• Title/Summary/Keyword: Entropy Decomposition

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Study on Decomposition Reactions of Poly(ethylene terephthalate) Films Treated with Mono-sodium Ethylene Glycolate (Mono-sodium ethylene glycolate에 의한 Poly(ethylene terephthalate) Film의 분해반응에 관한 연구)

  • Cho, Hwan;Huh, Man-Woo;Cho, In-Sul;Cho, Kyu-Min;Yoon, Hung-Soo
    • Textile Coloration and Finishing
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    • v.2 no.3
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    • pp.26-35
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    • 1990
  • This study was carried out with the view of fundamental investigating to improve the tactile and the hygroscopicity of Poly(ethylene Terephthalate) (PET)fibers. Mono-sodium ethylene glycolate in ethylene glycol (MSEG-EG) solution was prepared and PET films were treated with it. The following conclusions were obtained. When PET films were decomposed in MSEG-EG solution, decomposition rate constant showed an exponential relationship with treating temperature; activition energy was 23.30 Kcal/mol, activation enthalpy was 22.52~22.60 Kcal/mol and activation entropy was -29.20~ -29.41 e.u. On the basis of the results obtained above and structure identification of decomposition products, it was found that the decomposition reaction proceeded through ester interchange reaction.

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A Study on the Power Spectral Analysis of Background EEG with Pisarenko Harmonic Decomposition (Pisarenko Harmonic Decomposition에 의한 배경 뇌파 파워 스펙트럼 분석에 관한 연구)

  • Jung, Myung-Jin;Hwang, Soo-Young;Choi, Kap-Seok
    • Proceedings of the KIEE Conference
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    • 1987.07b
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    • pp.1271-1275
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    • 1987
  • With the stochastic process which consists of the harmonic sinusoid and the white nosie, the power spectrum of background EEG is estimated by the Pisarenko Harmonic Decomposition. The estimating results are examined and compared with the results from the maximum entropy spectral estimation, and the optimal order of this model can be determined from the eigen value's fluctuation of autocorrelation of background EEG. From the comparing results, this paper ensures that this method is possible to analyze the power spectrum of background EEG.

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Design of a Lossless Audio Coding Using Cholesky Decomposition and Golomb-Rice Coding (콜레스키 분해와 골롬-라이스 부호화를 이용한 무손실 오디오 부호화기 설계)

  • Cheong, Cheon-Dae;Shin, Jae-Ho
    • Journal of Korea Multimedia Society
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    • v.11 no.11
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    • pp.1480-1490
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    • 2008
  • Design of a linear predictor and matching of an entropy coder is the art of lossless audio coding. In this paper, we use the covariance method and the Choleskey decomposition for calculating linear prediction coefficients instead of the autocorreation method and the Levinson-Durbin recursion. These results are compared to the polynomial predictor. Both of them, the predictor which has small prediction error is selected. For the entropy coding, we use the Golomb-Rice coder using the block-based parameter estimation method and the sequential adaptation method with LOCO-land RLGR. The proposed predictor and the block-based parameter estimation have $2.2879%{\sim}0.3413%$ improved compression ratios compared to FLAC lossless audio coder which use the autocorrelation method and the Levinson-Durbin recursion. The proposed predictor and the LOCO-I adaptation method could improved by $2.2879%{\sim}0.3413%$. But the proposed predictor and the RLGR adaptation method got better results with specific signals.

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Real-time Acquisition of Three Dimensional NMR Spectra by Non-uniform Sampling and Maximum Entropy Processing

  • Jee, Jun-Goo
    • Bulletin of the Korean Chemical Society
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    • v.29 no.10
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    • pp.2017-2022
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    • 2008
  • Of the experiments to shorten NMR measuring time by sparse sampling, non-uniform sampling (NUS) is advantageous. NUS miminizes systematic errors which arise due to the lack of samplings by randomization. In this study, I report the real-time acquisition of 3D NMR data using NUS and maximum-entropy (MaxEnt) data processing. The real-time acquisition combined with NUS can reduce NMR measuring time much more. Compared with multidimensional decomposition (MDD) method, which was originally suggested by Jaravine and Orekhov (JACS 2006, 13421-13426), MaxEnt is faster at least several times and more suitable for the realtime acquisition. The designed sampling schedule of current study makes all the spectra during acquisition have the comparable resulting resolutions by MaxEnt. Therefore, one can judge the quality of spectra easily by examining the intensities of peaks. I report two cases of 3D experiments as examples with the simulated subdataset from experimental data. In both cases, the spectra having good qualitie for data analysis could be obtained only with 3% of original data. Its corresponding NMR measuring time was 8 minutes for 3D HNCO of ubiquitin.

Evaluation of Polarimetric Parameters for Flood Detection Using PALSAR-2 Quad-pol Data

  • Jung, Yoon Taek;Park, Sang-Eun;Baek, Chang-Sun;Kim, Dong-Hwan
    • Korean Journal of Remote Sensing
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    • v.34 no.1
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    • pp.117-126
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    • 2018
  • This study aims to evaluate the usability of polarimetric SAR measurements for discriminating water-covered area from other land cover types and to propose polarimetric parameters showing the better response to the flood. Flood-related changes in the polarimetric parameters were studied using the L-band PALSAR-2 quad-pol mode data acquired before and after the severe flood events occurred in Joso city, Japan. The experimental results showed that, among various polarimetric parameters, the HH-polarization intensity, the Shannon entropy, and the surfaces scattering component of model-based decomposition were found to be useful to discriminate water-covered areas from other land cover types. Particularly, an unsupervised change detection with the Shannon entropy provides the best result for an automated mapping of flood extents.

