• Resources Recycling
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• v.22 no.3
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• pp.28-35
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• 2013

The recycling of the Si/SiC mixture sludge obtained from solar cell industry is very significant, environmentally and economically. The sintering characteristics of Si/SiC mixture sludge was studied for the purpose of recycling. In this study, to understand sintering behavior, SiC content in the Si/SiC mixture was controlled using an air separator. Various Si/SiC mixtures having different SiC contents were sintered using carbon black, clay and aluminum hydroxide as sintering aids. Physical properties of Si/SiC mixture and sintered bodies have been characterized using SEM, XRD, particle size analyzer and apparent density measurement. SEM and particle size analysis result confirmed that the fine particles less than 1 ${\mu}m$ decreased or removed more effectively through the air separator in the case of 95% SiC sample compared than the case of 75% SiC sample or original SiC sample. Further, with addition of the Aluminum Hydroxide, ${\beta}$-cristobalite phase gradually decreased while mullite phase gradually increased. The addition of the carbon black improved the sintering characteristics.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.22 no.3
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• pp.200-208
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• 2012

Objectives: This study investigated the performance of three separate units of a portable photoionization detector (PID, ppb-RAE 3000) for measuring volatile organic compounds (VOCs) in a laboratory. Methods: A laboratory evaluation of the accuracy, precision, and inter-instrumental variance of three separate units of a portable PID (ppb-RAE 3000) was performed. The evaluation was based on the preparation of a test air sample of known toluene or ethylacetate concentration in a Tedlar$^{(R)}$ bag. The test air sample was monitored and data were logged consecutively by the three PIDs. A certified gas of 50 ppm toluene was also monitored during the test to ensure the reliability of the generated test air sample. Four different concentrations ranging from 0.1 to 2 TLV were used and a series of five measurements for each concentration level was performed. The accuracy was evaluated using National Institute for Occupational Safety and Health (NIOSH) criteria. Results: The results from the oldest ppb-RAE3000 unit among the three test units generally fell outside the NIOSH recommended accuracy criteria of ${\pm}25%$, whereas the other two units produced results which were acceptable at, or greater than, 25 ppm of toluene, or 0.5 TLV. These units also met the NIOSH criteria for some ethylacetate measurements but the results were not consistent. Conclusions: Considering the inconsistent performance of these ppb-RAE 3000 units, this device may not be appropriate for use as an alternative to the standard measurement methods. However, it can serve good survey instruments to identify exposure sources or concentration profiles. For all applications, the ppb-RAE 3000 should be used with frequent calibration checks, additional validation using a reference material, and careful maintenance.

• Journal of Environmental Impact Assessment
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• v.32 no.5
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• pp.353-362
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• 2023

TOC, which can measure more than 90% of organic substances, can be measured quickly and easily,replacing BOD and COD, which were indicators of organic pollutants. According to water quality pollution control standards, when measuring TOC, if the inorganic carbon ratio in the sample is over 50%, the NPOC (Non-Purgeable Organic Carbon) method should be used. If volatile organic compounds (VOCs) are present at a certain concentration, the TC-IC (subtracting inorganic carbon from total carbon) method should be used. To validate the limitations of these analytical conditions, experiments were conducted by varying the ratio of TOC to IC in purified water and measuring the concentration of TOC in test solutions. The results showed no significant difference between the TC-IC method and the NPOC method. When measuring samples with added VOC standard solutions, it was observed that the carbon loss due to purging was not significant when using the NPOC method. Therefore, it is concluded that the choice of analytical method does not lead to significant differences when VOCs are present in the sample. To account for potential variations in results based on water quality pollution control standards and regulations regarding the approval and testing of environmental measurement devices, a comparison of field sample concentration values was made using two widely used types of TOC analyzers in Korea. The results showed variations of 0.02 to 0.83 mg/L between methods depending on the manufacturer, highlighting the need for caution when selecting an instrument.

