• Journal of Sensor Science and Technology
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• v.32 no.1
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• pp.55-61
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• 2023

The objective of this study is to determine the concentrations of mixed gases by establishing a diagnosis method of a transformer using tunable-wavelength optical infrared sensors. Absorption of infrared light by methane, acetylene, and ethylene gases injected is measured from the outputs of the infrared sensors. Regression analysis equations of the gas concentrations are acquired from their respective measured absorption. The obtained concentrations are as follows: -3-9 % errors above 600 ppm(methane), 3 % errors above 1200 ppm(acetylene), and 10 % errors above 500 ppm(ethylene). The concentration inference equations obtained using the individual gases are applicable when the absorption wavelength bands do not overlap. The results of the fault analysis of a transformer using the Duval triangle method and the tunable infrared gas sensors are as follows: temperature faults with -1-1% errors and energy faults with -7-7 % errors.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.48 no.2
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• pp.20-27
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• 2016

Ethylene gas is a natural hormone that directly affects the freshness of agricultural products, so it is very important for the maintenance of freshness to remove ethylene gas from corrugated board boxes. Many methods for the removal of this and other gases have been reported. In this study, the utilization of an absorbent using activated carbon was adopted for the removal of ethylene gas from a corrugated board box. Activated carbon powders were prepared by grinding in a laboratory and were used to treat the surface and to laminate paperboards with a starch solution. The ethylene gas absorption was evaluated by using a gas chromatography to measure the residual ethylene gas concentration. About 60% of the ethylene gas was absorbed by the activated carbon itself. However, the paperboards that were surface-treated and laminated with starch and activated carbon showed lower than 20% ethylene gas absorption. This was because the starch and smaller particles of activated carbon blocked the surface pores of activated carbon particles. Therefore, either the use of the binders must be minimized for the surface treatment of paperboards, or activated carbon packs can be used as absorbents in corrugated boxes.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.40 no.1
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• pp.29-34
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• 2008

The charcoal has been used not only as fuel but also as human health care material since it was used. Charcoal's performances were generally investigated in aspects of energy efficiency and caloric values. This study was conducted in order to increase charcoal's application area and to develop functional paper. Five types of charcoal were used on a basis of gas absorption properties from previous study. Handsheets were made by two methods by internal loading and surface spray on interlayer. Strength properties of internal loading and interlayer spray handsheets were decreased as the charcoal loading increased. Ethylene gas absorption property was higher in both of oak's black charcoal and white charcoal than others. In terms of strength, 5-10% charcoal loading was efficient. Above 10% loading, a rate of strength decrease was higher than that of ethylene gas absorption rate. Formaldehyde absorption property was higher at both of oak's black charcoal and mixed charcoal than others. However, to guarantee enough charcoal loading should be higher than 95 $g/m^2$ for sufficient formaldehyde absorption.

• Transactions of the Korean hydrogen and new energy society
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• v.28 no.5
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• pp.561-569
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• 2017

In this study, a synthetic amine made using the ethylene oxide-ammonia reaction was used as an absorbent to remove carbon dioxide. Existing absorbents were used in a mix in order to improve performance; however, because the ethylene oxide-ammonia reaction generates primary, secondary, and tertiary amines simultaneously, it has the merit that separate mixing of the absorbents was not needed. The performance of carbon dioxide absorption with the synthetic amine was compared to that of MEA. As a result of an experiment, it was determined that the $CO_2$ loading was 1.15 times better than that of MEA (a commonly used amine), while the cyclic capacity was 2.28 times higher. Because the heat of reaction was 1.10 times lower than for MEA, the synthetic amine showed superior performance in terms of absorption and regeneration.

• Journal of the Korean Wood Science and Technology
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• v.31 no.6
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• pp.83-88
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• 2003

The woodceramics are porous amorphous carbon and glassy carbon composite materials. Woodceramics attracted a lot of attention in recent years because they are environmentally friendly and because of their unique functional characteristics such as catalysis, moisture absorption, deodorization, purification, carrier for microbial activity, specific stiffness, corrosion and friction resistance, and their electromagnetic shielding capacity. In this paper, we made new products of clay-woodceramics to investigate the industrial analysis and ethylene gas adsorption for basic data of building- and packging- materials keeping fruit fresh for a long time. Clay-woodceramics were carbonized for 3 h of heating in a special furnace under a gas flow of nitrogen(15 ml/min.) from 3 layers-clay-woodparticleboard made from pallet waste wood, phenol- formaldehyde resin(hereafter PF, Non volatile content:52%, resin content 30%), and clay(10%, 20% and 30%). Carbonization temperature was 400℃, 600℃ and 800℃. Experimental results shows that the higher the carbonization temperature, the higher the fixed carbon and the lower the volatile contents. The higher the clay content, the more the ash content. The higher the carbonization temperature, the more the ethylene gas adsorption. Carbonization temperature of 800℃ gave the best reslts as same as that of white charcoal and activated carbon.(800℃-clay-woodceramic: 5.36 ppm, white charcoal: 5.66 ppm, activated carbon: 5.79 ppm) The clay contents did not make difference of ethylene gas adsoption.

• Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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• 2001.06a
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• pp.1192-1192
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• 2001

Usually there are many furnaces in a ethylene plant and the performance of total furnaces can be improved if that of each furnace is monitored and controlled. For this purpose real-time data for the effluent of each furnace is necessary. However, it is very difficult to analyze the total effluent stream of a ethylene furnace by real-time because it is composed of so many components including heavy hydrocarbons. Fortunately, component data for lighter hydrocarbons is much more important than that of heavier ones for ethylene furnace. In ordinary case, the on-line measurement of light hydrocarbons is performed by on-stream gas chromatography, after separating gas-phase part from effluent. The main and important components of gas-phase are Methane, Ethane, Ethylene, and Propylene. If we can use Near-infrared spectroscopy for measuring those components within good reproducibility, shorter analysis time, better repeatability, easier maintenance and lower cost will make Near-infrared (NIR) analyzer replace on-stream gas chromatography in this process. Although it is known to be very difficult to measure gas components because of very weak absorption in Near-infrared region, we have studied the feasibility of the application of NIR for the measurement of gas-phase hydrocarbon in the effluent of ethylene furnace. The samples were obtained from actual process and NIR spectra were collected over 1100 to 2500nm range. NIR spectra and calibrations showed and demonstrated the possibility of extending NIR spectroscopy to the measurement of gas-phase hydrocarbon in the effluent of ethylene furnace.

• Korean Chemical Engineering Research
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• v.47 no.3
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• pp.380-385
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• 2009

The absorption rate of carbon dioxide with 2-amino-2-methyl-1-propanol(AMP) was measured in such non-aqueous solvents as methanol, ethanol, n-propanol, n-butanol, ethylene glycol, propylene glycol, and propylene carbonate, and in water at 298 K and 101.3 kPa using a semi-batch stirred tank with a plane gas-liquid interface. The overall reaction rate constant, obtained under the condition of fast reaction regime, from the measured rate of absorption was used to get the elementary reaction rate constants in complicated reactions represented by reaction mechanism of carbamate formation and the order of overall reaction of $CO_2$ with amine. The correlation between the elementary reaction rate constant and the solubility parameter of the solvent was also presented.

• Journal of Conservation Science
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• v.24
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• pp.13-22
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• 2008

The identification of species, hygroscopic property, and ability of ethylene gas absorption of 23 ancient charcoals excavated from wooden coffin burials and roof-tile kilns of Chudong-ri cultural site were investigated. All of the 12 charcoals excavated from wooden coffin burials were broad-leaved trees. Among the total 12 samples, 9 samples were Lepidobalanus and others were Celtis spp.. On the other hand, other 11 charcoals from roof-tile kilns were needle-leaved tree, Pinus spp.(hard pine). The broad-leaved tree charcoals from wooden coffin burials showed a higher moisture absorption capacity than needle-leaved tree charcoals from roof-tile kilns. The ethylene gas absorption was greater in the Lepidobalanus charcoal than that of Celtis spp. and Pinus spp. (hard pine) charcoal. The broad-leaved tree charcoal having high absorption ability of substances was due to a large microporous and specific surface area. Therefore, it was estimated that broad-leaved tree charcoals were filled in order to make favorable condition in tomb. The wood quality of pine is soft and easy to burn because of low specific gravity, as well as high calorific value by resin in wood. We could assume that the pine wood was used as fuel for roof-tile kilns because of easy control of heating and thermal power.

• Horticultural Science & Technology
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• v.19 no.2
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• pp.174-178
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• 2001

Absorption potential of oak charcoal was estimated using simulated static and dynamic systems to establish a model for practical application of the charcoal in modified atmosphere (MA) packaging and during the storage of 'Fuji' apples. Practical MA packaging was performed using $60{\mu}m$ PE film zipper bags in which five apples were placed. Absorption potential of oak charcoal was $58.4{\mu}L/100g$ charcoal for ethylene and 583 mg/100 g charcoal for carbon dioxide. Effects of enclosing a 100 g-charcoal packet inside a MA package seemed not to last long enough for quality maintenance of 'Fuji' apples stored at $0^{\circ}C$ for three months. During extended storage, ethylene and $CO_2$ levels were not significantly reduced by charcoal treatment. Nevertheless, absorption of carbon dioxide appeared to alleviate the incidence of $CO_2$-related internal browning disorder. Modelling study of practical storage and marketing procedure indicates that 0.19 kg charcoal/day is required to offset $CO_2$ production from 15 kg of apples at $0^{\circ}C$. The amount of charcoal should be increased to 3.10 kg/day if ethylene is a target gas. From the practical point of view, the results suggest that charcoal could be used only for small unit packages for a short period.

• Journal of Veterinary Clinics
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• v.20 no.1
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• pp.91-95
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• 2003

It has been known that periods of absorption varies allografts or xenografts of transplantations of freeze-dried cortical bone(FDCB). In this study changes of absorption of FDCB in xenograft transplantations were evaluated according to extracted time with chloroform-methanol solution(CM sol.). The FDCB from pig was removed soft tissue by surgical knife. Fat of the FDCB was removed with treatments of CM sol. for 2, 6, and 10 days, then the treated FDCB was freeze-dried at $-80^{\circ}C$ and sterilized with ethylene oxide gas. The FDCB was transplanted to fifteen millimeter artificial-defected regions of 6 dogs on fibular diaphyses. This was biweekly examined by radiograph for 18 weeks. In result new bone formation with FDCB treated for 6 days was higher than the other bones treated for 2 and 10 days. Duration of absorption with FDCB treated for 6 days was longer than the others. The remain with FDCB treated for 10 days was more than the others.