• Journal of the Korean Applied Science and Technology
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• v.34 no.3
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• pp.683-693
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• 2017

Transport biofuels have been recognized as a promising means to resolve the following issues like global warming, oil depletion and environmental pollutions. Among various biofuels, biodiesel has several advantages such as less emission of air pollutants and higher cetane values compared to diesel oil. Demand for biodiesel in Korea is increasing that leads to higher dependence on the imported feedstocks. Therefore, it is important to utilize the waste materials collected domestically for biodiesel production. Food waste oil collected in waste treatment facility has not been used for biodiesel production due to high free fatty contents in the oil. In this work, biodiesel conversion of food waste oil by Amberlyst 15 was studied. Synthetic and actual food waste oils have been used in the study. First, the effects of the major operating parameters including reaction temperature, methanol to oil molar ratio and catalyst loading on the conversion rates and yields were determined with synthetic waste oil. Kinetic modelling work was also done to determine the activation energy of the reaction. From the work, optimization reaction conditions were determined to be 383K, 1: 26.1 for methanol molar ratio to oil, 10 wt.% for catalyst loading and 360 min for reaction time. Activation energy of the reaction is determined to be 29.75 kJ/mol, lower than those reported in the previous works. So the solid catalyst, Amberlyst 15, was more efficient for esterification than the solid catalysts employed in the other works. Agitation rates have the negligible effects on the conversion rates and yields. With the identified optimization conditions, conversion of the actual food waste oil was also carried out. The esterification yield of actual food waste oil in 60 min was 13% lower than that of synthetic waste oil but the final yields in 240 min were similar each other, 98.12% for synthetic oil and 97.62% for actual waste oil.

• Journal of Korean Society of Environmental Engineers
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• v.37 no.12
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• pp.696-704
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• 2015

This study was carried out to evaluate the optimum operational condition of Semi-continuously Fed and Mixed Reactor (SCFMR) to treat the dairy cow manure and saw dust mixture. Step-wise increase in organic loading rates (OLRs) or decrease in hydraulic retention times (HRTs) were utilized until the biogas volume became significantly decreased at mesophilic temperature ($35^{\circ}C$). The optimum operating condition of the SCFMR fed with TS 13% dairy cow manure and saw dust mixture was found to be an HRTs of 25 days and its corresponding OLRs of $4.45kg\;VS/m^3-day$. At this condition the biogas and methane production rates were 1.44 v/v-d and 1.12 v/v-d (volume of biogas per volume of reactor per day), respectively and the TVS removal efficiency of 37% was achieved. The successful operation with such a high OLR was due to the high reactor alkalinity concentration of 14,500~15,600 mg/L as $CaCO_3$ as a result of the characteristic of the original substrate, dairy cow manure and saw dust mixture whose alkalinity was more than 8,000 mg/L as $CaCO_3$. The parameters for the reactor stability, the ratios of volatile acids and alkalinity concentrations (V/A) and the ratio of propionic acid and acetic acid concentrations (P/A) appeared to be 0.11 and 0.43, respectively, that were greatly stable in operation. Free ammonia toxicity was not experienced due to the long term acclimation by the reactor TS content ranged 7.2~10.4% during the entire operational period.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.9
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• pp.1035-1043
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• 2007

A leachate containing an elevated concentration of organic and inorganic compounds has the potential to contaminate adjacent soils and groundwater as well as downgradient areas of the watershed. Moreover high-strength ammonium concentrations in leachate can be toxic to aquatic ecological systems as well as consuming dissolved oxygen, due to ammonium oxidation, and thereby causing eutrophication of the watershed. In response to these concerns landfill stabilization and leachate treatment are required to reduce contaminant loading sand minimize effects on the environment. Compared with other treatment technologies, leachate recirculation technology is most effective for the pre-treatment of leachate and the acceleration of waste stabilization processes in a landfill. However, leachate recirculation that accelerates the decomposition of readily degradable organic matter might also be generating high-strength ammonium in the leachate. Since most landfill leachate having high concentrations of nitrogen also contain insufficient quantities of the organic carbon required for complete denitrification, we combined a shortcut biological nitrogen removal (SBNR) technology in order to solve the problem associated with the inability to denitrify the oxidized ammonium due to the lack of carbon sources. The accumulation of nitrite was successfully achieved at a 0.8 ratio of $NO_2^{-}-N/NO_x-N$ in an on-site reactor of the sequencing batch reactor (SBR) type that had operated for six hours in an aeration phase. The $NO_x$-N ratio in leachate produced following SBR treatment was reduced in the landfill and the denitrification mechanism is implied sulfur-based autotrophic denitrification and/or heterotrophic denitrification. The combined leachate recirculation with SBNR proved an effective technology for landfill stabilization and nitrogen removal in leachate.

