• Journal of the Korean Crystal Growth and Crystal Technology
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• v.25 no.5
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• pp.205-211
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• 2015

Most of the sulfur is obtained from desulfurization of natural gas and crude oil. In Korea, more than 120 tons of sulfur are produced by refinery, and about 50 % of the produced sulfur is used as a raw material for the production of fertilizer and sulfuric acid. Modified sulfur is manufactured from excessive sulfur that could be used to improve concrete properties, and this study evaluated concrete strength and durability that contains modified sulfur. Flexural and compressive strengths of concrete with sulfur modified polymer were comparable to those of OPC concrete with mixing water at similar temperatures, while the strengths increased a little as mixing water temperature increased. It was also confirmed that the resistance to freeze-thaw damage was more dependent on entrained air characteristics obtained by a proper use of air entraining agent than on the use of sulfur modified polymer. When concrete was immersed in 5 % sulfuric acid, the rate of reduction in compressive strength of OPC concrete was less than 1/4 of the strength reduction of concrete with sulfur modified polymer. Also, the resistance of concrete with sulfur modified polymer to scaling due to the use of de-icing salt was evaluated as Class 1, while that of OPC concrete was evaluated as Class 4, as aggregates were exposed. Accordingly, it is believed that sulfur modified polymer could be effectively used for bridge deck concrete since sulfur modified polymer improves the durability of concrete.

• Journal of the Korean Magnetics Society
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• v.16 no.2
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• pp.144-148
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• 2006

$CoGa_{0.1}Fe_{1.9}O_4$ nanoparticles have been prepared by a sol-gel method. The structural and magnetic properties have been investigated by XRD, SEM, VSM and $M\ddot{o}ssbauer$ spectroscopy. $CoGa_{0.1}Fe_{1.9}O_4$ powder that was annealed at $250^{\circ}C$ has spinel structure and behaved superparamagnetically. The estimated size of superparammagnetic $CoGa_{0.1}Fe_{1.9}O_4$ nanoparticle is around 10 nm. The hyperfine fields at 4.2 K f3r the A and B patterns were found to be 518 and 486 kOe, respectively. The blocking temperature $(T_B)$ of superparammagnetic $CoGa_{0.1}Fe_{1.9}O_4$ nanoparticle is about 250 K. The magnetic anisotropy constant of $CoGa_{0.1}Fe_{1.9}O_4$ nanoparticle was calculated to be $3.0X10^5\;ergs/cm^3$. $CoGa_{0.1}Fe_{1.9}O_4$ nanoparticle was annealed at $250^{\circ}C$ will be used to candidate for biomedicine applications as magnetic carriers.

• Journal of the Korean Society of Marine Environment & Safety
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• v.23 no.2
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• pp.187-193
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• 2017

This study evaluated tidal stream energy resources according to tidal flow properties around Uido off the west coast of, Jeollanam-do, South Korea. A feasibility study was first carried out through the collection of bathymetry data and tidal phase information. For this simulation, a depth-averaged 2D ADCIRC (Advanced Circulation) model for real sea situations was applied to a Finite Element Method (FEM) approach for tides given the variation of tidal current speed. Hydrodynamics were simulated with 4 major tidal constituents (M2, S2, K1, and O1) after setting up 4 observation points. From the real depth-averaged model simulation results, it was found that the spring tide Higher High Water (HHW) and tidal current speed values at the 4 observation points were about 2.2 m and 1.33 m/s, respectively. The ADCIRC model results were analyzed with reference to the Korea Hydrographic and Oceanographic Agency's (KHOA) observed data for verification. Furthermore, using topographical characteristics via the Tidal Flux Method (TFM), tidal energy density distribution was calculated, indicating a maximum tidal energy density of about $1.75kW/m^2$ for the 5 assessment areas around Uido. The tidal energy density was evaluated with consideration given to topographical characteristics as well as tidal elevation and tidal current speed to determine an optimum tidal farm candidate.

• Polymer(Korea)
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• v.33 no.6
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• pp.551-554
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• 2009

Poly (vinyl alcohol) (PVA) and carboxymethyl cellulose (CMC) have received increasing attention in biomedical and biochemical applications because of their properties such as being water-soluble and biocompatible. In this study, a PVA/CMC hydrogel applicable to artificial cartilage was prepared by a freezing-thawing technique and a gamma-ray irradiation. The solid concentration of PVA was 7 wt% and the concentration of CMC was 4 wt%. The freezing/thawing process was repeated twice and the dose of gamma-ray irradiated was 30 kGy. Results of gelation before and after gamma-ray irradiation were similar, but the swelling degree decreased and compressive strength increased. The cytotoxicity was investigated with CCK-8 assay.

• Polymer(Korea)
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• v.38 no.6
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• pp.702-707
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• 2014

Corneal endothelium is mono-inner cell layer of cornea and lay on Descmet's membrane which comprised of various proteins called extracellular matrix such as fibronectin, collagen, laminin, and proteoglycan, etc. In this study, we fabricated transparent poly(lactic-co-glycolic acid) (PLGA) film because PLGA is widely used for tissue engineering based on their properties. We investigated the behaviors of rabbit corneal endothelial cells (rCEnCs) on PLGA film surfaces coated with various cell-adhesive molecules like fibronectin, laminin, collagen type I and IV and FNC coating mix. The morphologic images, proliferation and adhesion assay, immunofluorescence for ZO-1 and $Na^+/K^+-ATPase$ and RT-PCR for expression of specific markers were conducted. These results showed that PLGA film plays a role as CEnC carriers in vitro and the cell-adhesive molecules give positive effects on the behaviors of rCEnC.

