• Title/Summary/Keyword: Energy measurement

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Effect of Ni Addition on ATiO3 (A = Ca, Sr, Ba) Perovskite Photocatalyst for Hydrogen Production from Methanol Photolysis (메탄올 광분해 수소제조를 위한 ATiO3 (A = Ca, Sr, Ba) Perovskite 광촉매의 Ni 첨가 영향)

  • Kwak, Byeong Sub;Park, No-Kuk;Lee, Tae Jin;Lee, Sang Tae;Kang, Misook
    • Clean Technology
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    • v.23 no.1
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    • pp.95-103
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    • 2017
  • In this study, $ATiO_3$ (A = Ca, Sr, Ba) perovskite, which is the widely known for non $TiO_2$ photocatalysts, were synthesized using sol-gel method. And Ni was added at the A site of $ATiO_3$ by using that it is easy to incorporate. The physicochemical characteristics of the obtained $ATiO_3$ and Ni-$ATiO_3$ particles were confirmed using the X-ray diffraction (XRD) UV-visible spectroscopy, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), the $N_2$ adsorption-desorption isotherm measurement, and X-ray photoelectron spectroscopy (XPS). The $H_2$ was produced using the photolysis of MeOH. Using the Ni-$ATiO_3$ photocatalysts, $H_2$ production was higher than using the $ATiO_3$ photocatalysts. Especially, $273.84mmolg^{-1}$ $H_2$ was produced after 24 h reaction over the Ni-$SrTiO_3$. Also in the water (0.1 M KOH) with the Ni-$SrTiO_3$, $H_2$ production was $961.51mmolg^{-1}$ after 24 h reaction.

Determination of Exposure Dose Rate and Isotropic Distributions of Substitute High Dose Rate Ir-192 Source for Co-60 Brachytherapy Source (원격강내조사용 Co-60 선원의 대체용 Ir-192 선원의 조사선량결정 및 선량 등방성조사)

  • 최태진;원철호;김옥배;김시운;김금배;조운갑;한현수;박경배
    • Progress in Medical Physics
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    • v.9 no.1
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    • pp.55-64
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    • 1998
  • In recent, the demand of development of the high dose rate brachytherapy source increased for substitute for Co-60 source by iridium source, since the supplying Co-60 source is very depressed and the high dose rate brachytherapy sources are entirely imported from the abroad. This study investigated the exposure rates and isotropic dose distributions for the Ir-192 source produced from $\^$191/Ir(n,r)$\^$192/Ir by nuclear reactor in Korea Atomic Energy Research Institute. The activity of source was obtained an 1.012 Ci (the initial activity without encapsulation was 2,87Ci) by measurement with encapsuled stainless steel. The exposure rate of provided Ir-192 source was determined on 6.36 ${\pm}$ 0.147 Rm$^2$/h-GBq (2.350 ${\pm}$ 0.054 Rcm$^2$/mCi-hr) within ${\pm}$ 2.2% discrepancy with IC-10 ion chamber (0.14 cc) which was mounted on the acrylic jig to 5, 10 and 20 cm from the center of source. The calculated doses with 22 most significant spectrum lines were corrected with intrinsic efficiency of the germanium detector were compared to measured exposure dose rates within ${\pm}$3.8 % discrepancy. The authors confirmed the high dose rate Ir-192 source could be replaced the long decayed Co-60 source via investigation of the isotropic dose distributions in lateral, source axis and diagonal direction of source center are very closed to within 3% uncertainties. Especially, this exposure rate constant and isotropic dose distribution will be fundamental to build the high dose rate source and develop the computed therapy planning system.

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Contribution of Non-Point Pollution to Water Quality and Runoff Characteristics from Agricultural Area of the Upstream Watersheds of Lake Chinyang

