• Bulletin of the Korean Chemical Society
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• 제20권9호
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• pp.1026-1030
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• 1999

The properties of semiflexible polymer brushes are studied by applying the classical limit of mean-field approach for chains with marginal chain stiffness. Using the mean-spherical Gaussian model, the most probable configuration for semiflexible chains is obtained, which reduces to the parabolic brush of Milner et al. [Mac-romolecules 1988, 21, 2610] in the flexible limit. From this configuration, equilibrium brush height as well as interactions between semiflexible brushes are estimated.

• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2006년도 학술논문요약집
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• pp.193-193
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• 2006

• 방사성폐기물학회지
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• 제19권2호
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• pp.187-196
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• 2021

Chemical equilibrium calculations for multicomponent aqueous systems involving the reductive dissolution of magnetite (Fe₃O₄) with oxalic acid (H₂C₂O₄) were performed using the HSC Chemistry® version 9. They were conducted with an aqueous solution model based on the Pitzer's approach of one molality aqueous solution. The change in the amounts and activity coefficients of species and ions involved in the reactions as well as the solution pH at equilibrium was calculated while changing the amounts of raw materials (Fe₃O₄ and H₂C₂O₄) and the system temperature from 25℃ to 125℃. In particular, the conditions under which Fe₃O₄ is completely dissolved at high temperatures were determined by varying the raw amount of H₂C₂O₄ and the temperature for a given raw amount of Fe₃O₄ fed into the aqueous solution. When the raw amount of H₂C₂O₄ added was small for a given raw amount of Fe₃O₄, no undissolved Fe₃O₄ was present in the solution and the pH of the solution increased significantly. The formation of ferrous oxalate complex (FeC₂O₄) was observed. The equilibrium amount of FeC₂O₄ decreased as the raw amount of H₂C₂O₄ increased.

• 방사성폐기물학회지
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• 제21권3호
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• pp.397-410
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• 2023

This study examined the efficacy of various chlorinating agents in partitioning light water reactor spent fuel, with the aim of optimizing the chlorination process. Through thermodynamic equilibrium calculations, we assessed the outcomes of employing MgCl₂, NH₄Cl, and Cl₂ as chlorinating agents. A comparison was drawn between using a single agent and a sequential approach involving all three agents (MgCl₂, NH₄Cl, and Cl₂). Following heat treatment, the utilization of MgCl₂ as the sole chlorinating agent resulted in a moderate separation. Specifically, this method yielded a solid separation with 96.9% mass retention, 31.7% radioactivity, and 44.2% decay heat, relative to the initial spent fuel. In contrast, the sequential application of the chlorinating agents following heat treatment led to a final solid separation characterized by 93.1% mass retention, 5.1% radioactivity, and 15.4% decay heat, relative to the original spent fuel. The findings underscore the potential effectiveness of a sequential chlorination strategy for partitioning spent fuel. This approach holds promise as a standalone technique or as a complementary process alongside other partitioning processes such as pyroprocessing. Overall, our findings contribute to the advancement of spent fuel management strategies.

• International Journal of Concrete Structures and Materials
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• 제10권4호
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• pp.513-525
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• 2016

The resistance-demand approach has emerged as an effective approach for determining the shear capacity of reinforced concrete beams. This approach is based on the fact that both the shear resistance and shear demand are correlated with flexural tensile strain from compatibility and equilibrium requirements. The basic shear strength, under a given loading is determined from the intersection of the demand and resistance curves. This paper verifies the applicability of resistance-demand procedure for predicting the shear capacity of high strength concrete beams without web reinforcement. A total of 18 beams were constructed and tested in four-point bending up to failure. The test variables included the longitudinal reinforcement ratio, the shear span to depth ratio, and the beam depth. The shear capacity of the beams was predicted using the proposed procedure and compared with the experimental values. The results of the comparison showed good prediction capability and can be useful to design practice.

• 전기학회논문지
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• 제57권1호
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• pp.34-39
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• 2008

Nash Equilibrium(NE) is essential to investigate a participant's bidding strategy in a competitive electricity market. Congestion on a transmission line makes it difficult to compute the NE due to causing a mixed strategy. In order to compute the NE of a multi-player game, some heuristics are proposed with concepts of a key player and power transfer distribution factor in other studies. However, generation capacity constraints are not considered and make it more difficult to compute the NE in the heuristics approach. This paper addresses an effect of generation capacity limits on the NE, and suggest a solution technique for the mixed strategy NE including generation capacity constraints as two heuristic rules. It is reported in this paper that a role of the key player who controls congestion in a NE can be transferred to other player depending on the generation capacity of the key player. The suggested heuristic rules are verified to compute the mixed strategy NE with a consideration of generation capacity constraints, and the effect of the generation constraints on the mixed strategy NE is analyzed in simulations of IEEE 30 bus systems.