• Korean Journal of Optics and Photonics
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• v.16 no.2
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• pp.168-173
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• 2005

Ag-doped $TiO_2$ thin films were prepared by RF magnetron co-sputtering method, and their physical and chemical properties were examined as a function of calcination temperature. XRD results showed that the crystallite size of Ag-doped films was smaller than that of the $TiO_2$ thin films. SEM results showed that the particle size of $Ag/TiO_2$ film was smaller and more uniform than pure $TiO_2$ film. The films had high transparency in the visible range. The films calcined at $600^{\circ}C$ were the anatase phase, and the films calcined at $900^{\circ}C$ were a mixture of anatase and rutile phases. The absorption edge of films calcined at $900^{\circ}C$ was red-shifted. This is due to the augmented absorption resulting from the phase transformation from anatase to rutile phase. And the transmittance of films decreased by the light scattering and absorption in the films. Photocatalytic activity of $Ag/TiO_2$ thin films was higher than that of the pure $TiO_2$ thin films.

• Journal of Adhesion and Interface
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• v.2 no.2
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• pp.20-27
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• 2001

Recently polycarbonate material has been utilized as windows in aircraft, buildings, and optical lens. However, while polycarbonate has excellent optical transparency, impact strength and many beneficial mechanical properties, it possesses poor abrasion resistance and weatherability. Then, there is a need for developing optically clear, anti-abrasive and weather resistant hard coating agents for polycarbonate. In this study, N-triethoxy silyl propyl quinine urethane(TESPQU) was synthesized with quinine and 3-isocyanato propyl triethoxy silane(3-IPTES). In order to introduce optically active silane in the main siloxane network, TESPQU was co-hydrolysed and co-condensed with methyl triethoxy silane(MTES) under acidic conditions. Polycarbonate sheets were coated with silica coating agents by the sol-gel method, and their abrasion resistance, ability of UV absorption and weatherability were evaluated. Coating agents containing hydroxybenzophenone as a UV absorber were also prepared to compare weatherability with TESPQU containing coating agent. TESPQU containing coating agent had good weatherability in accelerated QUV test.

• Journal of Adhesion and Interface
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• v.2 no.4
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• pp.10-23
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• 2001

In order to increase the lower values of % grafting and monomer conversion in the emulsion graft polymerization of methylmethacrylate(MMA) onto sodium alginate (SA; a polymer electrolyte) with alginic acid-g-PMMA, the graft polymerization with water soluble (methanol and acetone) and insoluble solvents was carried out using a varity of solvent amounts and agitating rates. And some physical properties of the graft polymer were also investigated. In the polymerizations with water insoluble solvent, there were pronounced improvements in both % grafting and MMA conversion by the promotion of MMA diffusion from the core to the SA adsorpted on the outer layer of particle and that of MMA complex formation with SA. And the effect was larger for the solvents (cyclohexane, decalin) which do not dissolve PMMA. On the other hand, in the polymerization with water soluble solvent, there was an significant increase in MMA conversion and a considerable increase in the % grafting by the destruction of electrical double layer around the SA chains, abstracting the hydrated water in the layer and the effect was more potential in the case of methanol which is a precipitant of PMMA.

• 한국지구물리탐사학회:학술대회논문집
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• 1999.08a
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• pp.92-116
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• 1999

Tomographic approaches to image underground structure using electrical properties, can be divided into DC resistivity, electromagnetic, and radar tomography, based on the operating frequency. DC resistivity and radar tomography methods have been recently applied to site investigation for engineering purpose in Korea. This paper review these two tomography methods, through the case histories acquired in Korea. As another method of borehole radar survey, borehole radar reflection method is included, and its inherent problem and solution are discussed, how to find the azimuth angle of reflector using direction-finding-antenna. Since the velocity anisotropy of radar wave has been commonly encountered in field data, anisotropic radar tomography is discussed in this paper. In DC resistivity tomography, two subjects are focussed, electrode arrays, and borehole effect owing to the conductive fluid in borehole. Using the numerical modeling data, various kinds of electrode ways are compared, and borehole effect is illustrated. Most of the case histories presented in this paper are compared with known geology, core logging data, and/or Televiewer images.

• 한국지구물리탐사학회:학술대회논문집
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• 1999.08a
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• pp.48-64
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• 1999

For quantitative evaluation of geotechnical engineering properties such as rippability and diggability, clear interpretation on the subsurface velocity structures should be preceded by figuring out top soil, weathered and soft rock layers, shape of basement, fracture zones, geologic boundary and etc. from the seismic refraction data. It is very important to set up suitable field parameters, which are the configuration of profile and its length, spacings of geophones and sources and topographic conditions, for increasing field data quality Geophone spacing of 3 to 5m is recommended in the land slope area for house land development and 5 to 10m in the tunnel site. In refraction tomography technique, the number of source points should be more than a half of available channel number of instrument, which can make topographic effect ignorable. Compared with core logging data, it is shown that the velocity range of the soil is less than 700m/s, weathered rock 700${\~}$1,200m/s, soft rock 1,200${\~}$1,800m/s. And the upper limit of P-wave velocity for rippability is estimated 1,200 to 1,800m/s in land slope area of gneiss. In case of tunnel site, it is recommended in tunnel design and construction to consider that tunnel is in contact with soft rock layer where three lineaments intersecting each other are recognized from the results of the other survey.