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http://dx.doi.org/10.9713/kcer.2020.58.2.257

Application of Flory-Treszczanowicz-Benson model and Prigogine-Flory-Patterson theory to Excess Molar Volume of Binary Mixtures of Ethanol with Diisopropyl Ether, Cyclohexane and Alkanes (C6-C9)  

Kashyap, Pinki (Department of Chemical Engineering, Deenbandhu Chhotu Ram University of Science and Technology)
Rani, Manju (Department of Chemical Engineering, Deenbandhu Chhotu Ram University of Science and Technology)
Tiwari, Dinesh Pratap (Department of Chemical Engineering, Deenbandhu Chhotu Ram University of Science and Technology)
Park, So-Jin (Department of Chemical Engineering and Applied Chemistry, College of Engineering, Chungnam National University)
Publication Information
Korean Chemical Engineering Research / v.58, no.2, 2020 , pp. 257-265 More about this Journal
Abstract
Densities (ρ) for binary mixtures of ethanol (1) + diisopropyl ether (DIPE) or cyclohexane or alkane (C6-C9) (2) were measured at 298.15 K, 308.15 K and 318.15 K. The excess molar volume (VEm) of binary mixtures was calculated using ρ data and correlated with Redlich-Kister polynomial equation. The VEm values for binary mixtures of ethanol (1) + cyclohexane or n-alkane (C6-C9) (2) were positive, whereas for ethanol (1) + DIPE (2) these were negative. The magnitude of VEm values follows the order: cyclohexane > n-nonane > n-octane > n-heptane > n-hexane > DIPE. The VEm values have been interpreted qualitatively and also quantitatively in terms of Flory-Treszczanowicz-Benson (FTB) model and Prigogine-Flory-Patterson (PFP) theory. The values VEm predicted using FTB model agree well with experimental VEm values at all mole fractions. But the PFP theory describes well VEm data in ethanol-rich region (x1 > 0.5) for all binary mixtures and is able to predict the sign of VEm vs x1 curve for ethanol-lean region (x1 < 0.5) except for ethanol (1) + nonane (2) mixtures.
Keywords
Excess molar volume; Ethanol; DIPE; Alkanes; FTB; PFP;
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Times Cited By KSCI : 2  (Citation Analysis)
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