• 설비공학논문집
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• 제10권5호
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• pp.535-549
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• 1998

A numerical study for performance analysis of a counterflow type forced draft tower and natural draft cooling tower has been performed based on the method using the finite volume method with non-orthogonal body fitted and non-staggered grid system. For solving the coupling problem between water and air, air enthalpy balance, moisture fraction balance, water enthalpy balance, and water mass balance equations are solved with Navier-Stoke’s equations simultaneously. For the effect of turbulence, the standard k-$\varepsilon$ turbulent model is implied in this analysis. The predicted result of the present analysis is compared with the experimental data and the commercial software result to validate the present study, The predicted results show good agreement with the experimental data and the commercial software result. To investigate the influence of the cooling tower design parameters such as approach, range and wet bulb temperature, parametric studies are also peformed.

• 한국유체기계학회 논문집
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• 제14권3호
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• pp.33-38
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• 2011

Medicated water electrolysis apparatus, which electrolyzes water into acidic water and alkaline water, was in the spotlight as becoming known the effect of alkaline water. It is known as good for health as removing active oxygen in the human's body and promoting digestion. But, the customers could not get that desired water temperature because these apparatuses are directly connected with a water pipe. So, the cooling system was developed for controlling the temperature of the alkaline water. One of the typical way is to store water in water tank and control the temperature. But, in this way, storing water can be polluted impurities coming from outside. For protecting this pollution, the cooling system based on indirect heat exchange method through phase change between water and ice was developed. In this study, we have calculated efficiency of the cooling system with phase change by experiment and commercial CFD(Computational Fluid Dynamics) code, ANSYS CFX. To consider the effect of latent heat that is generated by melting ice, we have simulated two phase numerical analyses used enthalpy method and found the temperature, velocity, and ice mass distribution for calculating the efficiency of cooling. From the results of numerical analysis, we have obtained the relationship between the cooling efficiency and each design factor.

• 청정기술
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• 제20권1호
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• pp.22-27
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• 2014

$CF_4$와 $C_2F_6$의 압력이 20.7 kPa 이하일 경우, 활성탄에의 평형흡착량을 여러 온도(293.15-333.15 K)에서 실험적으로 조사하였다. 실험데이터가 가장 잘 맞을 수 있도록 1차층 흡착으로 Langmuir모델을 쓰고 그 다음 단계에는 Freundlich 물리흡착을 이용하는 이단계모델을 제안한다. 1단계에 대한 흡착엔탈피를 구하기 위해 실험데이터의 최초기울기를 이용하였고, Clausius-Clapeyron식을 사용함으로써 2단계에 대한 흡착엔탈피를 구하였다. $CF_4$의 경우 1, 2단계의 흡착엔탈피는 각각 25.9와 11.8 kJ/mol이고, $C_2F_6$의 경우는 38.7과 38.2 kJ/mol이다.

• Bulletin of the Korean Chemical Society
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• 제28권7호
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• pp.1183-1186
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• 2007

A shake-flask method was used to determine the n-octanol/water partition coefficients of sulfamethazine, sulfadimethoxine, sulfamethoxydiazine, sulfamonomethoxine, sulfamethoxazole, sulfaquinoxaline and sulfachloropyrazine from (298.15 to 333.15) K. The results showed that the n-octanol/water partition coefficient of each sulfonamide decreased with the increase of temperature. Based on the fluid phase equilibrium theory, the thermodynamic relationship of n-octanol/water partition coefficient depending on the temperature is proposed, and the changes of enthalpy, entropy, and the Gibbs free energy function for sulfonamides partitioning in n-octanol/ water are determined, respectively. Sulfonamides molecules partitioning in n-octanol/water is mainly an enthalpy driving process, during which the order degrees of system increased. The temperature effect coefficient of n-octanol/water partition coefficient is discussed. The results show that its magnitude is the same as that of values in the literature.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 1997년도 춘계학술대회 논문집
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• pp.597-601
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• 1997

The technology of Semi-Solid Forging(SSF) has been actively developed to fabricate near-net shape products using light and hardly formable materials. Generally, the SSF process is composed of slug heating,forming,compression holding and ejecting step. After forming step in SSF, the slug is comperssed during a certain holding time in order to be completely filled in the die cavity and be accelerated in solidification rate. This paper presents the analysis of temperature,solid fraction and shrinkage at compression holding step for a cylindrical slug,then predicts the solidification time to obtain the final shaped part. Enthalpy-based finite element analysis is performed to solve the heat transfer problem considering phase change in solidification.

• 한국정밀공학회지
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• 제14권10호
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• pp.102-108
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• 1997

The technology of Semi-Solid Forging (SSF) has been actively developed to fabricate near-net- shape products using light and hardly formable materials. Generally, the SSF process is composed of slug heating, forming, compression holding and ejecting step. After forming step in SSF, the slug is compressed during a certain holding time in order to be completely filled in the die cavity and be accelerated in solidification rate. This paper presents the analysis of temperature, solid fraction and shrinkage at compression holding step for a cylindrical slug, then predicts the solidification time to obtain the final shaped part. Enthalpy-based finite element analysis is performed to solve the heat transfer problem considering phase change in solidification.

• Bulletin of the Korean Chemical Society
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• 제6권5호
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• pp.266-269
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• 1985

The dissociation constants(K) of m-chloroanilinium ion in water-ethanol mixture, where the volume percentage of water is 89.5%, were evaluated by UV-spectroscopic method at $20{\sim}50^{\circ}C$, up to 1500 bars with changing ionic strength from 0.04 to 0.10 mol $kg^{-1}$ by use of acetate buffer. K values enhance with increasing ionic strength and temperature, but decrease with elevating pressure. From K values, we obtained the partial molar volume change and some other thermodynamic parameters. From the values of enthalpy, entropy and isoequilibrium temperature (649 K), we concluded that the dissociation of m-chloroanilinium ion mentioned above is controlled by enthalpy.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2005년도 하계학술발표대회
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• pp.171-171
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• 2005

• 약학회지
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• 제15권1호
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• pp.8-15
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• 1971

Betacyclodextrin 과 수종의 sulfonamide와의 상호반응을 solubility method로 고찰하였다. 본실험에서 사용한 betacyclodextrin의 농도 범위에서는 sulfonamide의 solubility 증가와 batacyclodextrin의 농도와의 관계 함수관계에 있음을 나타내었다.열역학적인 해석을 시도하여 본반응의 formation constant, free energy, enthalpy 및 entropy를 개측하였다.

• 설비공학논문집
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• 제19권8호
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• pp.585-592
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• 2007

Good cold start characteristics are essential for satisfactory operation of fuel cell vehicles. In this study, the melting process has been numerically investigated for a water tank used in fuel cell vehicles. The 2-D model of the tank containing ice and plate heaters was assumed and the unsteady melting process of the ice was calculated. The enthalpy method was used for the description of the melting process, and a FVM code was used to solve the problem. The feasibility study compared with other experiment showed that the developed program was able to describe the melting process well. From the numerical analysis carried out for different wall temperatures of the pate heaters, some important design factors could be found such as local overheating and pressurization in the tank.