• Title/Summary/Keyword: Ethylenediaminetetraacetic Acid

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The Study of Effect of EDTA(Ethylenediaminetetraacetic acid) to the defected Ni-Cr-Fe Alloy in the Steam Generator Chemical Cleaning of the Nuclear Power Plant (원전 SG 화학세정 환경에서 EDTA가 결함 Ni-Cr-Fe 합금에 미치는 영향 연구)

  • Gwon, Hyeok-Cheol;Lee, Han-Cheol;Seong, Gi-Bang
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2013.05a
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    • pp.117-118
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    • 2013
  • 증기발생기 화학세정 모사 장치를 이용하여 고농도 화학세정(EPRI/SGOG) 용액인 EDTA(20%)가 인위적으로 제작한 결합 시편에 미치는 영향 평가를 수행하였다. 평가 방법은 세정 전 후 표면 산화막 성분, ECT 분석값 비교, 증기발생기 구성 재료 부식률를 이용하였다. 화학세정 전후 부식률은 A508은 $8.023{\mu}m$, Alloy 600(HTMA)은 $0.007{\mu}m$이며 갈바닉 시편의 경우 $63.193{\mu}m$로 모두 부식 허용치 이내이다. 표면 산화막 성분 및 ECT 분석값 역시 변함이 없었다. 이와 같은 결과로 화학세정 용액인 EDTA는 결함 튜브에 미치는 영향이 없는 것으로 판단된다.

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Determination of Silver with Mercaptans (III). Amperometric Titration of Silver with 2-Mercaptothiazoline (Mercapto 화합물에 의한 은의 정량 (제3보). 2-Mercaptothiazoline에 의한 은의 전류적정)

  • Young Gu Ha
    • Journal of the Korean Chemical Society
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    • v.17 no.6
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    • pp.439-443
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    • 1973
  • 2-Mercaptothiazoline is very sensitive reagent for silver, which have been used for highly selective amperometric determination of silver. A method is described for the determination of micro-quantity of silver by amperometric titration with 2-mercaptothiazoline in ammonical solution. Direct titration of milligram amount of silver (0.05∼1.00mg) is possible in the presence of a number of foreign ions in ammonical solution containing ethylenediaminetetraacetic acid as masking agent under atmosphere. The interfering elements are gold and platinum. The milligram amounts of silver can be determined by the proposed method within an error ${\pm}$5%.

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Synthesis and Properties of Ca8Gd2(PO4)6O2 Nano-Crystalline Structures

  • Bharat, L. Krishna;Yu, Jae Su
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.286.1-286.1
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    • 2013
  • Nowadays, the glare towards the light-emitting diode (LED) lighting source has much attention due to its eco-friendly nature, reduced energy consumption, and low CO2 emission. LEDs can show versatile colors by changing the composition ratio of semiconductors. Phosphors re-emit light by absorbing light from LED, which is the key factor for emission. The endeavor to make replica of natural white light is increasing day by day. Industrially, blue LED chip crowned with a yellow phosphor coated lens gives low quality white light. Newly, many researchers are introducing modern approaches, adding red phosphor to the yellow phosphor to increase the quality of white light. Here, we synthesized structurally and chemically stable europium doped oxyapatite Ca8Gd2(PO4)6O2 nano-crystalline structures by a hydrothermal method. The ultrafine structures were formed due to the effect of ethylenediaminetetraacetic acid, which is confirmed by the transmission electron microscope images. The structural properties were analyzed using the X-ray diffraction patterns.

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Pulsed Amperometric Detection of Metal Ions Complexing with EDTA in a Flow Injection System

  • 이준우;여인형;편종홍
    • Bulletin of the Korean Chemical Society
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    • v.18 no.3
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    • pp.316-318
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    • 1997
  • A general and universal detection method, which can be used in high performance liquid chromatography (HPLC) and flow injection analysis (FIA) system for the determination of any metal ions complexing with ethylenediaminetetraacetic acid (EDTA), is demonstrated. Pulsed amperometric detection scheme is applied in a flow-through thin layer electrochemical cell at an Au working electrode. Fluctuation of peak current level at the same flow rate of carrier solution is minimized at this solid working electrode, whereas not at a dropping mercury electrode. Removal of dissolved oxygen can be omitted with this detection method, which is a required step for cathodic detection methods. Also, a group of metal ions can be determined selectively and indirectly with this detection scheme.

EDTA-functionalized KCC-1 and KIT-6 mesoporous silicas for Nd3+ ion recovery from aqueous solutions

  • Ravi, Seenu;Zhang, Siqian;Lee, Yu-Ri;Kang, Kyoung-Ku;Kim, Ji-Man;Ahn, Ji-Whan;Ahn, Wha-Seung
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.210-218
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    • 2018
  • Ethylenediaminetetraacetic acid (EDTA)-functionalized KIT-6 and KCC-1 mesoporous silicas were prepared via post-synthesis grafting and examined for their ability to promote the recovery of rare earth metal ions such as $Nd^{3+}$ from an aqueous medium. The obtained adsorption isotherms were fitted to the Langmuir model, which gave a maximum adsorption of $Nd^{3+}$ ions of 109.8 and 96.5 mg/g for KIT-6-EDTA and KCC-1-EDTA, respectively, at $25^{\circ}C$ and pH 6. The adsorption kinetic profile of KIT-6 was faster than KCC-1. KIT-6 was also proved to be more stable against desorption under acidic regeneration conditions.

