• 한국전기전자재료학회논문지
• /
• 제22권1호
• /
• pp.74-80
• /
• 2009

In the structure of ITO/N,N'-diphenyl-N,N' bis (3-methylphenyl)-1,1'-biphenyl-4,4'-diamine(TPD)/tris (8-hydroxyquinoline)aluminum($Alq_3$)/Al device, we studied the efficiency improvement of organic light-emitting diodes due to variation of deposition rate of hole transport layer (TPD) materials using hole-size of crucible boat. The thickness of TPD and $Alq_3$ was manufactured 40 nm, 60 nm, respectively under a base pressure of $5{\times}10^{-6}$ Torr using a thermal evaporation. The $Alq_3$ used for an electron-transport and emissive layer were evaporated to be at a deposition rate of $2.5\;{\AA}/s$. When the deposition rate of TPD increased from 1.5 to $3.0\;{\AA}/s$, we studied the efficiency improvement of TPD using the hole-size of crucible is 1.0 mm. When the deposition rate of TPD is $2.5\;{\AA}/s$, we found that the average roughness is rather smoother, the luminous efficiency the external quantum efficiency is superior to the others. Compared to the two from the devices made with the deposition rate of TPD is $2.0\;{\AA}/s$ and $3.0\;{\AA}/s$, the external quantum efficiency was improved by four-times and two-times, respectively.

• 폴리머
• /
• 제33권5호
• /
• pp.407-412
• /
• 2009

유기발광소자(OLED)에서 정공 수송층(hole injection layer, HIL)으로 사용되는 N,N'-di-1-naphthyl-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine (NPD)가 정공 주입층(hole injection layer HIL)으로 사용된 PEDOT-PSS 층 위로 진공 증착되었다. PEDOT-PSS 층은 ITO 유리 위에 스핀 코팅되어 제조되었다. 또한, NPD와 $C_{60}$의 공증착에 의해 $C_{60}$이 약 10 wt% 도핑된 NPD-$C_{60}$ 층을 제조하였으며, AFM과 XRD를 이용하여 NPD-$C_{60}$ 박막의 모폴로지 특성을 관찰하였다. 다층 소자를 제조하여 J-Y, L-V 및 전류 효율 특성이 고찰되었다. $C_{60}$박막은 국부적인 결정성 구조를 가지고 있으나, NPD-$C_{60}$ 박막에서는 $C_{60}$ 분자가 균일하게 분산되어 $C_{60}$의 결정성 구조가 확인되지 않았다. 또한, $C_{60}$의 도핑에 의해서 박막의 표면이 균일해지는 것을 확인하였으며, 박막 내의 전류 밀도가 증가됨을 확인하였다. NPD-$C_{60}$ 박막을 이용하여 ITO/PEDOT-PSS/NPD-$C_{60}/Alq_3$/LiF/Al 다층 소자를 제조하였을 때, 소자의 휘도 측면에서 약 80% 향상 효과가 있었으며, 소자 효율 측면에서도 약 25%의 향상을 기대할 수 있었다.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2009년도 하계학술대회 논문집
• /
• pp.310-310
• /
• 2009

In the two structure of ITO/N,N'-diphenyl-N,N' bis (3-methylphenyl)-1,1'-biphenyl-4,4'-diamine(TPD)/R-H : R-D/Al device, ITO/Amorphous Fluoropolymers/TPD/R-H : R-D/LiF/Al device. we studied the effect of organic materials defending on the electrical characteristics of red OLEDs. The thickness of TPD and R-H : R-D was manufactured 40 nm, 60 nm, respectively under a base pressure of $5\times10^{-6}$Torr using a thermal evaporation. The AF used for an hole-injection is the thickness of 0.5 [nm] and the LiF used for an electron-injection is the thickness of 0.5 [nm]. Compared to the two from the devices made with the hole injection and without hole injection We found that the luminous efficiency and the external quantum efficiency are improved a fact of one- hundred, two, respectively.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2005년도 춘계학술대회
• /
• pp.196-200
• /
• 2005

In this work, we investigated simple Aㅣ/TCO/a-Si:H(n)/c-Si(p)/Al hetero-junction solar cells prepared by low temperature processes, unlike conventional thermal diffused c-Si solar cells. a-Si:H/c-Si hetero-junction solar cells are processed by low temperature deposition of n-type hydrogenated amorphous silicon (a-Si:H) films by plasma-enhanced chemical vapor deposition on textured and flat p-type silicon substrate. A detailed investigation was carried out to acquire optimization and compatibility of amorphous layer, TCO (ZnO:Al) layer depositions by changing the plasma process parameters. As front TCO and back contact, ZnO:Al and AI were deposited by rf magnetron sputtering and e-beam evaporation, respectively. The photovoltaic conversion efficiency under AMI.5 and the quantum efficiency on $1cm^2$ sample have been reported. An efficiency of $12.5\%$ is achieved on hetero-structure solar cells based on p-type crystalline silicon.

