• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.3
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• pp.268-275
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• 2021

The three factors that determine the strength of concrete are the strength of cement paste, aggregate and ITZ(Interfacial Transition Zone) between aggregate and cement paste. Out of these, the strength of ITZ is the most vulnerable. ITZ is formed in 10~50㎛, the ratio of calcium hydroxide is high, and CSH appears low ratio. A high calcium hydroxide ratio causes a decrease in the bond strength of ITZ. ITZ is due to further weak area. The problem of ITZ appears as a more disadvantageous factor when it used lightweight aggregate. The previous study of ITZ properties have measured interfacial toughness, identified influencing factors ITZ, and it progressed SEM and XRD analysis on cement matrix without using coarse aggregates. also it was identified microstructure using EMPA-BSE equipment. However, in previous studies, it is difficult to understand the microstructure and mechanical properties. Therefore, in this study, a method of measuring electrical resistance using EIS(Electrochemical Impedance Spectroscopy) measuring equipment was adopted to identify the ITZ between natural aggregate and lightweight aggregate, and it was tested the change of ITZ by surface coating of lightweight aggregate with ground granulated blast furnace slag. As a result, the compressive strength of natural aggregate and lightweight aggregate appear high strength of natural aggregate with high density, surface coating lightweight aggregate appear strength higher than natural aggregate. The electrical resistivity of ITZ according to the aggregate appeared difference.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.27 no.6
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• pp.319-326
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• 2017

In this study, a lightweight geopolymer was prepared using by slag discharged from IGCC (Integrated Gasification Combined Cycle) power plant and its physical properties, the density and compressive strength, were analyzed as a function of the concentration of alkali activators, W/S ratio and aging times. Also the possibility of applying it to lightweight materials by adding Si sludge as a foaming agent to the geopolymerg was investigated. In particular, a complex composition of alkali activator and a pre-curing process were applied to improve the strength properties of lightweight geopolymers. While the compressive strength of the lightweight geopolymer using a single activator was 9.5 MPa, the specimen made with a complex composition of alkali activator had compressive strength of 2~5 times higher. In addition, the lightweight geopolymer with pre-curing process showed a compressive strength value of 18~48 % higher than that of specimen made with no precuring process. In this study, by using a complex activator and a pre-curing process. the maximum compressive strength of lightweight geopolymer was obtained as 40 MPa (The specimen was aged for 3 days and had density of $1.83g/cm^3$), which is comparable to cement concrete. By analyzing the crystal phase and microstructure of geopolymers obtained in this study using by XRD and SEM, respectively, it was confirmed that the flower-bud-like zeolite crystal was homogeneously distributed on the surface of the C-S-H gel (sodium silicate hydrate gel) in the geopolymer.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.2
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• pp.116-122
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• 2019

This study evaluated the properties of Coal gasification slag(CGS) according to the CGS contents of cement mortar condition as a basic step to examine the applicability of CGS as concrete fine aggregate. Flow increased with increasing CGS contents for both Crushed sand a(CSa) and Crushed sand b+Sea sand(CSb+SS), but the amount of air contents decreased to the opposite tendency. Based on 28 days is maximum compressive strength was obtained at CGS 50% when CSa was used and CGS 75% when CSb+SS. The flexural strength were the maximum at 25% and 50% of CGS, but the tendency was similar to the compressive strength. Compared with CSa, the compressive strength and flexural strength 5% higher than those of CSb+SS, in CGS using of were about 5% higher than those of unused CGS. As a result of comprehensive study on the quality of mortar according to the CGS contents, it can be concluded that when CGS is mixed with fine aggregate at about 50%, it can contribute to securing workability and strength development positively so that resource recycling and quality improvement can be achieved at the same time.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2018.06a
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• pp.101-101
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• 2018

Quantitative measurement of chloride ion concentration has an important role in various fields of electrochemistry, medical science, biology, metallurgy, architecture, etc. Among them, its importance of architecture is ever-growing due to unexpected degradations of building structure. These situations are caused by corrosion of reinforced concrete (RC) structure of buildings. And chloride ions are the most powerful factors of RC structure corrosion. Therefore, precise inspection of chloride ion concentration must be required to increase the accuracy of durability monitoring. Multi-walled Carbon nanotubes (MWCNTs) have high chemical resistivity, large surface area and superior electrical property. Thus, it is suitable for the channels of electrical signals made by the sensor. Silver nanoparticles were added to giving the sensing property. CuBTC, one of the metal organic frameworks (MOFs), was employed as a material to improve the sensing property because of its hydrophilicity and high surface area to volume ratio. In this study, sensing element was synthesized by various chemical reaction procedures. At first, MWCNTs were functionalized with a mixture of sulfuric acid and nitric acid because of enhancement of solubility in solution and surface activation. And functionalized MWCNTs, silver nanoparticles, and CuBTC were synthesized on PTFE membrane, one by one. Electroless deposition process was performed to deposit the silver nanoparticles. CuBTC was produced by room temperature synthesis. Surface morphology and composition analysis were characterized by scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDS), respectively. X-ray photoelectron spectroscopy (XPS) was also performed to confirm the existence of sensing materials. The electrical properties of sensor were measured by semiconductor analyzer. The chloride ion sensing characteristics were confirmed with the variation of the resistance at 1 V.

