• Korean Chemical Engineering Research
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• 제53권4호
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• pp.425-430
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• 2015

고분자 복제방법을 이용하여 제조한 폼 형태의 다공성 탄화규소 표면에 수열 합성 방법을 적용하여 ZSM-5를 합성하였다. 다공성 탄화규소 표면으로부터 ZSM-5가 합성될 수 있도록 유도하기 위하여 합성단계에 앞서 탄화규소 표면에 산화 층을 형성하였다. 수열합성 반응은 산화처리 된 다공성 탄화규소와 TEOS, $Al(NO_3){\cdot}9H_2O$ 및 TPAOH를 원료로 사용하여 $150^{\circ}C$에서 7시간 진행하였다. XRD 및 SEM 분석을 통하여 $1{\sim}3{\mu}m$ 크기의 ZSM-5가 다공성 탄화규소 표면에 코팅되어 성장하였음을 확인하였다. BET 분석결과 ZSM-5 합성 후에 $10{\AA}$이하의 미세기공이 급격히 증가하였으며, 비표면적이 $0.83m^2/g$에서 $30.75m^2/g$으로 급격히 증가되었음을 알 수 있었다.

• Advances in environmental research
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• 제2권3호
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• pp.167-177
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• 2013

We investigated that removal of aqueous U(VI) by nano-sized Zero Valent Iron (nZVI) and Fe(II) bearing minerals (controls) in this study. Iron particles showed different U(VI) removal efficiencies (Mackinawite: 99%, green rust: 95%, nZVI: 91%, magnetite: 87%, pyrite: 59%) due to their different PZC (Point of Zero Charge) values and surface areas. In addition, noticeable amount of surface Fe(II) (181 ${\mu}M$) was released from nZVI suspension in 6 h and it increased to 384 ${\mu}M$ in the presence of U(VI) due to ion-exchange of U(VI) with Fe(II) on nZVI surface. Analysis of Laser-Induced Breakdown Detection (LIBD) showed that breakdown probabilities in both filtrates by 20 and 200 nm sizes was almost 24% in nZVI suspension with U(VI), while 1% of the probabilities were observed in nZVI suspension without U(VI). It indicated that Fe(II) colloids in the range under 20 nm were generated during the interaction of U(VI) and nZVI. Our results suggest that Fe(II) colloids generated via ion-exchange process should be carefully concerned during long-term remediation site contaminated by U(VI) because U could be transported to remote area through the adsorption on Fe(II) colloids.

• 한국환경과학회지
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• 제16권9호
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• pp.1091-1098
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• 2007

Activated carbon was prepared from waste citrus peels by chemical activation with $ZnCl_2$. The optimal condition of carbonization was at $300^{\circ}C$ for 1.5 hr. Activation experiments with carbonized samples prepared at optimal carboniztion condition were carried out under various conditions such as activation temperature of 400 to $900^{\circ}C$, activation time of 0.5 to 2.0 hr, and $ZnCl_2$ ratio of 100 to 300%. In order to investigate the physical properties of the activated carbons prepared, iodine adsorptivities and specific surface areas were measured and their morphologies were observed from scanning electron microscopy. As $ZnCl_2$ ratio increased, activation yield decreased, while iodine adsorptivity and specific surface area increased. The optimal condition of activation was at 300% $ZnCl_2$ ratio and $300^{\circ}C$ for 1.5 hr, and then iodine adsorptivity and specific surface area was measured as about 862 mg/g and $756m^2/g$, respectively. SEM photography showed that the surface morphology was changed and many active pore were produced by chemical activation.

• 한국환경보건학회지
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• 제38권5호
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• pp.424-430
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• 2012

Objective: The purpose of this study was to present the standard deviation of the elemental normalization of concentration of selected heavy metals in the surface sediment of Lake Paldang. Methods: Grain size dependency of selected heavy metal concentrations in the surface sediments of Lake Paldang was analyzed by the extrapolation method. The heavy metal concentrations were the sum of all fractions. Results: Cd and Cu showed an increase of the coefficient of determination($r^2$) in the fractional content of particle size, from <256 ${\mu}m$ to <20 ${\mu}m$, and a decrease from <20 ${\mu}m$ to <1 ${\mu}m$. The normalized concentration of Cd and Cu by extrapolation at 50% <20 ${\mu}m$ were 0.8 mg/kg, 37.0 mg/kg, 57.6 mg/kg and 201.7 mg/kg respectively. Conclusions: The normalized concentrations in the sediment of Lake Paldang are 1.5-2.0 times higher than mean average concentration. We concluded that in interpretation of heavy metal concentration in the sediment of Lake Paldang, normalization of grain size dependency should be considered.

• 한국환경과학회지
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• 제20권1호
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• pp.93-106
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• 2011

Physically-based resampling scheme for roughness coefficient of surface runoff considering the spatial landuse distribution was suggested for the purpose of effective operational application of recent grid-based distributed rainfall runoff model. Generally grid scale(mother scale) of hydrologic modeling can be greater than the scale (child scale) of original GIS thematic digital map when the objective basin is wide or topographically simple, so the modeler uses large grid scale. The resampled roughness coefficient was estimated and compared using 3 different schemes of Predominant, Composite and Mosaic approaches and total runoff volume and peak streamflow were computed through distributed rainfall-runoff model. For quantitative assessment of biases between computational simulation and observation, runoff responses for the roughness estimated using the 3 different schemes were evaluated using MAPE(Mean Areal Percentage Error), RMSE(Root-Mean Squared Error), and COE(Coefficient of Efficiency). As a result, in the case of 500m scale Mosaic resampling for the natural and urban basin, the distribution of surface runoff roughness coefficient shows biggest difference from that of original scale but surface runoff simulation shows smallest, especially in peakflow rather than total runoff volume.