• International Journal of Highway Engineering
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• v.13 no.2
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• pp.103-114
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• 2011

Usage of bicycle has been supported the universal reduction of energy consumption and $CO_2$. For the same purpose, new constructions for long length bike roads are planned in Korea. Recently, laboratory tests of physical properties and resistance against environmental loading about optimum mix design of roller compacted concrete, that have advantages of high structural performance by cement hydration and aggregate interlocking, simple construction procedure and low construction cost, are performed for the effective construction of new bike roads. However, properties of roller compacted concrete had different results between laboratory and field tests since it had different compaction method. Also, construction method of roller compacted concrete are not defined for the application of bike roads since it had different demand performance such as thin pavement thickness, low strength and etc with road pavements. Thus, in this experimental research was launched to evaluate the core properties, visual inspection, compaction ratio, water content, thickness reduction rate of roller compaction, skid resistance and roughness by experimental construction about variable mix proportion and compaction method based on laboratory test results. And construction method of roller compacted concrete pavement were suggested for the application of bike roads.

• Journal of the Korea Concrete Institute
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• v.18 no.5 s.95
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• pp.595-602
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• 2006

An experimental study was conducted to investigate seismic behaviour of post-tensioned(PT) exterior slab-column connections used for the purpose to resist gravity loads only. For these, 2/3-scale, two PT post-tensioned exterior connections with two different tendon arrangement patterns and one conventional reinforced concrete(RC) exterior connection was tested under quasi-static, uni-directional reversed cyclic loading. During the lateral testing, gravity forces transferred to the column were kept constant to closely simulate a moment to shear ratio of a real building. One of the objectives of this study was to assess the necessity and/or the quantity of bottom bonded reinforcement needed to resist moment reversal which would occur under significant inelastic deformations of the adjacent lateral force resisting systems. The ACI 318 and 352 provisions for structural integrity were applied to provide the bottom reinforcement passing through the column for the specimens. Prior test results were also collected to conduct comparative studies for some design parameters such as the tendon arrangement pattern, the effect of post-tensioning forces and the use of bottom bonded reinforcement. Consequently, the impact of tendon arrangement on the seismic performance of the PT connection, that is lateral drift capacity and ductility, dissipated energy and failure mechanism, was considerable. Moreover, test results showed that the amount of bottom reinforcement specified by ACI 352. 1R-89 was sufficient for resisting positive moments arising from moment reversal under reversed cyclic loads. Shear strength of the tested specimens was more accurately predicted by the shear strength equation(ACI 318) considering the average compressive stress over the concrete($f_{pc}$) due to post-tensioning forces than that without considering $f_{pc}$.

• Journal of the Korea Concrete Institute
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• v.27 no.3
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• pp.291-298
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• 2015

In this paper, a bundled diagonal reinforcement using high performance steel fiber was proposed to enhance the construct ability and seismic performance. Experiments of coupling beam was composed of four specimens and the hysteretic behavior evaluated for reverse cyclic loading to specimens using high performance steel fiber. The main variables of the experiment is a amount of stirrup and bundled reinforcement, depending on whether the mix of steel fiber. Specimen which criteria was applied 100% of stirrup and bundled diagonal reinforcement of ACI318 criteria. With this, by appling same diagonal reinforcement, two specimens were created by adjusting stirrup of 75%, 50%. So, a total of four specimens were produced. When coupling beam was placed concrete, this experiment was mixed in a content of steel fiber 1%. All the specimens were produced by aspect ratio 3.5(l/h=1050/300) to a half-scale. In this result, two specimens as reduced to stirrup of 75%, 50% was no significant difference in the strength, stiffness and energy dissipation capacity, respectively compared to the stirrup of 100%.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.2 no.1
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• pp.19-31
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• 1982