  • Lee, Chun-Sik;Jang, Seong-Ho
    • Journal of Environmental Science International
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    • v.22 no.3
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    • pp.259-267
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    • 2013
  • In this study, non-point source(NPS) contribution was investigated based on flow rates and water qualities of streams into the lake during rainfall events. Event mean concentration(EMC) and the pollution loads were calculated to establish a database for NPS control measurement in the survey area, and so on. The runoff characteristics of NPS were investigated and estimated on the basis of the ratio of an agricultural to forest area in the stream of sub-catch basin during rainfall events. Non-point source pollution loads were also calculated to establish a database for NPS control measure in the upstream lake Chinyang. At a rainfall event, BOD concentrations rise sharply at the early peak time of runoff, however, peaks of TSS concentration were observed at the similar time of peak flow. This was a phenomenon shown at the watersheds caused by forest and geological types. The discharged EMC range was 2.9-4.8 mg/L in terms of BOD. The discharged EMC range was 6.2-8.2 mg/L in terms of SS. The discharged EMCs of T-N and T-P were 1.4-2.5 mg/L and 0.059-0.233 mg/L, respectively. Total BOD loading rate through the 3 tributaries to the lake Chinyang was 1,136 kg/d during dry weather. The upper watershed area of the Nam-river dam in this study was divided into 14 catchment basins based on the Korean guideline for total maximum daily load(TMDL) of water quality pollutants. The higher the agricultural land-use ratio, the more NPS loading rate discharged, but the more occupied a forest area, the lower more NPS loading rate discharged. In an agricultural land-use area more than 20%, the increase of NPS loadings might be dramatically diffused by increasing the integrated complex-use like vinyl-house facilities and fertilizer use etc. according to the effective land-use utilization. The NPS loading rates were BOD 0.3 $kg/ha{\cdot}day$, SS 0.21 $kg/ha{\cdot}day$, TN 0.02 $kg/ha{\cdot}day$, TP 0.005 $kg/ha{\cdot}day$ under less than 10% agricultural land-use. In agricultural land-use of 20%-50%, these values were investigated in the range of 0.32 $kg/ha{\cdot}day$-0.73 $kg/ha{\cdot}day$ for BOD, 0.92 $kg/ha{\cdot}day$-3.32 $kg/ha{\cdot}day$ for SS, 0.70 $kg/ha{\cdot}day$-0.90 $kg/ha{\cdot}day$ TN, 0.03 $kg/ha{\cdot}day$-0.044 $kg/ha{\cdot}day$ for TP.

Effect of Sampling and Analytical Methods on the Fibrous Materials from the Ground Water (시료 채취 조건 및 검사방법에 따른 지하수내 섬유상 물질 검출 양상에 관한 연구)

  • Kim, Ji-Yong;Kim, Jung Ran;Cheong, Hae-Kwan;Lim, Hyun-Sul;Paik, Nam-Won
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.7 no.2
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    • pp.209-222
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    • 1997
  • Authors surveyed the ground water near the waste disposed from a fiberglass production factory to confirm the presence of glassfiber in the water and to determine the effect of sampling conditions and storage on the recovery of fibrous materials in the ground water. Sample was collected at every 4 hours for 48 hours consecutively. After finishing the 48 hours sample, water sampling was done from each tap after repeated turning on and off the water for 30 seconds at each time. Sample was collected in the two 1.5 liter polyethylene bottle after vigorously shaking the bottle with the same water several times with the flowing tap water. At each paired sample, one bottle was stored stand still at room temperature, and the other sample was filtered immediately after sampling. Water was filtered on the Mixed Cellulose Ester filter with negative pressure. Each sample was divided into upper and lower layer. The other bottle was stored at room temperature standstill for 7 days and filtered in the same fashion as the other pair of sample did. Each MCE filter was divided into 4 pieces and one piece was treated with acetone to make it transparent. Each prepared sample was observed by two researchers under the light and polarizing microscopy, scanning electron microscopy and energy dispersive X-ra microanalysis. Fibers were classified by the morphology and polarizing pattern under the polarizing microscope, and count was done. 1. There was a significant fluctuation in number of the fibers, but there was no specific demonstrable pattern. 2. Non-polarizing fibers frequently disappeared after 7 days's storage. But cluster of fibers were found at the wall of the same container by scratching technique. 3. Polarizing fibers were usually found in between the filter and the manicure pasted area. Possible explanations for this phenomenon will be that either these fibers are very light or have electronic polarity. Hence, these fibers are not able to be attached on the surface of slide glass. 4. Under the scanning electron microscopic examination, the fibers which are not refractive under the light microscopy were identified as glassfiber. Other fibers which is refractive under the polarizing microscopy were identified as magnesium silicate fibers. It is strongly suggested that development of standardized method of sample collection and measurement of fibrous material in the water is needed.

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A Study on the Lime Reactivity of Concrete Admixtures (콘크리트 혼합재의 석회반응성에 관하여)

  • Chang, Pok-Kie;Yoon, Chung-Han
    • Journal of the Korean Ceramic Society
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    • v.39 no.5
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    • pp.452-459
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    • 2002
  • This paper addresses the hydrothermal reactivity of blast furnace slag and fly ash with lime, respectively. The test conditions were CaO-to-$SiO_2$ ratio (C/S), autoclaving temperature ($140{\circ}C$ and $180{\circ}C$) and time (20 to 60h). The study was carried out in terms of the hydrothermal reactivity between $SiO_2$ contained in each hydraulic material and (pure) lime and the compressive strength of autoclaved specimens. Porosity measurement and the XRD analysis were also made in order to ascertain the hydraulicity of the siliceous materials. Compressive strength of the specimens was interpreted in terms of porosity and the reactivity of CaO and $SiO_2$. And the XRD analysis showed the C/S change of the hydrates in the course of autoclaving process. $SiO_2$ in the blast furnace slag was more reactive with CaO than that in the fly ash and consequently the blast furnace slag specimens resulted in much higher compressive strength. A maximum compressive strength of $807kg/cm^2$ was obtained for the blast furnace slag at the autoclaving condition of $180{\circ}C$ and 40 h, while only $397kg/cm^2$ was maximally to achieve with fly ash.

