• International Journal of Automotive Technology
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• v.6 no.4
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• pp.323-332
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• 2005

A cylindrical constant volume combustion chamber was used to investigate the flow characteristics at the spark electrode gap and the combustion characteristics of a homogeneous charged methane-air mixture under various overall charge pressures, excess air ratios and ignition times. The flow characteristics, including the mean velocity and turbulence intensity, were analyzed with a hot wire anemometer. Combustion pressure development measured by piezoelectric pressure transducer, a flame propagation image acquired by ICCD camera and exhaust emissions measured by 2-valve gas chromatography were used to investigate effects of initial pressures, excess air ratios and ignition times on the combustion characteristics. It was found that the mean velocity and turbulence intensity had the maximum value around 200-300 ms and then decreased gradually to a near-zero value after 3000 ms and that the combustion duration was shorten and the flame speed and laminar burning velocity had the highest value under the condition of an excess air ratio of 1.1, an overall charge pressure of 0.15 MPa and an ignition time of 300 ms in the present study. The $CO_2$ concentration was proportional to the ignition time and overall charge pressure, the $CO_2$ concentration was proportional to the excess air ratio, and the UHC concentration was inversely proportional to the ignition time and overall charge pressure.

• Korean Chemical Engineering Research
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• v.57 no.2
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• pp.198-204
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• 2019

For the removal of carbon dioxide from the chemical process, a chemical absorption method is typically used industrially. Development of new processes for the removal of carbon dioxide by the chemical absorption method has been developing new absorbents by using various absorbents. Thermodynamic data of the sorbent mixture in the new process design using hybrid absorbent is essential to reduce the equipment cost and operating costs of the process. In this study, densities of water+diisopropanolamine (DIPA), DIPA+MDEA(Methyldiethanolamine) binary systems and Water+DIPA+MDEA ternary system were measured over the full range of composition at temperatures from 303.15 K to 333.15 K by using an Anton Paar digital vibrating tube densimeter (DMA4500). The experimental excess volumes have been obtained from the experimental density results and have been fitted using the Redlich-Kister-Muggianu expression. The parameters obtained from the binary excess volume data were used for the correlation of ternary system with one additional ternary parameter for each isotherm. All investigated binary and ternary systems are completely miscible, because the values of excess volume are negative under the examined conditions.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.19 no.10
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• pp.1075-1082
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• 2009

Using GIS data of C-si as basic data when making noise map of road traffic, we estimated exactly the noise excess areas and consequently suggested the population and the area exposed to road traffic noise accurately. We made 3D noise map to assess regional distribution of noise quantitatively. The noise map consists of noise prediction model based on data base such as traffic volume and speed changes for estimating quantitatively the noise and 3D urban space model which includes locations of noise sources, 3D buildings, topography and roads. We made noise standard map according to land use conditions and compared this map to road traffic noise map, and consequently made excess noise map. Using excess noise map, we assessed areas which exceed environmental noise level standards and noise guidelines quantitatively and effectively through GIS spatial analysis, and consequently more accurate noise exposed area and noise exposed population could be estimated. To show buildings' outer walls noise exposure, we analyzed 3D urban noise distributions using 3D-analysis of GIS.

• Physical Therapy Korea
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• v.14 no.3
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• pp.1-8
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• 2007

The purpose of this study was to determine whether aromatherapy massages with manual lymph drainage (MLD) are significantly more effective than sham massages with MLD in reducing edematous limb volume in lymphedema. This study was performed on 46 patients who had developed unilateral upper or lower lymphedema. Twenty-three patients served as the experimental group and were treated with complex decongestive physiotherapy (CDP) applications including aroma massages with MLD, multi layered compression bandages, remedial exercises and skin care. Twenty-three patients in the control group were treated with CDP applications including sham massages with MLD, bandages, exercises and skin care. Patients undergo a therapy program once a day; 5 days a week for 2 weeks. Percentage excess volume (PEV) and body mass index (BMI) were recorded before and after treatment. PEV and BMI were significantly decreased before and after treatment in the experimental as well as in the control groups (p<.05). However, the percentage excess volume and BMI were not significantly improved after treatment between the two groups (p>.05). This study there suggests that aroma massages is not effective in the edema of patients with lymphedema.

• Geomechanics and Engineering
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• v.23 no.6
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• pp.561-573
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• 2020

The creep and consolidation behaviors of clays subjected to thermal cycles are of fundamental importance in the application of energy geostructures. This study aims to numerically investigate the physical mechanisms for the temperature-triggered volume change of saturated clays. A recently developed thermodynamic framework is used to derive the thermo-mechanical constitutive model for clays. Based on the model, a fully coupled thermo-hydro-mechanical (THM) finite element (FE) code is developed. Comparison with experimental observations shows that the proposed FE code can well reproduce the irreversible thermal contraction of normally consolidated and lightly overconsolidated clays, as well as the thermal expansion of heavily overconsolidated clays under drained heating. Simulations reveal that excess pore pressure may accumulate in clay samples under triaxial drained conditions due to low permeability and high heating rate, resulting in thermally induced primary consolidation. Results show that four major mechanisms contribute to the thermal volume change of clays: (i) the principle of thermal expansion, (ii) the decrease of effective stress due to the accumulation of excess pore pressure, (iii) the thermal creep, and (iv) the thermally induced primary consolidation. The former two mechanisms mainly contribute to the thermal expansion of heavily overconsolidated clays, whereas the latter two contribute to the noticeable thermal contraction of normally consolidated and lightly overconsolidated clays. Consideration of the four physical mechanisms is important for the settlement prediction of energy geostructures, especially in soft soils.

