• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.28 no.11
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• pp.421-427
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• 2016

The indoor temperature of a building increases during the day due to solar radiation. This behavior is significant in school buildings that are finished with high thermal capacity materials. Moreover, in school buildings, windows cannot be opened until the class has finished owing to the security policy of schools. Consequently, classrooms maintain a high temperature throughout the morning. It is thus important to remove the indoor heat before the commencement of classes in order to reduce the cooling energy needed. The Energy Recovery Ventilator (ERV) system is currently being installed in school buildings for ventilating the classrooms. Night-purge control using ERV can be a good strategy to cool the classroom in advance of the operation of the cooling system. However, the optimal operation method of the ERV for night-purge control has not yet been reported. In this study, the effect of night-purge control with ERV in school buildings is analyzed by simulation method. The results of this study showed that the energy saving effect of night-purge control with ERV is most effective in the case of 2 hours operation prior to the commencement of the first lass and when enthalpy based outdoor air cooling is used.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2007.10a
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• pp.246-249
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• 2007

In numerical analysis for phase change material, numerical values of thermodynamic properties such as temperature, pressure, specific volume, enthalpy and entropy are required. But the steam table or diagram itself cannot be used without modelling. In this study applicability of neural networks in modelling superheated vapor region of water was examined by comparing with the quadratic spline. neural network consists of an input layer with 2 nodes, two hidden layers and an output layer with 3 nodes. Quadratic spline interpoation method was also applied for comparison. Neural network model revealed smaller percentage error to quadratic spline interpolation. From these results, it is confirmed that the neural networks could be powerful method in modelling the superheated range of the steam table.

• Analytical Science and Technology
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• v.14 no.3
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• pp.197-202
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• 2001

The characteristics of the electrochemically Li intercalated synthetic graphite were determined from the studies with XRD method, DSC and solid $^7Li-NMR$ spectrophotometric analysis. From the results of X-ray diffraction method, it was found that the compounds in the stage 1 structure were predominantly formed. The enthalpy and entropy changes of the compounds can be obtained from the differential scanning calorimetric analysis results. From these results, it was found that exothermic and endothermic reactions of lithium intercalated into synthetic graphite are related to thermal stability of lithium ion between carbon graphene layers. From the $^7Li-NMR$ data, scientific observation found that bands are shift toward higher frequencies with increasing lithium concentration because non-occupied electron shells of Li increased in charge carrier density. Line widths of the Li intercalated synthetic graphite compounds decreased slowly because of non-homogeneous local magnetic order and the random electron spin direction for substituted Li.

• Proceedings of the Plant Resources Society of Korea Conference
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• 2018.04a
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• pp.72-72
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• 2018

The root of Angelica gigas Nakai (AGN) is used as a traditional herbal medicine in Korea for the treatment of many diseases. However, a major challenge associated with the usage of the active compounds from AGN is their poor water solubility. Therefore, this work aimed to enhance the solubility of active compounds by a chemical (viz. surfactant) and physical (hot melt extrusion) crosslinking method (CPC). Infrared Fourier transform spectroscopy (FT-IR) revealed multiple peaks in extrudate solids representing new functional groups including carboxylic acid, alkynes and benzene derivatives. Differential scanning calorimetry (DSC) analysis of the extrudate showed lower glass transition temperature (Tg) and lower enthalpy (${\Delta}H$) (Tg: $43^{\circ}C$; ${\Delta}H$: <6 (J/g)) compared to the non-extrudate (Tg $68.5^{\circ}C$; ${\Delta}H$: 123.2) formulations. X-ray powder diffraction (XRD) analysis revealed amorphization of crystal materials in extrudate solid. In addition, nanonization, enhanced solubility and higher extraction of phenolic compounds were achieved in the extrudate solid. Among the different extrudates, acetic acid- and Span 80-mediated formulations showed superior extractions. We conclude that the CPC method successfully enhanced the production of amorphous nano dispersions from extrudate solid formulations.

• Journal of the Korean Society of Propulsion Engineers
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• v.17 no.6
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• pp.75-80
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• 2013

In this study, a forced ignition method with a plasma jet torch is studied in Mach 2 laboratory scaled wind-tunnel. The hyper-mixer is used as a mixer. For two normal injection cases, the one is collided against a wedge plate of the hyper-mixer and the other is directly injected into the cold main flow. For the first case, the hyper-mixer disperses the injected fuel, leading to the mixing enhancement. Furthermore, the fuel-air mixture is provided into the plasma hot gas, which enhances the combustion performance. However, the direct injection into the main flow method spends amount of fuel without ignition in the cold supersonic flow. In the end, for the forced combustion, it is important to supply the fuel-air mixture into the heat source.

