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http://dx.doi.org/10.14478/ace.2015.1019

Adsorption Kinetics and Thermodynamics of Brilliant Blue FCF Dye onto Coal Based Granular Activated Carbon  

Lee, Jong Jib (Division of chemical Engineering, Kongju National University)
Publication Information
Applied Chemistry for Engineering / v.26, no.2, 2015 , pp. 210-216 More about this Journal
Abstract
Adsorption of brilliant blue FCF dye using coal based the granular activated carbon from aqueous solution was investigated. Batch experiments were carried out as a function of the adsorbent dose, initial concentration, contact time and temperature. The equilibrium adsorption data were fitted to Langmuir, Freundlich and Temkin models. The results indicate that Freundlich model provides the best correlation of the experimental data. Base on the estimated Freundlich constant (1/n = 0.129~0.212), this process could be employed as an effective treatment method. Adsorption data were modeled using the pseudo-first-order and pseudo-second-order kinetic equations. It was shown that the pseudo-second-order kinetic equation could describe well the adsorption kinetics. The negative Gibbs free energy value (-4.81~-10.33 kJ/mol) and positive enthalpy value (+78.59 kJ/mol) indicated that the adsorption was a spontaneous and endothermic process.
Keywords
brilliant blue FCF; dye adsorption; adsorption; adsorption kinetic; dye;
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Times Cited By KSCI : 3  (Citation Analysis)
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1 J. W. Lee, Safety assessment of food additives by combined exposure: five tar food colors, 14-15, Korean Ministry of Food and Drug Safety, Seoul (2007).
2 H. H. Baek, H. C. Kwon, S. H. Choi, and K. W. Lee, Safety of food additives, 47-84, Korean Food Safety Reserch Institute, Seoul (2009).
3 Korean Ministry of Food and Drug Safety, Dietary intake of food additive by korean population-coal tar dye, combined diet intake, 120-131, Hanhakmunhwa, Seoul (2006).
4 J. P. Maloney, A. C. Halbower, B. F. Fouty, K. A. Fagan, V. Balasubramaniam, A. W. Pike, P. V. Fennessey, M. Moss, and N. Engl, Systemic absorption of food dye in patients with sepsis, J. Med., 343, 1047-1048 (2000).
5 J. P. Maloney, T. A. Ryan, K. J. Brasel, D. G. Binion, D. R. Johnson, A. C. Halbower, E. H. Frankel, M. Nyffeler, and M. Moss, Food dye use in enteral feedings: a review and a call for a moratorium, Nutr. Clin. Practice, 17, 168-181 (2002).
6 W. H. Hansen, O. G. Fitzhugh, A. A. Nelson, and K. J. Davis, Chronic toxicity of two food colors, brilliant blue FCF and indigotine, Toxicol. Appl. Pharmacol., 8, 29-36 (1966).   DOI   ScienceOn
7 H. Ketelsen and S. Meyer-Windel, Adsorption of brilliant blue FCF by soils, Geoderma, 90, 131-145 (1999).   DOI   ScienceOn
8 J. German-Heins and M. Flury, Sorption of brilliant blue FCF in soils as affected by pH and ionic strength, Geoderma, 97, 87-101 (2000).   DOI   ScienceOn
9 V. K. Gupta, A. Mittal, L. Krishnan, and J. Mittal, Adsorption treatment and recovery of the hazardous dye, brilliant blue FCF, over bottom ash and de-oiled soya, J. Colloid Interf. Sci., 293, 16-26 (2006).   DOI   ScienceOn
10 Z. Wu, H. Joo, and K. Lee, Kinetics and thermodynamics of the organic dye adsorption on the mesoporous hybrid xerogel, Chem. Eng. J., 112, 227-236 (2005).   DOI   ScienceOn
11 A. Mittal, Use of hen feathers as potential adsorbent for the removal of a hazardous dye, brilliant blue FCF, from wastewater, J. Hazard. Mater., B128, 233-239 (2006).
12 K. Mahmoudi, K. Hosni, N. Hamdi, and E. Srasra, Kinetics and equilibrium studies on removal of methylene blue and methyl orange by adsorption onto activated carbon prepared from date pits-A comparative study, Korean J. Chem. Eng., 32(2), 274-283 (2015).   DOI   ScienceOn
13 S. K. Yun, J. W. Kim, J. S. Im, S. D. Kim, J. S. Hong, J. K. Suh, and Y. S. Lee, Natural gas sorption using activated-carbon with surface treatment, Trans. Korean. Hydro. New Energy Soc., 17, 434-439 (2006).
14 J. J. Lee, Equilibrium, Kinetics and Thermodynamic parameters studies on metanil yellow dye Adsorption by granular Activated Carbon, Appl. Chem. Eng., 25, 96-102 (2014).   DOI   ScienceOn
15 I. A. W. Tan, A. L. Ahmad, and B. H. Hameed, Adsorption of basic dye on high-surface-area activated carbon prepared from coconut husk, J. Hazard. Mater., 154, 337-346 (2008).   DOI   ScienceOn
16 P. Sivakumar and P. N. Palanisamy, Adsorption studies of basic red 29 by a non conventional activated carbon prepared from euphorbia antiquorum L, Int. J. Chem. Tech. Res., 1, 502-510 (2009).
17 J. Monika, V. Garg, and D K. Kadirvelu, Chromium(VI) removal from aqueous solution, using sunflower stem waste, J. Hazard. Mater., 162, 365-372 (2009).   DOI   ScienceOn
18 G. Xing, S. Liu, Q. Xu, and Q. Liu, Preparation and adsorption behavior for brilliant blue X-BR of the cost-effective cationic starch intercalated clay composite matrix, Carbohydr. Polym., 87, 1447-1452 (2012).   DOI   ScienceOn
19 W. S. W. Ngah and M. A. K. M. Hanafiah, Adsorption of copper on rubber (hevea brasiliensis) leaf powder: kinetic, equilibrium and thermodynamic studies, Biochem. Eng. J., 39, 521-530 (2008).   DOI   ScienceOn
20 M. Dorgan, M. Alkan, O. Demirbas, Y. Ozdemir, and C. Ozmetin, Adsorption kinetics of maxilon blue GRL onto sepiolite from aqueous solutions, Chem. Eng. J., 124, 89-101 (2006).   DOI   ScienceOn
21 M. Ghaedi, H. Hossainian, M. Montazerozohori, A. Shokrollahi, F. Shojaipour, M. Soylak, and M. K. Purkait, A novel acorn based adsorbent for the removal of brilliant green, Desalination, 281, 226-233 (2011).   DOI   ScienceOn