• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.225.1-225.1
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• 2010

Within recent years attention has been focused on the method of hydrogen storage using metal hydride reactor due to its high energy density, durability, safety and low operating pressure. In this paper, a numerical study is carried out to investigate the coupled heat and mass transfer process for absorption in a cylindrical metal hydride hydrogen storage reactor using a newly developed model. The simulation results demonstrate the evolution of temperature, equilibrium pressure, H/M atomic ratio and velocity distribution as time goes by. Initially, hydrogen is absorbed earlier from near the wall which sets the cooling boundary condition owing to that absorption process is exothermic reaction. Temperature increases rapidly in entire region at the beginning stage due to the initial low temperature and enough metal surface for hydrogen absorption. As time goes by, temperature decreases slowly from the wall region due to the better heat removal. Equilibrium pressure distribution appears similarly with temperature distribution for reasons of the function of temperature. This work provides a detailed insight into the mechanism and corresponding physicochemical phenomena in the reactor during the hydrogen absorption process.

• Carbon letters
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• v.12 no.1
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• pp.1-7
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• 2011

In the present study, the removal of Pb (II) ions on oxidized activated carbons (ACs) was investigated. ACs were derived from activation of indigenous cotton stalks waste with potassium hydroxide (KOH) in two-stage process. The KOH-ACs were subjected to liquid-phase oxidation with hot $HNO_3$ and one untreated sample was included for comparison. The obtained carbons were characterized by Fourier transform infrared (FTIR), slurry pH and $N_2$-adsorption at 77 K, respectively. Adsorption capacity of Pb (II) ions on the resultant carbons was determined by batch equilibrium experiments. The experimental results indicated that the oxidation with nitric acid was associated with a significant increase in mass of yield as well as a remarkable reduction in internal porosity as compared to the untreated carbon. The AC-800N revealed higher adsorption capacity than that of AC-800, although the former sample exhibited low surface area and micropore volume. It was observed that the adsorption capacity enhancement attributed to pore widening, the generation of oxygen functional groups and potassium containing compounds leading to cation-exchange on the carbon surface. These results show that the oxidized carbons represented prospective adsorbents for enhancing the removal of heavy metals from wastewater.

• Journal of Ocean Engineering and Technology
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• v.25 no.4
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• pp.7-11
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• 2011

The installation phase for a topside module suggested can be divided into 9 stages, which include start, pre-lifting, lifting, lifted, rotating, positioning, lowering, mating, and end of installation. The transfer of the topside module from a transport barge to a crane vessel takes place in the first three stages, from start to lifting, while the transfer of the module onto a floating spar hull occurs in the last three stages, from lowering to the end. The coupled multi-body motions are calculated in both calm water and in irregular waves with significant wave height (1.52m), with suggested force equilibrium diagrams. The effects of the hydrodynamic interactions between the crane vessel and barge during the lifting stage have been considered. The internal forces caused by the load transfer and ballasting are derived for the lifting phases. The results of these internal forces for the calm water condition are compared with those in the irregular sea condition. Although the effect of pitch motion on the relative vertical motion between the deck of the floating structure and the topside module is significant in the lifting phases, the internal force induced pitch motion is too small to show its influence. However, the effect of the internal force on the wave-induced heave responses in the lifting phases is noticeable in the irregular sea condition because the transfer mass-induced draught changes in the floating structure are observed to have higher amplitudes than the external force induced responses.

• Industrial Engineering and Management Systems
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• v.8 no.4
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• pp.221-227
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• 2009

There are customer services jointly provided by two facilities so that each customer will complete the course made up of both facilities' sub-services. The two facilities are assumed invested respectively by an infrastructure owner and one subordinate facility owner, whose partnership is built on their capital investments. This paper presents a mathematical model of Stackelberg competition between the two facility owners to derive their optimal Nash equilibrium. In this study, each facility owner's profit is consisted of fixed revenue fractions of sold services, operating costs (including depreciation cost) and maintenance costs of her facility. The maintenance costs of one facility are incurred both by failures and deterioration due to usage. Moreover, for both facilities, failures are rectified immediately by minimal repairs and preventive maintenance is carried out at a fixed time epoch. Additional assumptions are also employed to develop the model such as customer arrivals are manipulated to follow a Poisson process, and each facility's lifetime is independently Weibull-distributed. The Stackelberg game proceeds as follows. At the first stage of decision making process, the infrastructure owner (acting as a leader) decides the allocation of revenue shares based on her self-interest. After observing the allocation of revenue shares, the subordinate facility owner determines her own optimal price of services. This paper investigates actions and reactions of the two partners in the system. Then analytical conditions are proposed to achieve a unique optimal Nash equilibrium. Finally, some suggestions for further research are discussed.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.11a
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• pp.201-205
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• 2011

In a cryogenic propellant tank the pressurant is contracted due to heat loss and the propellant itself evaporates. On a restartable propulsion system such phenomena are more intensive because the propellant contacts with the pressurant on the larger surface during the coast flight. Such heat and mass transfer phenomena should be considered for estimating the amount of pressurant. On the hypothesis that the heat and mass transfer quasi-equilibrium is achieved during the coast flight, the calculation process of the equilibrium pressure is presented. On the process the amount of loaded helium on the Falcon-1 second stage is calculated.