• Analytical Science and Technology
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• v.20 no.4
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• pp.261-267
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• 2007

The 20 L small chamber test method is to evaluate pollutants such as TVOC, formaldehyde emitted from building materials. This method was only designed to evaluate the surface emission of sample exposed in the chamber. In this method, building materials cut with a fixed standard size are fixed in a sample sealing box. The sample sealing box is put into the 20 L test chamber. This chamber is ventilated at a standard air change rate with purified air for 7 days then the sample from the chamber is collected and analyzed to measure the emission rate of TVOC and formaldehyde. In this method, however, if the sealing box does not guarantee airtightness, accurate evaluation for the building materials can not be achieved due to the pollutants emitted from edge of the sample so called, edge effect. This edge effect can be much greater when evaluating panels such as plywood, flooring due to their surface treatment. In this study, flooring was tested to check airtightness of the sample sealing box with analytic results between 1L and 20 L test chamber. Furniture materials like LPM coated one side surface treatment and MDF coated both sides surface treatment with LPM were tested to identify whether the improvement of the sample sealing box airtightness is possible with the comparison between existing and improved test method that low VOC emission tape was used to seal the sample edge. After 7 days, MDF TVOC emission rate was different according to the existence and nonexistence of tape. The emission rate of the existing test method was $0.009mg/m^2h$ and that of improved test method was $0.003mg/m^2h$. Relative standard deviation for the existing test method was $0.004mg/m^2h$ and relative standard deviation for the improved test method was $0.002mg/m^2h$ when the same sample was analyzed three times. The improved test method in this study using low VOC emission tape was effective and able to reduce the heterogeneous effect of the edge from the sample sealing box.

• Applied Chemistry for Engineering
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• v.27 no.4
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• pp.407-414
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• 2016

Ex-situ catalytic pyrolysis of a Korean native oak tree over microporous zeolites (HZSM-5, HBeta, and HY) was performed by using a fixed bed reactor. The effect of sample to catalyst ratio and reaction temperature was also investigated to optimize production conditions of high quality bio-oil. Among three catalysts, HZSM-5 showed the highest aromatic formation due to its proper pore size and strong acidity. Although HY and HBeta also showed the catalytic activity, they produced larger amounts of coke due to their larger pore size. The smaller ratio of the sample to the catalyst and higher reaction temperature were also required to maximize the yields of aromatic hydrocarbons via the catalytic pyrolysis of oak tree over HZSM-5.

• Analytical Science and Technology
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• v.13 no.6
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• pp.693-698
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• 2000

The object of this series of experiments was aimed for the systematic and long-term radioactivity monitoring through indirect search of C-14 concentration level changes in the natural conditions around the operating nuclear facilities. The result of environmental radioactivity level through tree-ring analysis is increased after operating nuclear facilities and such a level can be proved to relate power generation closely. The measured result of ${\delta}^{13}C$ through the treatment of cellulose can be showed the level -30‰. This figure is very different from one which is measured the -17‰ of air sample by passive air sampling and -8‰ of air sample by active air sampling. And these differences can be assumed as isotope fractionation by photosynthesis, but the problem is more study as needed.

• Membrane and Water Treatment
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• v.10 no.6
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• pp.471-484
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• 2019

The complex combination of organic contaminants in the wastewater made water treatment challenging; hence, organic matter in water bodies is usually measured in terms of organic carbon. Since it is important to identify the types of compounds when deciding suitable treatment methods, this study implemented a quantitative and qualitative analysis of the organic matter content in an actual graywater sample from Ulsan, Republic of Korea using mass spectroscopy (MS). The graywater was treated using adsorption to remove the organic contaminants. Using orbitrap MS, the organic matter content between an untreated graywater and the treated effluent were compared which yielded a significant formula count difference for the samples. It was revealed that CHON formula has the highest removal count. Isotherm studies found that the Freundlich equation was the best fit with a coefficient of determination ($R^2$) of 0.9705 indicating a heterogenous GAC surface with a multilayer characteristic. Kinetics experiments fit the pseudo-second order equation with an $R^2$ of 0.9998 implying that chemisorption is the rate-determining step between the organic compounds and GAC at rate constant of $52.53g/mg{\cdot}h$. At low temperatures, the reaction between GAC and organic compounds were found to be spontaneous and exothermic. The conditions for optimization were set to achieve a maximum DOC and TN removal which yielded removal percentages of 94.59% and 80.75% for the DOC and TN, respectively. The optimum parameter values are the following: pH 6.3, 2.46 g of GAC for every 30 mL of graywater sample, 23.39 hrs contact time and $38.6^{\circ}C$.

