• Title/Summary/Keyword: Epoxy Resins

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Structural Performance of Reinforced Concrete Beams Strengthened with Sprayed Fiber Reinforced Polymers (Sprayed FRP로 보강된 철근콘크리트 보의 보강성능에 관한 연구)

  • Lee, Kang-Seok;Son, Young-Seon;Lee, Moon-Sung
    • Journal of the Korea Concrete Institute
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    • v.19 no.4
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    • pp.421-431
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    • 2007
  • The main purpose of this study is to develop a sprayed FRP repair and strengthening method, which is a new technique for strengthening the existing concrete structures by mixing one of the carbon or glass chopped fibers and one of the epoxy or vinyl ester resins with high-speed compressed air in open air and randomly spraying the mixture onto the concrete surface. At present, the sprayed FRP repair and strengthening method using the epoxy resin has not been fully discussed. In order to investigate the material property of the sprayed FRP, this study carried out tensile tests of the material specimens, which were changed with the combinations of various variables including the length of chopped fiber and the mixture ratio of chopped fiber and resin. These variables were set to have the equal material strength, compared with that of one layer of the FRP sheet. As a result, the optimal length of glass and carbon chopped fibers was fumed out to be 38 mm, and the optimal mixture ratio between chopped fiber and resin was also turned out to be 1 : 2 from each variable. And also, the thickness of the sprayed FRP to have the equal strength to one layer of the FRP sheet was finally calculated. In is study, a series of experiments were carried out to evaluate the strengthening effects of flexural beams, shear beams and damaged beams strengthened with the sprayed FRP method, respectively. The results revealed that the strengthening effects of the flexural and shear specimens were reasonably similar to those of the FRP sheet, and the developed Sprayed FRP technique is able to be used as a strengthening scheme of existing RC building.

Influence of Acid and Base Surface Treatment of Multi-Walled Carbon Nanotubes on Mechanical Interfacial Properties of Carbon Fibers-Reinforced Composites (산-염기 표면처리된 MWNTs의 첨가가 탄소섬유 강화 복합재료의 기계적 계면특성에 미치는 영향)

  • Jung, Gun;Nah, Chang-Woon;Seo, Min-Kang;Byun, Joon-Hyung;Lee, Kyu-Hwan;Park, Soo-Jin
    • Polymer(Korea)
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    • v.36 no.5
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    • pp.612-616
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    • 2012
  • In this work, the effect of chemical treatments of multi-walled carbon nanotubes (MWNTs) on the mechanical interfacial properties of carbon fiber fabric-reinforced composites was investigated. The surface properties of the MWNTs were determined by acid and base values, Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS) analyses. The mechanical interfacial properties of the composites were assessed by interlaminar shear stress (ILSS) and critical stress intensity factor ($K_{IC}$). The chemical treatments based on acid and base reactions led to a significant change of surface characteristics of the MWNTs, especially A-MWNTs/carbon fibers/epoxy composites had higher mechanical properties than those of B-MWNTs and non-treated MWNTs/carbon fibers/epoxy composites. These results were probably due to the improvement of interfacial bonding strength, resulting from the acid-base interaction and hydrogen bonding between the epoxy resins and the MWNT fillers.

Optimization of Elastic Modulus and Cure Characteristics of Composition for Die Attach Film (다이접착필름용 조성물의 탄성 계수 및 경화 특성 최적화)

  • Sung, Choonghyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.4
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    • pp.503-509
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    • 2019
  • The demand for smaller, faster, and multi-functional mobile devices in increasing at a rapidly increasing rate. In response to these trends, Stacked Chip Scale Package (SCSP) is used widely in the assembly industry. A film type adhesive called die attach film (DAF) is used widely for bonding chips in SCSP. The DAF requires high flowability at high die attachment temperatures for bonding chips on organic substrates, where the DAF needs to feel the gap depth, or for bonding the same sized dies, where the DAF needs to penetrate bonding wires. In this study, the mixture design of experiment (DOE) was performed for three raw materials to obtain the optimized DAF recipe for low elastic modulus at high temperature. Three components are acrylic polymer (SG-P3) and two solid epoxy resins (YD011 and YDCN500-1P) with different softening points. According to the DOE results, the elastic modulus at high temperature was influenced greatly by SG-P3. The elastic modulus at $100^{\circ}C$ decreased from 1.0 MPa to 0.2 MPa as the amount of SG-P3 was decreased by 20%. In contrast, the elastic modulus at room temperature was dominated by YD011, an epoxy with a higher softening point. The optimized DAF recipe showed approximately 98.4% pickup performance when a UV dicing tape was used. A DAF crack that occurred in curing was effectively suppressed through optimization of the cure accelerator amount and two-step cure schedule. The imizadole type accelerator showed better performance than the amine type accelerator.