• Journal of the Korean Applied Science and Technology
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• v.38 no.3
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• pp.832-839
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• 2021

We tried to investigate the effects of substituent position, temperature, and additives such as NaCl and n-butanol on the solubilizations of cresol isomers by tetradecyltrimethylammonium bromide (TTAB), using the UV-Vis spectrophotometric method. The measured solubilization constants (K_s) values for each cresol isomer increased in the order o-cresolo and ∆H^o values for the solubilizations of cresols were all negative values but the ∆S^o values were all positive values within the measured ranges. The values of ∆G^o increased also with increasing the concentration of n-butanol but decreased with increasing the concentration of NaCl. From these facts, we could conclude that both the enthalpy and entropy changes contribute together for the solubilizations of cresols isomers by cationic surfactant of TTAB and they are solubilized in the polar palisade region or at the surface of micelle.

• Nuclear Engineering and Technology
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• v.54 no.1
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• pp.162-176
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• 2022

In Lead-based reactor (LBR) severe accident, the meltdown and migration inside the reactor core will lead to fuel fragment concentration, which may further cause re-criticality and even core disintegration. Accurately predicting the migration and solidification behavior of melt in LBR severe accidents is of prime importance for safety analysis of LBR. In this study, the Moving Particle Semi-implicit (MPS) method is validated and used to simulate the migration and solidification behavior. Two main surface tension models are validated and compared. Meanwhile, the MPS method is validated by the L-plate solidification test. Based on the improved MPS method, the migration and solidification behavior of melt in LBR severe accident was studied furthermore. In the Pb-Bi coolant, the melt flows upward due to density difference. The migration and solidification behavior are greatly affected by the surface tension and viscous resistance varying with enthalpy. The whole movement process can be divided into three stages depending on the change in velocity. The heat transfer of core melt is determined jointly by two heat transfer modes: flow heat transfer and solid conductivity. Generally, the research results indicate that the MPS method has unique advantage in studying the migration and solidification behavior in LBR severe accident.

• Applied Chemistry for Engineering
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• v.2 no.4
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• pp.385-392
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• 1991

Nonstoichiometry and defect model for $Ni_{1-x}O$ were determined by coulometric titration method. In the temperature range of 1123-1198K and oxygen partial pressure of 0.21-0.1 atm, the nonstoichiometry was found to be proportional to the fourth root of the oxygen partial pressure. This pressure dependence can be explained by the fact that nonstoichiometric $Ni_{1-x}O$ contains singly ionized metal vacancies as the predominant point defects. At T=1173K and $Po_2=0.21atm$, the nonstoichiometry, x was $1.21{\times}10^{-4}$. The standard formation enthalpy of defects in $Ni_{1-x}O$ was found, on the basis of this defect model, to be 0.95 eV. Also the result indicates that both of singly and doubly ionized metal vacancies are simultaneously present at above 1248K.

• Applied Chemistry for Engineering
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• v.26 no.2
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• pp.210-216
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• 2015

Adsorption of brilliant blue FCF dye using coal based the granular activated carbon from aqueous solution was investigated. Batch experiments were carried out as a function of the adsorbent dose, initial concentration, contact time and temperature. The equilibrium adsorption data were fitted to Langmuir, Freundlich and Temkin models. The results indicate that Freundlich model provides the best correlation of the experimental data. Base on the estimated Freundlich constant (1/n = 0.129~0.212), this process could be employed as an effective treatment method. Adsorption data were modeled using the pseudo-first-order and pseudo-second-order kinetic equations. It was shown that the pseudo-second-order kinetic equation could describe well the adsorption kinetics. The negative Gibbs free energy value (-4.81~-10.33 kJ/mol) and positive enthalpy value (+78.59 kJ/mol) indicated that the adsorption was a spontaneous and endothermic process.

• Applied Chemistry for Engineering
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• v.26 no.5
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• pp.581-586
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• 2015

Adsorption of Safranin using granular activated carbon from aqueous solution was investigated. Batch experiments were carried out as a function of adsorbent dose, initial concentration, contact time and temperature. The equilibrium adsorption data were fitted to Langmuir, Freundlich and Dubinin-Radushkevich isotherm models. Based on an estimated Langmuir separation factor, $R_L=0.183{\sim}0.254$ and a Freundlich separation factor, 1/n = 0.518~0.547, this process could be employed as an effective treatment method. Adsorption data were also modeled using the pseudo-first and second-order kinetic equations. It was shown that the pseudo-second-order kinetic equation could best describe the adsorption kinetics. The negative Gibbs free energy (${\Delta}G=-3.688{\sim}-7.220kJ/mol$) and positive enthalpy (${\Delta}H=33.126kJ/mol$) indicated that the adsorption process was spontaneous and endothermic.