• 환경생물
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• 제25권3호
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• pp.205-214
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• 2007

Marine environmental characteristics on the dinoflagellate cysts distribution in surface sediment of the southwest sea of Korea were investigated from 21 stations in September 2003, and 36 stations in June, 2004. The water mass characteristics indicated that the southwest sea of Korea is characterized by various oceanographic conditions due to coastal waters of Korea and China. The Tsushima warm currents and the cold bottom water of the Yellow Sea. Mud contents and chlorophyll a concentrations were higher in central region such as, Namhaedo, Yeosu and Goheung coast than in western region such as, Wando, Haenam and Jindo coast in the South Sea of Korea. A total of 35 taxa of dinoflagellate cysts were identified representing 21 genera, 33 species, 2 unidentified species. Cyst abundance ranged from 13 to 527 cysts $g-dry^{-1}$, showing higher abundance in the coastal areas than in western region of the South Sea of Korea. From the result of the PCA analysis, the distribution of dinoflagellate cysts was not only related to the different water masses which appeared in the southwestern sea but also to physical and biological parameters such as water temperature, light, surface sediment faces and phytoplankton biomass.

• 한국환경과학회지
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• 제16권10호
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• pp.1127-1137
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• 2007

We focused on effects on data assimilation of simulated wind fields by using upper-air observations (wind profiler and sonde data). Local Analysis Prediction System (LAPS), a type of data assimilation system, was used for wind field modeling. Five cases of simulation experiments for sensitivity analysis were performed: which are EXP0) non data assimilation, EXP1) surface data, EXP2) surface data and sonde data, EXP3) surface data and wind profiler data, EXP4) surface data, sonde data and wind profiler data. These were compared with observation data. The result showed that the effects of data assimilation with wind profiler data were found to be greater than sonde data. The delicate wind fields in complex coastal area were simulated well in EXP3. EXP3 and EXP4 using wind profiler data with vertically high resolution represented well sophisticated differences of wind speed compared with EXP1 and EXP2, this is because the effects of wind profiler data assimilation were sensitively adjusted to first guess field than those of sonde observations.

• 한국해양학회지:바다
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• 제18권1호
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• pp.32-39
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• 2013

인공위성은 넓은 지역에 대한 전 세계의 정보를 획득하는데 유용하지만, 좁은 지역에 대한 적시적소에 촬영하는 데는 한계가 있다. 이러한 단점을 극복하기 위하여 본 연구에서는 항공기 원격탐사 시스템을 구축하였다. 항공기 원격탐사시스템은 SAR센서와 열적외선 센서로 구성되어 있으며, 획득된 자료의 방사 및 기사보정을 위하여 GPS, IMU, 온도/습도계 등도 설치하였다. SAR영상은 표면 거칠기에 따라 민감하게 반응하여 밝기 값이 달라지게 되며, 해양에서는 바람에 의해 쉽게 생성 되는 표면 장력파의 진폭이 이러한 표면 거칠기를 야기한다. 따라서 정량화된 SAR의 후방산란과 해상풍 사이의 관계식을 통해 해상풍 추출이 가능하다. 한편, 열적외선 센서는 물체의 온도를 측정하는데 유용하며, 물체와 센서 사이의 대기에 의한 효과를 보정한 후 수온 추출이 이루어진다. 이 두 센서를 탑재한 항공기로 서해안 일대를 4차례 시험비행을 수행하였으며, 이로부터 획득된 SAR 및 열적외선 영상의 품질이 연안환경 모니터링 및 해양기상 자료 추출에 충분함을 보여주었다.

• 한국환경과학회:학술대회논문집
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• 한국환경과학회 2002년도 봄 학술발표대회 발표논문집
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• pp.452-454
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• 2002

A biosurfactant-producing microorganism, .Pseudomouos sp. EL-G527 was isolated from activated sludge by enrichment culture when grown on mineral salt medium containing n-hexadecane as a carbon source. The biosurfactant from .Pseudomonar sp. EL-G527 exhibited lesser toxicity to bacterial population than synthetic surfactants and in the biodegradation test, biosurfactant was rapidly degraded and lost its activity as surface active material after 1 day incubation. In this study, the biosurfactant from Pseudomonas sp. EL-G527 was effective surface-active compound, more biodegradable and less toxic to microbial ecosystem than various synthetic surfactants.

• 한국막학회:학술대회논문집
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• 한국막학회 2004년도 Proceedings of the second conference of aseanian membrane society
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• pp.25-28
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• 2004

In recent years, membranes have become fully or partially integrated into all facilities that produce drinking water since membrane processes can resolve technically complex and, at times, conflicting requirements related to compliance with multi-contaminant regulations. However, NF or RO technologies are hydraulically limited by the feed water quality that causes the fouling in a membrane system. In particular, NF or RO systems involved in surface water treatment generally require extensive pretreatment for controlling membrane fouling.(omitted)