• Water for future
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• v.28 no.4
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• pp.147-154
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• 1995

Scour characteristics of noncohesive bed materials at the downstream of free-falling jet were analyzed through hydraulic experiments. It was assumed that the downstream had no special energy dissipators. Flow characteristics of free falling jet from rectangular section were studied, and scour characteristics with and without mounds, which were generated at the downstream of the scour hole, were comparatively analyzed for various bed materials, discharges and tailwater depths. Not only the equilibrium scour depth but also the height of mound could be expressed as a function of densimetric Froude number. Densimetric Froude number had closer relationship with the equilibrium dimensionless scour depth than other dimensionless parameters. It was suggested that the mound effects should be considered at the design stage of bed protection works.

• Korean Journal of Soil Science and Fertilizer
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• v.11 no.3
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• pp.161-174
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• 1979

A review was made on the effect of organic matter application on the chemical characteristics of soils such as pH, solubilities of minerals, and cation exchange capacity mainly at flooded rice soils. The review can be summarized as follows: 1. Application of organic material such as rice straw and compost in flooded rice soil leads to a temporary lowering of soil pH at the earlier stage of soil reduction, due to the production of various organic acids and carbonic acid. This temporary lowered pH is replaced with the production of alkaline substances such as ammonia as the reduction of soil proceeds. 2. Incorporation of organic materials intensifies the ferrous iron, dissolving various minerals, virtually to the increase in electrical conductivity of soils. 3. Organic materials also play an important role in dissolving soil minerals through the production of various chelating agents. 4. Application of soil organic matter significantly increases cation exchange capacity of soils. 5. Continuous application of rice straw or compost leads to the increase in soil organic matter content to some extent, up to the level of equilibrium. In soils low in organic matter the equilibrium level is attained with five years continuous application of compost. 6. The manner of chemical fertilizer application influences the accumulation of organic matter applied in soils. Low levels of fertilization lowers the accumulation while high levels of fertilization accerelates the accumulation.

• Journal of Biosystems Engineering
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• v.19 no.2
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• pp.112-123
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• 1994

At present, no appropriate drying conditions can be found for the heated-air drying of mushroom in Korea. Usually, mushroom is being dried at the temperature range of 40 to $50^{\circ}C$ until the moisture content reaches 10~13% (wb). However, drying characteristics of the mushroom should be investigated for quality improvement and efficient drying operation of the mushroom. The results of this study may be summarized as follows ; 1. The effect of air temperature on the rate of drying was greater than that of relative humidity for drying of mushroom, and the rate of drying was increased with increase in the air temperature. 2. Drying rate for Shiitake mushroom showed falling-rate period of drying without constant-rate period of drying. Drying rate for Oyster mushroom showed a short constant-rate period at the initial stage of drying process, and followed by falling-rate period of drying. 3. Exponential and App.-Diffusion models were found to describe well the drying process of Shiitake mushroom. Exponential and Thompson models for Oyster mushroom in which Thompson model was the most suitable for Oyster mushroom. 4. The equilibrium moisture content of the mushroom decreased with decrease in the air temperature and increase in the relative humidity. In room condition($20^{\circ}C$, 54% RH), the calculated values of the equilibrium moisture content showed 11.17% for Shiitake mushroom and 13.19% for Oyster mushroom, respectively.

• Journal of the Korean Chemical Society
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• v.28 no.3
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• pp.194-202
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• 1984

The adsorption properties of organo sulfur compounds on cation exchanged natural zeolites from n-heptane were investigated. The equilibrium adsorbed amounts were dependent upon the exchanged cation and the nature of organo sulfur compounds such as length, volume, electronical structure. The increasing orders of equilibrium adsorbed amounts were thiophene derivatives, disulfide, sulfide mercaptane and thiophene, benzothiaphene, dibenzothiophene. And $Co^{+2}$-zeolite was the most prominent adsorbant. Rate determining step of the adsorption at initial stage was intraparticle diffusion into the transitional pores of zeolite. These adsorption rates were dependent upon the bulkiness of adsorbate. Finally, preadsorbed water didn't affect these adsorption until the cation exchanged natural zeolite contained 2.26${\times}10^{-3}$ mol/g of water. It indicated that water preferentially occupied the micro pores of the cation exchanged natural zeolites.

• Computers and Concrete
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• v.11 no.5
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• pp.411-440
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• 2013

Large fluctuations in surface strain at the level of steel are expected in reinforced concrete flexural members at a given stage of loading due to the emergent structure (emergence of new crack patterns). This has been identified in developing deterministic constitutive models for finite element applications in Ibrahimbegovic et al. (2010). The aim of this paper is to identify a suitable probability distribution for describing the large deviations at far from equilibrium points due to emergent structures, based on phenomenological, thermodynamic and statistical considerations. Motivated by the investigations reported by Prigogine (1978) and Rubi (2008), distributions with heavy tails (namely, alpha-stable distributions) are proposed for modeling the variations in strain in reinforced concrete flexural members to account for the large fluctuations. The applicability of alpha-stable distributions at or in the neighborhood of far from equilibrium points is examined based on the results obtained from carefully planned experimental investigations, on seven reinforced concrete flexural members. It is found that alpha-stable distribution performs better than normal distribution for modeling the observed surface strains in reinforced concrete flexural members at these points.