• Journal of Climate Change Research
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• v.9 no.4
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• pp.385-398
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• 2018

Although the importance of developing reliable and systematic GHG inventory has increased, the GIS/RS-based national scale LULUCF (Land Use, Land-Use Change and Forestry) sector analysis is insufficient in the context of the Paris Agreement. In this study, the change in $CO_2$ storage of forest land due to land use change is estimated using two GIS/RS methodologies, Sampling and Wall-to-Wall methods, from 2000 to 2010. Particularly, various imagery with sampling data and land cover maps are used for Sampling and Wall-to-Wall methods, respectively. This land use matrix of these methodologies and the national cadastral statistics are classified by six land-use categories (Forest land, Cropland, Grassland, Wetlands, Settlements, and Other land). The difference of area between the result of Sampling methods and the cadastral statistics decreases as the sample plot distance decreases. However, the difference is not significant under a 2 km sample plot. In the 2000s, the Wall-to-Wall method showed similar results to sampling under a 2 km distance except for the Settlement category. With the Wall-to-Wall method, $CO_2$ storage is higher than that of the Sampling method. Accordingly, the Wall-to-Wall method would be more advantageous than the Sampling method in the presence of sufficient spatial data for GHG inventory assessment. These results can contribute to establish an annual report system of national greenhouse gas inventory in the LULUCF sector.

• Geomechanics and Engineering
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• v.31 no.5
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• pp.461-476
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• 2022

Research studies on the scale effect on triaxial strength of intact rocks are scarce, being more common those in uniaxial strength. In this paper, the authors present and briefly interpret the peak and residual strength trends on a series of triaxial tests on different size specimens (30 mm to 84 mm diameter) of an intact granitic rock at confinements ranging from 0 to 15 MPa. Peak strength tends to grow from smaller to standard-size samples (54 mm) and then diminishes for larger values at low confinement. However, a slight change in strength is observed at higher confinements. Residual strength is observed to be much less size-dependent. Additionally, this study introduces preliminary modelling approaches of these laboratory observations with the help of three-dimensional particle flow code (PFC3D) simulations based on bonded particle models (BPM). Based on previous studies, two modelling approaches have been followed. In the first one, the maximum and minimum particle diameter (D_max and D_min) are kept constant irrespective of the sample size, whereas in the second one, the resolution (number of particles within the sample or ϕ_v) was kept constant. Neither of these approaches properly represent the observations in actual laboratory tests, even if both of them show some interesting capabilities reported in this document. Eventually, some suggestions are provided to proceed towards improving modelling approaches to represent observed scale effects.

• Journal of Korean Home Economics Education Association
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• v.10 no.2
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• pp.1-11
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• 1998

The purpose of this study is to analyze highschool girls' concerns about environmental problems after investigating the actual state of environmental education and to suggest some fundamental changes in the Home Economics classes to improve environmental education. The sample was selected form high school girl students in Kyounggi Province between September 16 and September 26, 1996. Eight hundred twenty (820) first and second grade respondents were used. The data were analyzed by frequency, mean, percentile, factor analysis. Duncan's Multiple Range Test, and Stepwise Multiple Regression. Based on the major findings, the most influential variable was parental attitudes towards environmental conservation and problem. Next in influence was the environmental education provided in Home Economics classes. Also important were the individual student's interest in Home Economics classes, and her belief in the utility of environmental conservation in everyday life. The research conclusions are as follows: 1. We'll find how to relate efficiently the environmental education with everyday life by analyzing thoroughly the text of home economics. 2. We'll develop how to educate students parents properly because parental attitudes to wards the environmental problem have a great effect on students' behaviors. 3. We'll ceinforce environmental education by developing problems, and to motivate them to take real action in the area of environmental conservation.