Maximum Entropy Power Spectral Estimation of Two-Dimensional Signal (2차원 신호의 최대 정보량을 갖는 전력 스펙트럼 추정)

  • Sho, Sang-Ho;Kim, Chong-Kyo;Lee, Moon-Ho
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.34 no.3
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    • pp.107-114
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    • 1985
  • This paper presents the iterative algorithm for obtaining the ME PSE(Maximum Entropy Power Spectral Estimation) of 2-dimensional signals. This problem involves a correction matching power spectral estimate that can be represented as the reciprocal of the spectral of 2-dimensional signals. This requires two matrix inversion every iterations. Thus, we compensate the matrix to be constantly positive definite with relaxational parameters. Using Row/Column decomposition Discrete Fourier Transform, we can decrease a calculation quantity. Using Lincoln data and white noise, this paper examines ME PSE algorithms. Finally, the results output at the graphic display device. The 2-dimensional data have the 3-dimensional axis components, and, this paper develops 3-dimensional graphic output algorithms using 2-dimensional DGL(Device Independent Graphic Library) which is prepared for HP-1000 F-series computer.

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Wavelet based Embedded Video Coding with 3-D Block Partition (3-D 블록분할을 이용하는 웨이브렛 기반 임베디드 비디오 부호화)

  • 양창모;임태범;이석필
    • Proceedings of the IEEK Conference
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    • 2003.11a
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    • pp.133-136
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    • 2003
  • In this paper, we propose a low bit-rate embedded video coding scheme with 3-D block partition in the wavelet domain. The proposed video coding scheme includes multi-level three dimensional dyadic wavelet decomposition, raster scanning within each subband, partitioning of blocks, and adaptive arithmetic entropy coding. Although the proposed video coding scheme is quite simple, it produces bit-streams with good features, including SNR scalability from the embedded nature. Experimental results demonstrate that the proposed video coding scheme is quite competitive to other good wavelet-based video coders in the literature.

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Crystal Structure and Thermal Decomposition Studies on Cobalt (II) Complex of 4-Chloro-2-((E)-(Isopropylimino)methyl)phenol (4-Chloro-2-((E)-(Isopropylimino)methyl)phenol 코발트(II) 착물에 대한 결정 구조 및 열분해 연구)

  • Pu, Xiao-Hua
    • Journal of the Korean Chemical Society
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    • v.55 no.3
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    • pp.341-345
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    • 2011
  • The Schiff base cobalt(II) complex, bis[4-chloro-2-((E)-(isopropylimino) methyl) phenol]cobalt(II), has been prepared and characterized by single-crystal X-ray diffraction analyses. The phenomenological, kinetic and mechanistic aspects of the cobalt (II) complex have been studied by TG/DTG techniques. On the basis of the experimental data, the kinetic parameters such as activation energy, pre-exponential factor and entropy of activation were computed, and then the most probable mechanism function was estimated as $g({\alpha})={\alpha}^2$ 2. Hence the rate controlling process at all stages of decomposition is onedimensional diffusion (Parabolic model).

A Study on the Alkali Hydrolysis of PET fabric with Ultrasonic Application(I) - Decomposition Rate Constant and Activation Energy - (초음파를 적용한 PET 직물의 알칼리 가수분해에 관한 연구(I) - 분해속도상수와 활성화 에너지-)

  • 서말용;조호현;김삼수;전재우;이승구
    • Textile Coloration and Finishing
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    • v.14 no.4
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    • pp.214-222
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    • 2002
  • In order to give a silk-like touch to PET fabrics, the PET fabrics were treated with NaOH alkaline solution in various conditions. In alkaline treatment, the liquor flow type pilot weight reduction apparatus with magnetostrictive ultrasonic transducer was used for the study. The weight loss of PET fabrics hydrolyzed in 4% and 6% NaOH solution, at $95^\circ{C}$ and $99^\circ{C}$ for 60min. with ultrasonic application showed 3.7~4.6% higher than that of treated fabric without ultrasonic application. From the difference of specific weight loss, the treatment condition of the maximum of hydrolyzation effect appeared at $95^\circ{C}$ in $4^\circ{C}$ and at $90^\circ{C}$ in 6% NaOH solution, respectively. During the alkali hydrolysis of PET fabrics, the decomposition rate constant(k) increased exponentially with the treatment temperature and were not related with ultrasonic cavitation. The activation energy$(E_a)$ in decomposition of PET fabrics were 21.06kcal/mol with ultrasonic application and 21.10kcal/mol without ultrasonic application. The ultrasonic application gave a little higher value of the activation entropy$(\Delta{S}^\neq)$ and a little lower value of Gibbs free energy$(\Delta{S}^\neq)$ compared with not used ultrasonic apparatus.

Word Sense Similarity Clustering Based on Vector Space Model and HAL (벡터 공간 모델과 HAL에 기초한 단어 의미 유사성 군집)

  • Kim, Dong-Sung
    • Korean Journal of Cognitive Science
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    • v.23 no.3
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    • pp.295-322
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    • 2012
  • In this paper, we cluster similar word senses applying vector space model and HAL (Hyperspace Analog to Language). HAL measures corelation among words through a certain size of context (Lund and Burgess 1996). The similarity measurement between a word pair is cosine similarity based on the vector space model, which reduces distortion of space between high frequency words and low frequency words (Salton et al. 1975, Widdows 2004). We use PCA (Principal Component Analysis) and SVD (Singular Value Decomposition) to reduce a large amount of dimensions caused by similarity matrix. For sense similarity clustering, we adopt supervised and non-supervised learning methods. For non-supervised method, we use clustering. For supervised method, we use SVM (Support Vector Machine), Naive Bayes Classifier, and Maximum Entropy Method.

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