The Effect of Thermal Annealing and Growth of Cdln2S4 Single Crystal Thin Film by Hot Wall Epitaxy (Hot Wall Epitaxy(HWE)법에 의한 Cdln2S4 단결정 박막 성장과 열처리 효과)

  • 홍광준;이관교
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.11
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    • pp.923-932
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    • 2002
  • A stoichiometric mixture of evaporating materials for CdIn$\_$2/S$\_$4/ single crystal thin films was prepared from horizontal furnace. To obtain the single crystal thin films, CdIn$\_$2/S$\_$4/ mixed crystal was deposited on thoroughly etched semi-insulating GaAs(100) substrate by hot wall epitaxy(HWE) system. The source and substrate temperatures were 630 $\^{C}$ and 420 $\^{C}$, respectively. The crystalline structure of single crystal thin films was investigated by the photoluminescence and double crystal X-ray diffraction(DCXD). The carrier density and mobility of CdIn$\_$2/S$\_$4/ single crystal thin films measured from Hall effect by van der Pauw method are 9.01$\times$10$\^$16/ cm$\^$-3/ and 219 ㎠/V$.$s at 293 K, respectively. From the optical absorption measurement, the temperature dependence of energy band gap on CdIn$\_$2/S$\_$4/ single crystal thin films was found to be Eg(T) = 2.7116 eV - (7.74 $\times$ 10$\^$-4/ eV) T$\^$2//(T+434). After the as-grown CdIn$\_$2/S$\_$4/ single crystal thin films was annealed in Cd-, S-, and In-atmospheres, the origin of point defects of CdIn$\_$2/S$\_$4/ single crystal thin films has been investigated by the photoluminescence(PL) at 10 K. The native defects of V$\_$cd/, V$\_$s/, Cd$\_$int/ and S$\_$int/ obtained by PL measurements were classified as donors or accepters type. And we concluded that the heat-treatment in the S-atmosphere converted CdIn$\_$2/S$\_$4/ single crystal thin films to an optical p-type. Also, we confirmed that In in CdIn$\_$2/S$\_$4/GaAs did not from the native defects because In in CdIn$\_$2/S$\_$4/ single crystal thin films existed in the form of stable bonds.

Evaluation of Shielding Rate of Bismuth Depending on the Type of Medical Radioisotope (의료용 방사성동위원소의 종류에 따른 비스무트의 차폐율 평가)

  • Han, Sang-Hyun
    • Journal of the Korea Convergence Society
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    • v.9 no.7
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    • pp.87-93
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    • 2018
  • In this study, $^{99m}Tc$, $^{123}I$, $^{201}Tl$, $^{18}F$, and $^{131}I$, which are widely used in nuclear medicine, were transmitted through a bismuth shield. We investigated the shielding rates according to the type of radioisotope and the distance of measurement. For the experiment, 6 sheets of lead equivalent 0.25 mm Pb of bismuth shielding material were stacked one by one up to 1.50 mm as the thickness increased. The distance was 30 cm, 50 cm, and 100 cm, and the transmission dose was measured. As a result, the shielding rates was measured as the thickness increased, and the measured value decreased as the distance increased. The shielding rate of $^{123}I$ and $^{201}Tl$ was higher than $^{99m}Tc$, $^{18}F$ and $^{131}I$ showed lower shielding effect when there is a shielding material than when there is no shielding material due to high energy and ${\beta}$ rays. Based on the results of experiments, it would be helpful to reduce the exposure of nuclear medicine workers and to manage the exposure if bismuth shields are used depending on the type of radioisotope.

Prediction Model for Reduced Bone mass in Women using Individual Characteristics & Life Style Factors (여성의 개인적 특성과 생활양식요인을 이용한 골량감소 예측모형)