• Korean Chemical Engineering Research
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• v.47 no.6
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• pp.755-761
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• 2009

To a first approximation, phase behavior of a system becomes increasingly skew in proportion to the boiling point difference of system-forming constituents. Therefore, phase behavior data of a system of a large boiling point difference are to be experimentally measured for thorough understanding of the thermodynamic characteristics of such system. In this work, isobaric vapor-liquid equilibrium of a mixture consisting of toluene and cresol, which shows a large boiling point difference of nearly $100^{\circ}C$ and is consequently expected to be considerably nonideal, was measured by using a recirculating equilibrium cell at various subatmospheric pressures ranging from 10 kPa to 60 kPa. The measured VLE data were correlated with NRTL and UNIQUAC models in a satisfactory manner and the accompanying thermodynamic consistency test represented soundness of the measurements. In addition, the excess molar volume of the mixture was also measured with a vibrating densitometer and correlated with a Redlich-Kister polynomial. A negative excess volume prevailed over the whole concentration range, which indicates a favorable attraction between toluene and cresol isomers and results in an extensive miscibility.

• Korean Chemical Engineering Research
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• v.58 no.2
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• pp.257-265
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• 2020

Densities (ρ) for binary mixtures of ethanol (1) + diisopropyl ether (DIPE) or cyclohexane or alkane (C₆-C₉) (2) were measured at 298.15 K, 308.15 K and 318.15 K. The excess molar volume (V^E_m) of binary mixtures was calculated using ρ data and correlated with Redlich-Kister polynomial equation. The V^E_m values for binary mixtures of ethanol (1) + cyclohexane or n-alkane (C₆-C₉) (2) were positive, whereas for ethanol (1) + DIPE (2) these were negative. The magnitude of V^E_m values follows the order: cyclohexane > n-nonane > n-octane > n-heptane > n-hexane > DIPE. The V^E_m values have been interpreted qualitatively and also quantitatively in terms of Flory-Treszczanowicz-Benson (FTB) model and Prigogine-Flory-Patterson (PFP) theory. The values V^E_m predicted using FTB model agree well with experimental V^E_m values at all mole fractions. But the PFP theory describes well V^E_m data in ethanol-rich region (x₁ > 0.5) for all binary mixtures and is able to predict the sign of V^E_m vs x₁ curve for ethanol-lean region (x₁ < 0.5) except for ethanol (1) + nonane (2) mixtures.

• Journal of the Korean Applied Science and Technology
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• v.35 no.1
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• pp.157-162
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• 2018

The partial molar volumes of an antidepressant in Halobacteriun Halobium and in suspensions of several lipids have been determined at $25^{\circ}C$ it using a excess volume dilatometer. The potency of general antidepressant, Fluoxetine has long been known to correlate with lipid solubility. Denaturations of the vesicle, which is a sole membrane protein in the purple membrane of Halobacteriun Halobium, were studied by absorption changes at 280 nm and fluorescence changes at 330 nm with excess volume dilatometer. The 1H NMR analysis of viscous polymer solutions by diffusion interchange is the important step by measurement. The partial molar volume and particle size of Fluoxetine in Halobacteriun Halobium were measured to be positive. An antidepressant can prevent diseases that produce a variety of cognitive and mental symptoms based on low morale and depression, resulting in poor daily performance.

• Korean Chemical Engineering Research
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• v.56 no.2
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• pp.204-211
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• 2018

In this study, densities of water + N-Methyldiethanolamine (MDEA), Water + 2-Amino-2-Methyl-1-Propanol (AMP), MDEA + AMP binary systems and Water+MDEA+AMP ternary system were measured over the full range of composition at temperatures from 303.15 K to 333.15 K by using an Anton Paar digital vibrating tube densimeter (DMA4500). The experimental excess volumes have been obtained from the experimental density results and have been fitted using the Redlich-Kister-Muggianu expression. The parameters obtained from the binary excess volume data were used for the correlation of ternary system with one additional ternary parameter for each isotherm. All investigated binary and ternary systems are completely miscible, because the values of excess volume are negative under the examined conditions.

• Journal of the Korean Applied Science and Technology
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• v.37 no.3
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• pp.516-525
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• 2020

The densities of aqueous solutions of the amphiphile 2-(2-hexyloxyethoxy)ethanol (C₆E₂) were measured at 279.15 K and 282.15 K by vibrating-tube densitometry. Then using the density data of the binary C₆E₂ (1)/water(2) system, the excess volumes and partial molar volumes were determined at various compositions. Excess volume V^E exhibits negative deviation for the whole region of composition, which implies relatively stronger attraction between molecules. At the C₆E₂ mole fraction of around 0.45, V^E was at its minimum. Partial molar volume ${\bar{V}}_1$ increases monotonously with the mole fraction x₁(=x) and ${\bar{V}}_2$ decreases with x. Any particular point in ${\bar{V}}_1$ and ${\bar{V}}_2$, which may point to molecular association, was unobserved.