Smear layer removal by different chemical solutions used with or without ultrasonic activation after post preparation

  • Poletto, Daniel;Poletto, Ana Claudia;Cavalaro, Andressa;Machado, Ricardo;Cosme-Silva, Leopoldo;Garbelini, Cassia Cilene Dezan;Hoeppner, Marcio Grama
    • Restorative Dentistry and Endodontics
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    • v.42 no.4
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    • pp.324-331
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    • 2017
  • Objectives: This study evaluated smear layer removal by different chemical solutions used with or without ultrasonic activation after post preparation. Materials and Methods: Forty-five extracted uniradicular human mandibular premolars with single canals were treated endodontically. The cervical and middle thirds of the fillings were then removed, and the specimens were divided into 9 groups: G1, saline solution (NaCl); G2, 2.5% sodium hypochlorite (NaOCl); G3, 2% chlorhexidine (CHX); G4, 11.5% polyacrylic acid (PAA); G5, 17% ethylenediaminetetraacetic acid (EDTA). For the groups 6, 7, 8, and 9, the same solutions used in the groups 2, 3, 4, and 5 were used, respectively, but activated with ultrasonic activation. Afterwards, the roots were analyzed by a score considering the images obtained from a scanning electron microscope. Results: EDTA achieved the best performance compared with the other solutions evaluated regardless of the irrigation method (p < 0.05). Conclusions: Ultrasonic activation did not significantly influence smear layer removal.

Ionic Recognition with Quinone-Derivatized Calixarenes in Solution and at Self-Assembled Monlayers

  • Kim Hasuck;Kang Sun Kil;Chung Taek Dong
    • Journal of the Korean Electrochemical Society
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    • v.3 no.2
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    • pp.69-71
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    • 2000
  • Redox-active calix[4]arenes with carboxylic acid and disulfide groups were prepared and spontaneous deposition on silver and gold surfaces was observed. Owing to their unusual structure, the calix[4]arenes exhibit selective affinity fur alkaline earth metal ions in aqueous media. When annular ionophores are immobilized on the surface, voltammetric and spectroscopic studies show the entrapment of metal ions. Furthermore, it was possible to reversibly capture and remove the ions using strong chelating agents such as ethylenediaminetetraacetic acid (EDTA).

Prevention and Dissociation of the Platelet Aggregation in a Patient with EDTA-dependent Pseudothrombocytopenia by Supplementation of Kanamycin : A Case Report (EDTA 의존성 가성혈소판감소증 환아에서 가나마이신 보충에 의해 혈소판 응집을 예방할 수 있었던 1례)

  • Jeon, In-Sang;Yang, Sung Wan
    • Clinical and Experimental Pediatrics
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    • v.48 no.6
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    • pp.675-677
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    • 2005
  • Pseudothrombocytopenia is usually associated with anticoagulant ethylene diaminetetraacetic acid (EDTA). The platelet clumping that occurs in EDTA-dependent pseudothrombocytopenia (EDPT) can sometimes be prevented by the use of other anticoagulants such as heparin or sodium citrate. As an alternative, we used kanamycin before or after the withdrawal of EDTA-anticoagulated blood in a 6-year-old boy with EDPT. Kanamycin used supplementarily during the differentiation of EDPT effectively prevented platelet clumping.

Characterization of Endolysin LysECP26 Derived from rV5-Like Phage vB_EcoM-ECP26 for Inactivation of Escherichia coli O157:H7

  • Park, Do-Won;Park, Jong-Hyun
    • Journal of Microbiology and Biotechnology
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    • v.30 no.10
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    • pp.1552-1558
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    • 2020
  • With an increase in the consumption of non-heated fresh food, foodborne shiga toxin-producing Escherichia coli (STEC) has emerged as one of the most problematic pathogens worldwide. Endolysin, a bacteriophage-derived lysis protein, is able to lyse the target bacteria without any special resistance, and thus has been garnering interest as a powerful antimicrobial agent. In this study, rV5-like phage endolysin targeting E. coli O157:H7, named as LysECP26, was identified and purified. This endolysin had a lysozyme-like catalytic domain, but differed markedly from the sequence of lambda phage endolysin. LysECP26 exhibited strong activity with a broad lytic spectrum against various gram-negative strains (29/29) and was relatively stable at a broad temperature range (4℃-55℃). The optimum temperature and pH ranges of LysECP26 were identified at 37℃-42℃ and pH 7-8, respectively. NaCl supplementation did not affect the lytic activity. Although LysECP26 was limited in that it could not pass the outer membrane, E. coli O157: H7 could be effectively controlled by adding ethylenediaminetetraacetic acid (EDTA) and citric acid (1.44 and 1.14 log CFU/ml) within 30 min. Therefore, LysECP26 may serve as an effective biocontrol agent for gram-negative pathogens, including E. coli O157:H7.

The Preparation and Growth Mechanism of the Recovered Bi2Te3 Particles with Respect to Surfactants (회수된 Bi2Te3의 계면활성제에 따른 합성 및 성장 거동)

  • So, Hyeongsub;Song, Eunpil;Choa, Yong-Ho;Lee, Kun-Jae
    • Journal of Powder Materials
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    • v.24 no.2
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    • pp.141-146
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    • 2017
  • $Bi_2Te_3$ powders are recovered by wet chemical reduction for waste n-type thermoelectric chips, and the recovered particles with different morphologies are prepared using various surfactants such as cetyltrimethylammonium bromide (CTAB), sodium dodecylbenzenesulfonate (SDBS), and ethylenediaminetetraacetic acid (EDTA). When citric acid is added as the surfactant, the shape of the aggregated particles shows no distinctive features. On the other hand, rod-shaped particles are formed in the sample with CTAB, and sheet-like particles are synthesized with the addition of SDBS. Further, particles with a tripod shape are observed when EDTA is added as the surfactant. The growth mechanism of the particle shapes depending on the surfactant is investigated, with a focus on the nucleation and growth phenomena. These results help to elucidate the intrinsic formation mechanism of the rod, plate, and tripod structures of the $Bi_2Te_3$ recovered by the wet reduction process.