• Journal of Conservation Science
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• v.30 no.3
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• pp.287-298
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• 2014

This study investigates the material properties of the traditional bricks used in the royal tomb of King Muryeong. Compressive strengths, thermal conductivities, absorptance and the rate of residual moisture are measured by non-destructive experiments. Compressive strength of the traditional bricks is estimated by using the ultrasonic wave velocity and the absorptance. Based on the experimental results, the predicted compressive strengths using the ultrasonic wave velocity are unsuitable for the traditional bricks due to the rough surface and thickness variation of the specimens. The strengths using the absorptance are more suitable than those using the velocity because the predicted average strengths (28.69 MPa ~ 33.19 MPa) are close to building materials like normal strength concrete. In addition, the methods using the absorptance are not influenced by surface and thickness conditions of the specimens. The average thermal conductivities of the bricks measured by using Mathis TCi are close to those of soils (1.58 W/mK). The absorptance and the rate of residual moisture of the bricks are 1.6 % ~ 15 %, 0 % ~ 0.7 %, respectively.

• Journal of the Korea Institute of Building Construction
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• v.15 no.2
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• pp.161-167
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• 2015

Nowadays, all the world face to the global warming problems due to the emission of $CO_2$. From the previous studies, recycled aggregates were used as an alkali activator in blast furnace slag to achieve zero-cement concrete, and favorable results of obtaining strength were achieved. In this study, gypsum and incineration waste ash were used as the additional alkali activation and effects of the gypsum and incineration waste ash to enhance the performance of the mortar were tested. Results showed that although the replacement ratio of 0.5% of incineration waste ash and 20% of anhydrous gypsum resulted in the low of mortar at the early age, while it improved the later strength and achieved the similar strength to that of conventional mortar (at 91 days).

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.1
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• pp.97-102
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• 2010

The objective of this paper is to explore the possibility of reuse of waste vegetable oil (WO) as an autogenous shrinkage reducer for high strength concrete and to compare the amount of autogenous shrinkage of the mortar using existing shrinkage reducing agent(SR) and expansive additives(EA). According to test results, as the dosages of WO increased, flow value exhibited to decrease, while the use of SR increased flow value. For the effect of WO on strength, although the use of SR and WO resulted in a slight decrease in compressive strength at early age, at 91 days they had similar strength level of the plain mixture. For autogenous shrinkage, as expected, the addition of WO, SR and EA resulted in a decrease of autogeneous shrinkage considerably especially, WO had superiority in autogenous shrinkage reducing effect compared with the case of SR and EA.

• Journal of Ceramic Processing Research
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• v.19 no.5
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• pp.378-382
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• 2018

It is a known fact that the cement production is responsible for almost 5% of total worldwide $CO_2$ emission, the primary factor affecting global warming. Geopolymers are valuable as ordinary Portland cement (OPC) substitutes because geopolymers release 80% less $CO_2$ than OPC and have mechanical properties sufficiently similar to those of OPC. Therefore, geopolymers have proven attractive to eco-friendly construction industries. Geopolymers can be fabricated from aluminum silicate materials with alkali activators such as fly ash, blast furnace slag, and so on. Integrated gasification combined cycle (IGCC) slag has been used for fabricating geopolymers. In general, IGCC slag geopolymers are fabricated with finely ground and sieved (<128 mesh) IGCC slag. The grinding process of as-received IGCC slag is one of the main costs in geopolymer production. Therefore, the idea of using as-received IGCC slag (before grinding the IGCC slag) as aggregates in the geopolymer matrix was introduced to reduce production cost as well as to enhance compressive strength. As-received IGCC slag (0, 10, 20, 30, 40 wt%) was added in the geopolymer mixing process and the mixtures were compared. The compressive strength of geopolymers with an addition of 10 wt% as-received IGCC slag increased by 19.84% compared to that with no additional as-received IGCC slag and reached up to 41.20 MPa. The enhancement of compressive strength is caused by as-received IGCC slag acting as aggregates in the geopolymer matrix like aggregates in concrete. The density of geopolymers slightly increased to $2.1-2.2g/cm^3$ with increasing slag addition. Therefore, it is concluded that a small addition of as-received IGCC slag into the geopolymer can increase compressive strength and decrease the total cost of the product. Moreover, the direct use of as-received IGCC slag may contribute to environment protection by reducing process time and $CO_2$ emission.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.3
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• pp.235-242
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• 2022

The percolation threshold of the CNT-reinforced cement paste is closely related to the optimal CNT amount to maximize the sensing ability of self-sensing concrete. However, the percolation threshold has various values depending on the cement, CNT, and water-to-cement ratio used. In this study, a percolation simulation model was proposed to predict the percolation threshold of the CNT-reinforced cement paste. The proposed model can simulate the percolation according to the amount of CNT using only the properties of CNT and cement, and for this, the concept of the number of aggregated CNT particles was used. The percolation simulation consists of forming a pre-hydrated cement paste model, random dispersion of CNTs, and percolation investigation. The simulation used CNT-reinforced cement paste with a water-cement ratio of 0.4 to 0.6, and the simulated percolation threshold point showed high accuracy with a simulation residual ratio of up to 7.5 % compared to the literature results.

• Composites Research
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• v.29 no.6
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• pp.328-335
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• 2016

The purpose of this study is to develop fiber reinforced cement matrix composite (ECC) produced with limestone powder in order to achieve high ductility of the composite, and to evaluate flexural performance of structural members made with ECC. Four kinds of mixture proportions were determined on the basis of the micromechanics and a steady state cracking theory considering the matrix fracture toughness and fiber-matrix interfacial characteristics. The mechanical properties of ECC, represented by strain-hardening behavior in uniaxial tension, were investigated. Also, strength property of the composite was experimentally evaluated. Two structural members made with ECC were produced and tested. Test results were compared with those of conventional concrete structural members. Increased limestone powder contents of ECC provides higher ductility of the composites while generally resulting in a lower strength property. ECC structural members exhibited higher flexural ductility, higher flexural load-carrying capacity and tighter crack width compared to conventional structural members.