to 5-10% of that of homogeneous ion exchange membranes.

• 품질경영학회지
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• 제17권2호
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• pp.64-69
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• 1989

This paper aims at analyzing the process capability and at determining an optimal condition by experimental designs using the 2-way classification with repitition in order to maintain lower Nacl content and to refine both of a very small quantity of fatty acid and various magnetic ions in the glycerin to use ion exchange resin treatment process. An optimal condition of each level combination in both of passing temperature of cation exchange resin($A_1$, $A_2$, $A_3$) and of anion exchange resin($B_1$, $B_2$, $B_3$) is $A_3B_3$. The process capability index is improved from 0.63 to 1.40 and is interpreted as a desirable state. This analysis of process capability by experimental designs will contribute to improving productivity and quality of products.

• 상하수도학회지
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• 제11권1호
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• pp.42-52
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• 1997

The affection of activated carbon on the dissolved aluminum ion in drinking water has been observed. In addition, the aluminum ion removal capability of activated, alumina, chitosan, and ion exchange resin have been investigated. Experimental results indicated that the coal based activated carbon released considerable amount of aluminum ion to the water while coconut shell based activated carbon didn't. However the release was not continuous. Activated alumina didn't show any recognizable removal capability for aluminum ion in water. Particulate chitosan has removed aluminum ion although dissolved chitosan has not. However it need to development a regeneration process for chitosan to be an effective mean for aluminum ion removal. Ion exchange resin showed a reliable aluminum ion removal capability. The ion exchange capacity was 2.63 meq/g resin for the aluminum ion in drinking water.

• Journal of the Korean Wood Science and Technology
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• 제15권4호
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• pp.12-17
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• 1987

To extract arabinogalactan from larch (Larix Leptolepis), chips immersed with water(20-$90^{\circ}C$) for 1hr, were defiberized by refiner. The liquors were recovered and purified to pure arabinogalactan by ion exchange resin(IRC-50 a. IR-45) or MgO. Additionally the optimal condition in purification with MgO was also investigated. 1. The amounts of solids(crude sugars) and pure arabinogalctan in solids are 8.6-11.3% and 7.3-8.5%(raw material = 100), respectively. 2. Phenolic materials in crude sugars are removed up to 96-89% by ion exchange resin and 94-88% by MgO, while recovery yields of pure arabinogalactan are 81-75% on purification with ion exchange resin and 91-87% on purification with MgO. 3. The optimal conditions of purification with MgO are the addition of 35mg MgO/0.5g of crude sugars, 45 minutes at $70^{\circ}C$, or 25 mg MgO, 30 minutes at $85^{\circ}C$.

• 한국환경농학회지
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• 제19권2호
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• pp.188-190
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• 2000

15년생 일본잎갈나무 조림지에서 약도, 중도, 강도의 간벌을 실시하고 약 1년이 경과한 다음 이온교환수지봉지를 이용하여 1년 동안 토양 내 유효태 질소 농도의 변화를 측정하였다. 측정시기에 따라 약간의 차이는 있었으나, 간벌이 토양 내 총 유효태 질소의 농도에는 영향을 미치지 않는 것으로 나타났다. 한편 토양 질소 유효도는 겨울에 비하여 여름과 가을에 높게 나타났다.

• 한국환경과학회지
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• 제7권5호
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• pp.697-705
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• 1998

$Pb^{2+}$ removal capacity and initial $Pb^{2+}$ removal rate were compared between non-biomaterials (granular activated carbon, powdered activated carbon, ion exchange resin, zeolite) and biomaterials (activated sludge, Aureobasidium pullulans, Saccharomyces cerevisiae). The $Pb^{2+}$ removal capacity of biomaterials were greater than that of non-biomaterials, generally. The $Pb^{2+}$ removal capacities of non-biomaterials and biomaterials were shown on the order of ion exchange resin ＞ zeolite ＞ granular activated carbon ＞ powdered activated carbon and A. pullulans ＞ S. cerevisiae ＞ activated sludge, respectively. In the initial $Pb^{2+}$ removal rate, the non-biomaterials showed powdered activated carbon ＞ granular activated carbon ＞ zeolite ＞ ion exchange resin and the biomaterials showed A. pullulans ＞ activated sludge ＞ S. cerevisiae. Comparing the $Pb^{2+}$ removal capacity and initial $Pb^{2+}$ removal rate of activated sludge with those of other non-biomaterials and biomaterials, activated sludge may have an availability on the removal of heavy metal ions by the economical and pratical aspects.