Design of Hazardous Fume Exhaust System in Vacuum Pressure Impregnation Process Using CFD (CFD를 이용한 진공가압함침공정 내 유해가스 배출시스템 설계)

  • Jang, Jungyu;Yoo, Yup;Park, Hyundo;Moon, Il;Lim, Baekgyu;Kim, Junghwan;Cho, Hyungtae
    • Korean Chemical Engineering Research
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    • v.59 no.4
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    • pp.521-531
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    • 2021
  • Vacuum Pressure Impregnation (VPI) is a process that enhances physical properties by coating some types of epoxy resins on windings of stator used in large rotators such as generators and motors. During vacuum and pressurization of the VPI process, resin gas is generated by vaporization of epoxy resin. When the tank is opened for curing after finishing impregnation, resin gas is leaked out of the tank. If the leaked resin gas spreads throughout the workplace, there are safety and environmental problems such as fire, explosion and respiratory problems. So, exhaust system for resin gas is required during the process. In this study, a case study of exhaust efficiency by location of vent was conducted using Computational Fluid Dynamics (CFD) in order to design a system for exhausting resin gas generated by the VPI process. The optimal exhaust system of this study allowed more than 90% of resin gas to be exhausted within 1,800 seconds and reduced the fraction of resin gas below the Low Explosive Limit (LEL).

Analytical Study on Vibrational Properties of High Damping Polymer Concrete (고 감쇠 폴리머 콘크리트의 진동 특성에 관한 해석적 연구)

  • Kim, Jeong-Jin;Kim, Jong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.5
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    • pp.119-125
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    • 2020
  • Research on high-attenuation concrete for the vibration reduction performance by mixing epoxy-based synthetic resins and aggregates is actively being conducted. The curing time of high-attenuation concrete is very short because water is not used, and the physical and dynamic properties are very excellent. therefore, it is expected to be widely used in building structures requiring reduction of interior-floor noise and vibration. Furthermore, A way to expand the applicability of the high-damping concrete mixed with polymer in the field of reinforcement material have been variously studied. In order to replace polymer concrete with ordirnary concrete and existing anti-vibration reinforcement material, it is necessary to review overall vibration reduction performance considering physical properties, dynamic properties, productivity and field applicability. In this study, the physical and dynamic properties of polymer concrete by epoxy mixing ratio compared with ordirnary concrete. As a result, the elastic modulus was similar. On the other hand, polymer concrete for the compressive, tensile, and flexural strengths was quite more excellent. In particular, the measured tensile strength of polymer concrete was 4-10 times higher than that of ordirnary concrete. it was a big difference, and the frequency response function and damping ratio was studied through modal test and finite element analysis model. The dynamic stiffness of polymer concrete was 20% greater than that of ordirnary concrete, and the damping ratio of polymer concrete was approximately 3 times more than that of ordirnary concrete.

The Study on the Synthesis of Urethane Polymer and Their Application for the Exclusive Use of Soil Layer Transcription and the 1st Transcript of Historical Site (유구 전사 및 토층 전사 전용 우레탄 수지의 합성과 그 적용에 관한 연구)

  • Han, Won-Sik;Wi, Koang-Chul
    • Journal of Conservation Science
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    • v.26 no.3
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    • pp.335-340
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    • 2010
  • Urethane resin applicable for the first transcription of historical site and transcription of soil layer were synthesized in order to replace the imported urethane resin, NS-10. Comparing to the NS-10, the urethane polymers showed similar penetration to wet soil and formed a stable layer of polyurethane during progress working the peeling off the polyurethane pre-product from epoxy surface of final product. The urethane resins used for the first transcription of historical site improved tensile strength, which is consistent with that of NS-10. In addition the urethane resin for transcription of soil layer was supplied with hardness that have a also same strong point as like NS-10. This property is advantage due to simplifying the transcription work of soil layer in backward. When we tested to the real ground soil as well as experimentation compressed soil with use these synthesis urethane resin, we ca get the satisfying result in penetration property and stability and these properties evaluated the resins as an advanced product serving better convenience for worker.

Conservation and Pedestal Stability Estimation of the Bukji-ri Stone Pensive Bodhisattva of Bonghwa (봉화 북지리 석조반가상의 보존 및 받침대 안정성 평가)

  • Chae, Woomin;Jang, Minkyeong;Yi, Younghee;Hwang, Hyunsung
    • Conservation Science in Museum
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    • v.17
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    • pp.85-100
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    • 2016
  • The Bukji-ri Stone Pensive Bodhisattva of Bonghwa in the collection of Kyungpook National University Museum was transported to the National Museum of Korea for display in a special exhibition('Masterpieces of Early Buddhist Sculpture 100 BCE - 700 CE') and therefore underwent conservation ahead of the exhibition's start date. The stone sculpture had visibly encrusted surface dirt, granular disintegration and fissures upon arrival. Notably, a crack running obliquely across its lower half rendered the object unable to support its own weight without a pedestal, so one was created in order to maintain the sculpture in an upright position while on exhibition. The sculpture was further examined using a polarizing microscope and a stereoscopic microscope. SEM-EDS resulted in petrographic analysis of the stone's mineral composition and identification of its surface contaminants. Polarizing light microscopy confirmed biotite granite as the main mineral component of the object. Several urethane resins cast in round cross-sections were inserted into the newly made pedestal and stability tests were perform to measure the frictional force of the resins. An additional test was performed to compare urethane resin and epoxy resin, with results showing urethane to have a higher coefficient of friction. Utilizing a pedestal with urethane resin effectively ensured the stability of the Bukji-ri Stone Pensive Bodhisattva of Bonghwa during the aforementioned exhibition.