  • Lee, Eun-Nam;Lee, Eun-Ok
    • Journal of muscle and joint health
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    • v.5 no.1
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    • pp.83-109
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    • 1998
  • This study was carried out to identify the Important modifiable risk factors for reduced bone mass and to construct prediction model which can classify women with either low or high bone mass. Through the literature review, individual characteristics such as age, body weight, height, education level, family history, age of menarche, postmenopausal period, gravity, parity, menopausal status, and breast feeding period were identified and factors of life style such as past milk consumption, past physical activity, present daily activity, present calcium intake, alcohol intake, cigarette smoking, coffee consumption were identified as influencing factors of reduced bone mass in women. Four hundred and eighty women aged between 28 and 76 who had given measurement bone mineral density by dual energy x-ray absortiometry in lumbar vertebrae and femur from July to October, 1997 at 4 general hospitals in Seoul and Pusan were selected for this study. Women were excluded if they had a history of any chronic illness such as rheumatoid arthritis, diabetes mellitus, hyperthroidism, & gastrointestinal disorder and any medication such as calcium supplements, calcitonin, estrogen, thyroxine, antacids, & corticosteroids known affect bone. As a result of these exclusion criteria, four hundred and seventeen women were used for analysis. Multiple logistic regression model was developed for estimating the likelihood of the presence or absence of reduced bone mass. A SAS procedure was used to estimate risk factor coefficient. The results are as follows For lumbar spine, the variables significant were age, body weight, menopause status, daily activity, past milk consumption, and past physical activity(p<0.01), while for femoral Ward's triangle, age, body weight, level of education, past milk consumption, past physical activity(p<0.001). Past physical activity, present daily activity and past milk consumption are the most powerful modifiable predictors in vertebrae and femur among the predictors. When the model performance was evaluated by comparing the observed outcome with predicted outcome, the model correctly identified 74.1% of persons with reduced bone mass and 84.5% of persons with normal bone mass in the lumbar vertebrae and 82.9% of persons with reduced bone mass and 75.0% of persons with normal bone mass in the femoral Ward's triangle. On the basis of these results, a number of recommendations for the management of reduced bone mass may be made : First, those woman who are classified as high risk group of the reduced bone mass in the prediction model should examine the bone mineral density to further examine the usefulness of this model. Second, the optimal amount of milk consumption and a regular weight bearing exercise in childhood, adolescence, and early adult should be ensured.

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Study of Acute Myelocytic Leukemia Patient Treatment That Used Total Skin Electron Beam (Total Skin Electron Beam을 이용한 급성 골수성 백혈병 환자 치료에 대한 연구)

  • Lee, Sang-Ryul;Kang, Min-Kyu;Kim, Sung-Kyu
    • Progress in Medical Physics
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    • v.20 no.3
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    • pp.152-158
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    • 2009
  • Total Skin Electron Beam Therapy (TSEBT) of linear accelerator has become use so as to be useful, 2~9 MeV of energy territories came to be used with mycosis fungoides and cutaneous lymphomas in the superficial lesion treatment which covers the major portion of the body. I treat a patient to Stanford technique in this study, and it is $60^{\circ}$ around the patients whom Stanford technique irradiated electronic beam to a linear accelerator in horizontal directions and there is a way a standard of TSEBT treat it to six located field (anterior, posterior, and four obliques) becoming. An each field does horizontally it and consist to beam of the two component which fitted the center to a suitable angle. a patient treats it to three dual field a day in order to make short treatment time. when a first day, we treat one dual field at anterior position and two dual field at posterior position. when the second day, treat one dual field at posterior position and two dual field at anterior position. Therefore, six dual field is finished in perfect periodic two days. we made cylindrical acrylic phantom, and I inserted a dosimeter film between phantom. in order to measure a dose distribution calculation before treat a patient, and a patient checked it in six field directions that got from a treatment. It is after that thermoluminescent dosimetry (TLD) as it uses Rando phantom and then measurement dose distribution in six field directions after attaching at chest, the right and left flank, a back after irradiation.

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Dose Distribution of Wedge filter by Dose Rate in LINAC (선형가속기의 선량율에 따른 쐐기필터의 선량분포)

  • Gwon, Taehyeong;Kim, Seunguk;Yoon, Yonghak;Won, Doyeon;Jeong, Kyeonghwan;Jung, Jaeeun;Cho, Juneho
    • Journal of the Korean Society of Radiology
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    • v.9 no.5
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    • pp.323-329
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    • 2015
  • This study is aimed at assessing whether dynamic wedge filters are appropriate to be used instead of physical wedge filters. The X-ray energy generated from linear accelerator is commercialize 6 MV and 10 MV. $15^{\circ}$, $30^{\circ}$, $45^{\circ}$, and $60^{\circ}$ of physical wedge filter was irradiated by dose rate 100, 200, 300, 400, 500, and 600 MU/min for each angle and for comparison with a dynamic wedge filter, irradiate 96 times under the same conditions. The measurement conditions are as 100 cm source-film distance and $10{\times}10cm$ irradiated surface. A developed film was scanned and analyzed after a calibration through a dose analysis program and the dose rate was compared after calculating the standard deviation. Dynamic wedge filters make dose, scattered rays and treatment time reduced and very useful due to less irradiated doses to patients. The errors at each dose rate under the same conditions were irrelevant. Thus, treatment based on a high dose rate depending on the patient is expected to be feasible.