• Composites Research
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• v.17 no.6
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• pp.1-7
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• 2004

The studies of particulate reinforced composites have been conducted for many years. The nanocomposites to be studied vigorously in recent years are one of them. We fabricated and studied multi-walled carbon nanotube(MWNT)/epoxy composites which may be useful as matrix for continuous fiber-reinforced composites. We investigated tensile properties of MWNT/epoxy composites as a function of MWNT concentration, which were prepared by the fabrication method established in this study. Tensile stiffness and strength increased 19% at 0.5 wt% and 12% at 0.2 wt%, respectively. We observed the reaggregation phenomenon of MWNTS during curing, which should be controlled to obtain higher tensile properties.

• Transactions of the Korean hydrogen and new energy society
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• v.25 no.2
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• pp.131-138
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• 2014

Highly conductive bipolar plate for polymer electrolyte membrane fuel cell (PEMFC) was prepared using phenol novolac-type epoxy/graphite powder (GP)/carbon fiber filament (CFF) composite, and a rubber-modified epoxy resin was introduced in order to give elasticity to the bipolar plate graphite fiber (GF) was incorporated in order to improve electrical conductivity. To find out the cure condition of the mixture of novolac-type and rubber-modified epoxies, differential scanning calorimetry (DSC) was carried out and their data were introduced to Kissinger equation. And tensile and flexural tests were carried out using universal testing machine (UTM) and the surface morphology of the fractured specimen and the interfacial bonding between epoxy matrix and CFF or GF were observed by a scanning electron microscopy (SEM).

• Journal of the Korean Society for Precision Engineering
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• v.16 no.8
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• pp.149-154
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• 1999

FRMLs(Fiber Reinforced Metal Laminates) is a new type of hybrid materials. FRMLs consists of high strength metal and fiber which are laminated using a structural adhesive bond(epoxy resin). The effect of resin mixture ratios on the fatigue crack propagation behavior and mechanical property of Aramid fiber reinforced aluminum composites was investigated. The epoxy, diglycidylether of bisphenol A(DGEBA) was cured with methylene dianiline(MDA) with or without accelerator(K-54). Eight kinds of resin mixture ratio were tested for the experiment ; five kinds of FRMLs(1))epoxy & curing agent) and three kinds of FRMLs(2)(epoxy & curing agent & accelerator). FRMLs(2) have a more effective characteristics on the fatigue crack propagation behavior and mechanical property than FRMLs(1)

• Proceedings of the Korean Society For Composite Materials Conference
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• 2000.11a
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• pp.79-83
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• 2000

Interfacial and microfailure properties of carbon liber/bismaleimide (BMI) composites were evaluated using both tensile fragmentation and compressive Broutman tests with acoustic emission (AE). Since BMI is rather difficult matrix to apply for the conventional fragmentation test because of its too low elongation and too brittle and high modulus properties, dual matrix composite system was applied. After carbon fiber/BMI composite was prepared for rod shape by controlling differing curing stage, composites rod was embedded in toughened epoxy as outer matrix. The typical microfailure modes including fiber break, matrix cracking, and interlayer failure were observed during tensile testing, whereas the diagonal slippage in fiber ends was observed during compressive test. On the other hand, AE amplitudes of BMI matrix fracture were higher than carbon fiber tincture under tensile test because BMI matrix has very brittle and high modulus. The waveform of signals coming from BMI matrix fractures was consistent with AE amplitude result under tensile tests.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2003.06a
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• pp.1495-1498
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• 2003

Recently, self-healing methods of a cracked matrix, especially polymeric composite materials, became the center of engineering researchers. In this paper, we summarized the self-healing concept for polymeric composite materials and investigated the effect of microparticle on the crack growth behavior in colorless and transparent matrix by experimental observation to describe the crack propagation around the microparticle inside epoxy matrix composite. Compression splitting test for the specimen involving microparticle was conducted. In addition, FE analysis was pursued to present the stress contour around microparticle in the matrix. Through the experiments and FE analysis, we found that the size. relative position, bonding condition and relative stiffness of microparticle are important parameters to decide the direction of crack propagation, which is related to the rupture of microparticle for self-healing

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2001.04a
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• pp.1-6
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• 2001

In this paper, edge delaminations in cracked composite plates are analytically investigated. A theoretical model based upon a sub-laminate approach is used to determine the strain energy release rate, $G^{ed}$, in [$\pm$$\theta_m$/$90_n$]$_s$ carbon/epoxy laminates loaded in tension. The analysis provides closed-form expressions for the reduced stiffness due to edge delamination and matrix cracking and the total energy release rate. The parameters controlling the laminate behaviour are identified. It is shown that the available energy for edge delamination is increased notably due to transverse ply cracking. Also thermal stresses increase substantially the strain energy release rate and this effect is magnified by the presence of matrix cracking. Prediction for the edge delamination onset strain is presented and compared with experimental data. The analysis could be applied to ceramic matrix composite laminates where similar mechanisms develop, but further experimental evidence is required.