The purpose of the research is to investigate the applicability of the filter activated sludge process for the treatment of toxic phenolic wastewaters. The experiment for the research was carried out by continuously feeding synthetic phenol wastewater for four periods, and the results show that a synthetic fiber filter is an adequate material for filter activated sludge process when taking consideration of durability, SS removal efficiency and wastewater permeability. The permeability of the filter sharply decreases when the temperature of the reactor is below $10{\sim}15^{\circ}C$ for a long period. In filter activated sludge process, even under high volumetric loading conditions, high phenol removal efficiencies can be attained due to the high microbial sludge concentration in the reactor and consequently low F/M ratio. In this research, the effluent phenol concentration were checked to be below $0.1mg/{\ell}$ at the influent phenol concentrations of $63{\sim}468mg/{\ell}$. During the research very low microbial yield coefficients, 0.035~0.160 kg SS/kg COD removed, were observed and the temperature coefficient for aerobic sludge digestion was measured to be 1.021.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.12 no.2
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• pp.43-54
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• 1992

For shallow arches with large dynamic loading, linear analysis is no longer considered as practical and accurate. In this study, a method is presented for the dynamic analysis of shallow arches in which geometric nonlinearity must be considered. A program is developed for the analysis of the nonlinear dynamic behavior and for evaluation of critical buckling loads of shallow arches. Geometric nonlinearity is modeled using Lagrangian description of the motion. The finite element analysis procedure is used to solve the dynamic equation of motion and Newmark method is adopted in the approximation of time integration. A shallow arch subject to radial step loads is analyzed. The results are compared with those from other researches to verify the developed program. The behavior of arches is analyzed using the non-dimensional time, load, and shape parameters. It is shown that geometric nonlinearity should be considered in the analysis of shallow arches and probability of buckling failure is getting higher as arches are getting shallower. It is confirmed that arches with the same shape parameter have the same deflection ratio at the same time parameter when arches are loaded with the same parametric load. In addition, it is proved that buckling of arches with the same shape parameter occurs at the same load parameter. Circular arches, which are under a single or uniform normal load, are analyzed for comparison. A parabolic arch with radial step load is also analyzed. It is verified that the developed program is applicable for those problems.

• Analytical Science and Technology
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• v.17 no.3
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• pp.263-270
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• 2004

A method is described for the analysis of short-chain alkylphenol ethoxylates (APEOs), 4-octylphenol-di-ethoxylate (OP2EO) and 4-nonylphenol-di-ethoxylate (NP2EO), in drinking water or wastewater using reversed phase high-performance liquid chromatography with electrospray ionization mass spectrometry. The solvent system was water and methanol containing $10{\mu}M$ trifluoroacetic acid as an ionization solvent. We acidified 1 L of water samples to less than pH 2 with concentrated $H_2SO_4$ and loaded onto Sep-Pak $C_{18}$, and eluted with acetone. The calibration of OP2EO and NP2EO was performed for the concentration range from 20 to 500 ng/L and the correlation coefficients were 0.999 and 0.990, respectively. The limits of detection were 20 ng/L (OP2EO) and 50 ng/L (NP2EO) at a signal-to-noise ratio of 3. Accuracy and precision of this analytical method were 85.8 ~ 122.1% and 8.2 ~ 18.8%, respectively. The proposed method allowed a sensitive and rapid detection of OP2EO and NP2EO and it could be applied for monitoring of APEOs from environmental samples.

• Journal of the Korean Geotechnical Society
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• v.28 no.4
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• pp.91-100
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• 2012

Soil-water characteristic curves (SWCCs), which represent a physical property in partially saturated soils, show the relation between volumetric water content and matric suction. The SWCCs exhibit hysteresis during wetting and drying, however experimental expressions used to describe SWCCs have generally ignored the hysteresis. In addition, the shape of SWCC may depend on the void ratio which is changed by soil skeleton deformations or hysteretic behavior under various loading conditions. Hence, it is necessary to understand, both empirically and analytically, the relationship between soil skeleton deformations and the SWCCs of various soils. The typical SWCCs experimentally have drying, wetting, and the second drying curve. The measurement of a complete set of hysteretic curves is severely time-consuming and difficult works, then the first drying curve of SWCC is generally determined to estimate the hydraulic conductivity and shear strength function of partially saturated soils. This paper presents the hydraulic-mechanical behavior of partially saturated soils (weathered soil and silty soil) for volume changes and hysteresis in SWCCs regarding the difference between the first drying and wetting curve.