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http://dx.doi.org/10.7464/ksct.2017.23.1.095

Effect of Ni Addition on ATiO3 (A = Ca, Sr, Ba) Perovskite Photocatalyst for Hydrogen Production from Methanol Photolysis  

Kwak, Byeong Sub (Department of Chemistry, College of Science, Yeungnam University)
Park, No-Kuk (School of Chemical Engineering, College of Engineering, Yeungnam University)
Lee, Tae Jin (School of Chemical Engineering, College of Engineering, Yeungnam University)
Lee, Sang Tae (Wooshin Industrial Co. LTD.)
Kang, Misook (Department of Chemistry, College of Science, Yeungnam University)
Publication Information
Clean Technology / v.23, no.1, 2017 , pp. 95-103 More about this Journal
Abstract
In this study, $ATiO_3$ (A = Ca, Sr, Ba) perovskite, which is the widely known for non $TiO_2$ photocatalysts, were synthesized using sol-gel method. And Ni was added at the A site of $ATiO_3$ by using that it is easy to incorporate. The physicochemical characteristics of the obtained $ATiO_3$ and Ni-$ATiO_3$ particles were confirmed using the X-ray diffraction (XRD) UV-visible spectroscopy, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), the $N_2$ adsorption-desorption isotherm measurement, and X-ray photoelectron spectroscopy (XPS). The $H_2$ was produced using the photolysis of MeOH. Using the Ni-$ATiO_3$ photocatalysts, $H_2$ production was higher than using the $ATiO_3$ photocatalysts. Especially, $273.84mmolg^{-1}$ $H_2$ was produced after 24 h reaction over the Ni-$SrTiO_3$. Also in the water (0.1 M KOH) with the Ni-$SrTiO_3$, $H_2$ production was $961.51mmolg^{-1}$ after 24 h reaction.
Keywords
N-$ATiO_3$; Photocatalyst; Perovskite; Hydrogen production; Photolysis;
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