• Transactions of the Korean Society of Mechanical Engineers
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• v.16 no.2
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• pp.200-206
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• 1992

The effect of fiber diameter and gauge length on pull-out test for the interfacial properties in fiber reinforced resin composites have been investigated and these results have been arranged as statistical analysis. The fiber and matrix resins used for this study were stainless steel fiber (SUS316) and carbon fiber (high strength type), epoxy and high density polyethylene resin. From this study, it has been found that shear strength are constant regardless of gauge length of pull-out test and coefficient of variation depend on fiber diameter. In addition, it has been found that the interfacial shear strength decreased with the increasing fiber diameter, and in all case, Weibull parameter (m) has approximately 1.2/C.O.V.

• Polymer(Korea)
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• v.25 no.4
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• pp.587-593
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• 2001

In this work, red mud (RM) was chemically modified by 0.1, 1, and 5 M H3PO4 solution to prepare epoxy/RM nanocomposites. The effect of chemical treatment on pH, acid-base values, specific surface area, and porosity of RM surface was analyzed. To estimate the mechanical interfacial properties of epoxy/RM nanocomposites, the critical stress intensity factor (K$_{IC}$) was measured. From the experimental results, it was clearly revealed that the porosity, specific surface area, and acid values of RM surface were developed as the increase of the treatment concentration due to the increase of acidic functional group, including hydroxyl group on RM surface. The mechanical interfacial properties of epoxy/treated-RM nanocomposites were higher than those of epoxy/RM as-received due to an improvement of interfacial bonding between basic matrix and RM surface.

• Polymer(Korea)
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• v.26 no.5
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• pp.623-633
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• 2002

The flame retardant and thermal properties of ortho-cresol novolac (OCN) and biphenyl epoxy blends containing red-phosphorus were investigated. For five types of compounds designed with the volume ratio of OCN and biphenyl epoxy, thermal properties were analysed by TGA or DTC, and flame retardancy effectiveness was estimated through UL-94V test. While the flame retardant and thermal properties were improved with the content of filler and red-phosphorus, the excessive amount of red-phosphorus caused to deteriorate those properties. Using the blends of OCN/biphenyl rather than pure OCN or biphenyl epoxy as a matrix the flame retardancy of composites could be improved by the synergic effects of high thermal resistance of OCN and intumescent property of biphenyl. The flame retardant me chanism of epoxy compound containing red-phosphorus could be thought of the heat-insulating effect of intumescent char-layer formed in the surface of composites.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.32 no.11
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• pp.918-923
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• 2008

Since crack detection for laminated composites in-service is effective to improve the structural reliability of laminated composites, it have been tried to detect cracks of laminated composites by various nondestructive methods. An electric potential method is one of the widely used approaches for detection of cracks for carbon fiber composites, since the electric potential method adopts the electric conductive carbon fibers as reinforcements and sensors and the adoption of carbon fibers as sensors does not bring strength reduction induced by embedding sensors into the structures such as optical fibers. However, the application of the electric method is limited only to electrically conductive composite materials. Recently, a piezoelectric method using piezoelectric characteristics of epoxy adhesives has been successfully developed for the adhesive joints because it can monitor continuously the damage of adhesively bonded structures without producing any defects. Polymeric materials for the matrix of composite materials have piezoelectric characteristics similarly to adhesive materials, and the fracture of composite materials should lead to the fracture of polymeric matrix. Therefore, it seems to be valid that the piezoelectric method can be applied to monitoring the damage of composite materials. In this research, therefore, the feasibility study of the damage monitoring for composite materials by piezoelectric method was conducted. Using carbon fiber epoxy composite and glass fiber composite, charge output signals were measured and analyzed during the static and fatigue tests, and the effect of fiber materials on the damage monitoring of composite materials by the piezoelectric method was investigated.