Lateral Load Performance Evaluation of Larch Glulam Portal Frames Using GFRP-Reinforced Laminated Plate and GFRP Rod (GFRP 보강적층판 및 GFRP rod를 이용한 낙엽송 집성재 문형라멘 구조의 수평가력 성능평가)

  • Jung, Hong-Ju;Song, Yo-Jin;Lee, In-Hwan;Hong, Soon-Il
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.1
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    • pp.30-39
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    • 2016
  • The evaluation of the lateral load performance for larch glulam portal frames was carried out using glass fiber reinforced plastic (GFRP) as connector in two different systems: the GFRP-reinforced laminated plates combined with veneer, and GFRP rod joints glued with epoxy resins to replace usual metal connectors for the structural glulam rahmen joints. As a result the yield strength, ultimate strength, initial stiffness of glulams of GFRP rod joints glued with epoxy resin decreased to 49%, 52% and 61% compared to those of the conventional metal connector. This connector will be a stress device where the bonding strength between the GFRP rod and glued laminated timber is important. Thus, there will be a high possibility that a problem may occur when it is applied to the field. On the other hand, the GFRP-reinforced laminated plates and wood (Eucalyptus marginata) pin were measured all within 3% for all measurements of the yield strength, ultimate strength, initial strength and ductility factor, regardless of high cross sectional loss on the glued laminated timber slit joint. In addition, the variation of stiffness on the cycle was 35%, which was the lowest, confirming that it was almost the same performance as the specimen prepared with the metal connector.

A Study on the Anchorage Length of Metal Stiffeners for the Structural Reinforcement of Stone Cultural Heritages (석조문화재의 구조적 보강을 위한 금속보강재 정착길이 연구)

  • Kim, Sa-Dug;Lee, Dong-Sik;Kim, Hyun-Yong
    • Journal of Conservation Science
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    • v.28 no.2
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    • pp.141-151
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    • 2012
  • It was the 1900s that the damaged materials of stone heritages began to be preserved and managed for the purpose of reuse, especially since cement, an inorganic material, began to be used during the Japanese colonial period. Epoxy resin, an organic material, was introduced to architecture around the turn of the 1990s, and has been being used across the board. In particular, filler mixtures began to be aggressively used for the structural reinforcement of severed materials. The problem was metal stiffeners used for structural reinforcement. The anchorage length varied depending in different conservation scientists, and as a result the secondary damage was apt to occur in the materials. In this study, hereat, a calculation was made of the most effective anchorage length with the minimization of material damage. The results were as in the following: the anchorage length of an 8-milimeter-across (ø8) metal stiffener was found to be most effective at 60.88mm. Those of ø12 and ø16 were 60.88mm and 91.32mm respectively. In the case of other calibers, the anchorage length was calculated by a formula ${\ell}_d=a_tf_y/u{\Sigma}_0$. In the experiment, helically-threaded round bars were used as metal stiffeners in order that they could bear surcharge loads such as bending, shear and constriction.

Effect of Die Attach Film Composition for 1 Step Cure Characteristics and Thermomechanical Properties (다이접착필름의 조성물이 1단계 경화특성과 열기계적 물성에 미치는 영향에 관한 연구)

  • Sung, Choonghyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.12
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    • pp.261-267
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    • 2020
  • The demand for faster, lighter, and thinner portable electronic devices has brought about a change in semiconductor packaging technology. In response, a stacked chip-scale package(SCSP) is used widely in the assembly industry. One of the key materials for SCSP is a die-attach film (DAF). Excellent flowability is needed for DAF for successful die attachment without voids. For DAF with high flowability, two-step curing is often required to reduce a cure crack, but one-step curing is needed to reduce the processing time. In this study, DAF composition was categorized into three groups: cure (epoxy resins), soft (rubbers), hard (phenoxy resin, silica) component. The effect of the composition on a cure crack was examined when one-step curing was applied. The die-attach void and flowability were also assessed. The cure crack decreased as the amount of hard components decreased. Die-attach voids also decreased as the amount of hard components decreased. Moreover, the decrease in cure component became important when the amount of hard component was small. The flowability was evaluated using high-temperature storage modulus and bleed-out. A decrease in the amount of hard components was critical for the low storage modulus at 100℃. An increase in cure component and a decrease in hard component were important for the high bleed-out at 120℃(BL-120).