• Journal of Electrical Engineering and Technology
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• 제8권6호
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• pp.1530-1541
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• 2013

The coexistence and extinction of species are important concepts for biological systems and can be distinguished by an investigation of stability. When determining local stability of nonlinear systems, Lyapunov indirect method based on the Jacobian linearization has been widely employed due to its simplicity. Despite such popularity, it is not applicable to singular systems whose Jacobian has at least one eigenvalue that is equal to zero. In such singular cases, an appropriate Lyapunov function should be sought to determine the stability of systems, which is rather difficult and quite involved. In this paper, we seek for a simple criterion to determine stability of the equilibrium that is located at the boundary of the positive orthant, when one of eigenvalues of the Jacobian is zero. The goal of the paper is to present a generalized condition for the equilibrium to attract all trajectories that starting from initial condition in the positive orthant and near the equilibrium. Unlike the Lyapunov direct method, the proposed method requires just a simple algebraic computation for checking the stability of the critical point. Our approach is applied to various biological systems to show the effectiveness of the proposed method.

• Structural Engineering and Mechanics
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• 제20권3호
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• pp.313-334
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• 2005

The paper presents a new approach for the analysis of slope stability that is based on the numerical solution of a differential equation, which describes the thrust force distribution within the potential sliding mass. It is based on the evaluation of the thrust force value at the endpoint of the slip line. A coupled approximation of the slip and thrust lines is applied. The model is based on subdivision of the sliding mass into slices that are normal to the slip line and the equilibrium differential equation is obtained as the slice width approaches zero. Opposed to common iterative limit equilibrium procedures the present method is straightforward and gives an estimate of slope stability at the value of the safety factor prescribed in advance by standard requirements. Considering the location of the thrust line within the soil mass above the trial slip line eliminates the possible development of a tensile thrust force in the stable and critical states of the slope. The location of the upper boundary point of the thrust line is determined by the equilibrium of the upper triangular slice. The method can be applied to any smooth shape of a slip line, i.e., to a slip line without break points. An approximation of the slip and thrust lines by quadratic parabolas is used in the numerical examples for a series of slopes.

• 한국세라믹학회지
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• 제45권2호
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• pp.90-93
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• 2008

The oxygen gas behavior in PDP (plasma Display Panel) glass melts doped with sulfate ($SO_4^{-2}$) or blast furnace slag (BFS, $S^{2-}$) or both by means of yttria-stabilized zirconia (YSZ) electrodes was observed after the first fining. The temperature dependence of oxygen equilibrium pressure ($P_{O2}$) in each melt showed typical behavior, namely $P_{O2}$ decreased as temperature decreased. This suggests that an oxidation of $S^{4+}$ to $S^{6+}$ took place. However, the $P_{O2}$-value at constant temperature increased in the following order: BFS$P_{O2}$ of the melt doped with sulfate+BFS was much lower than that of the melt with only sulfate, although only 10% of sulfur was added by the BFS. This behavior can be explained by the redox reaction between sulfide ions in the BFS and dissolved oxygen ions in the melt during the first fining.

• 유통과학연구
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• 제10권9호
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• pp.5-11
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• 2012

Purpose - The objective of the paper is to explain both the price sensitivity of international tourists to South Korea and the price sensitivity of Korean tourists to international travel. The study examines long-run equilibrium relationships and Granger causal relationships between foreign exchange rates and inbound and outbound tourism demand in South Korea. Research design/ data / methodology - The study employs monthly time series data from January 1990 to September 2010. The paper examines the long-run equilibrium relationship using the Johansen cointegration test approach after unit root tests. The short-run Granger causality was tested using the vector error correction model with the Wald test. Results - Hypothesis 1 testing whether there is a long-run equilibrium relationship between exchange rates, inbound and outbound tourism demand is supported. Hypothesis 2 testing whether exchange rates lead to a change in touristarrivals and expenditure is not supported. Hypothesis 3 testing whether exchange rates lead to a change in tourist departures and expenditure is supported. Conclusions - The findings of this study show that the impacts of tourism price competitiveness are changing quite significantly with regard to destination competitiveness. In other words, the elasticity of tourism price over tourism demand has been moderated.