• 한국전기전자재료학회논문지
• /
• 제22권12호
• /
• pp.1039-1044
• /
• 2009

Red color OLED has been fabricated by the doping method apply to CBP using co-evaporation, GDI4349 of phosphorescent dopant, and rubrene of fluorescent dopant. The OLED structure are multi-layer of ITO(150 nm)/ELM_HIL(50 nm)/ELM_HTL(30 nm)/CBP : Rubrene, GDI4349 (30 nm)/BAlq (30 nm)/LiF(0.7 nm)/Al (100 nm). Accomplished best result at 3 vol.% of rubrene when the OLEDs were made of 1, 3, 5, 7, 9 vol.% doped rubrene. The highest efficiency of 7.2 cd/A was resulted at 8 vol.% of GDI4349 when the OLEDs were made among 5, 8, 11, 14 vol.% of GDI4349. Obviously, the best concentration of rubrene at 3 vol.% and changing GDI4349 concentration to 5, 8, 11, 14 vol.% OLED dramatically enhanced characteristic of resulted 10.7 cd/A at 8 vol.% of GDI4349. This result would understand to analyse as the emission efficiency increases by energy transport efficiency increase using GDI4349 energy transfer when rubrene absorbs the energy from CBP of fluorescences host.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
• /
• pp.662-662
• /
• 2013

Over the last several decades, innovative light-harvesting devices have evolved to achieve high efficiency in solar energy transfer. Research on the mechanisms for plasmon resonance is very desirable to overcome the conventional efficiency limits of photovoltaics. The influence of localized surface plasmon resonance on hot electron flow at a metal-semiconductor interface was observed with a Schottky diode composed of a thin silver layer on $TiO_2$. The photocurrent is generated by absorption of photons when electrons have enough energy to travel over the Schottky barrier and into the titanium oxide conduction band. The correlation between the hot electrons and the surface plasmon is confirmed by matching the range of peaks between the incident photons to current conversion efficiency (IPCE, flux of collected electrons per flux of incident photons) and UV-Vis spectra. The photocurrent measured on Ag/$TiO_2$ exhibited surface plasmon peaks; whereas, in contrast to the Au/$TiO_2$, a continuous Au thin film doesn't exhibit surface plasmon peaks. We modified the thickness and morphology of a continuous Ag layer by electron beam evaporation deposition and heating under gas conditions and found that the morphological change and thickness of the Ag film are key factors in controlling the peak position of light absorption.

• 한국전기전자재료학회논문지
• /
• 제26권9호
• /
• pp.701-706
• /
• 2013

We have focused on the conversion efficiency of CIGS thin film solar cell prepared by co-evaporation method as well as the optimization of process condition. The total thickness of back electrode was fixed at 1 ${\mu}m$ and the structural, electric and optical properties of CIGS thin film were investigated by varying the thickness of Mo:Na bottom layer from 0 to 500 nm. From the experimental results, the content of Na was appeared as 0.28 atomic percent when the thickness of Mo:Na layer was 300 nm with compactly densified plate-shape surface morphology. From the XRD measurements, (112) plane was the strongest preferential orientation together with secondary (220) and (204) planes affecting to the crystallization. The lowest roughness and resistivity were 2.67 nm and 3.9 ${\Omega}{\cdot}cm$, respectively. In addition, very high carrier density and hole mobility were recorded. From the optimization of Mo:Na layer, we have achieved the conversion efficiency of 9.59 percent.

• 에너지공학
• /
• 제18권2호
• /
• pp.93-100
• /
• 2009

습식압축으로 압축소요동력을 줄이고 재생기로 배기가스 에너지를 회수함으로써 열효율을 향상시킬 수 있는 습식압축 재생 브레이튼 사이클에 대하여 엑서지 해석을 수행하였다. 해석모델을 통하여 시스템의 엑서지 효율과 요소별 엑서지 파괴비 및 배기가스로 인한 엑서지 손실비에 미치는 압력비와 물분사율의 영향을 조사하였다. 전형적인 운전조건에 대한 계산 결과 습식압축 재생 가스터빈 사이클에 의하여 엑서지 효율을 상당히 향상시킬 수 있음을 확인하였다. 물 분사 효과는 배기가스의 엑서지 손실의 감소와 출력 동력의 증가로 나타난다.

• 동력기계공학회지
• /
• 제18권5호
• /
• pp.88-93
• /
• 2014

In this paper, the performance analysis of condensation and evaporation capacity, turbine work and efficiency of the OTEC power system using vapor-liquid Ejector is presented to offer the basic design data for the operating parameters of the system. The working fluid used in this system is $CO_2$. The operating parameters considered in this study include the vapor quality at heat exchanger outlet, pressure ratio of ejector and inlet pressure of low turbine, mass flow ratio of separator at condenser outlet. The main results were summarized as follows. The efficiency of the OTEC power cycle has an enormous effect on the mass flow ratio of separator at condenser outlet. With a thorough grasp of these effects, it is possible to design the OTEC power cycle proposed in this study.

• 한국진공학회지
• /
• 제17권3호
• /
• pp.211-214
• /
• 2008

Metal organic chemical vapor deposition (MOCVD)를 이용하여 사파이어 기판 위에 405 nm의 파장을 갖는 GaN light-emitting diode (LED)를 제작하였다. LED의 InGaN 활성층에서 생성되어 칩의 후면으로 향하는 광자를 전면으로 반사시키기 위하여, 사파이어 기판 후면에 반사막을 증착하였다. 반사막으로는 Al을 사용하였으며, 사파이어 기판에 대한 Al 박막의 접착력을 개선하기 위하여 사파이어 기판 후면에 Ti를 먼저 증착한 후에 Al을 증착하였다. Ti-Al 반사막을 채용한 결과, 광추출 효율이 52 % 향상되었다.