• Journal of Digital Convergence
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• v.11 no.5
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• pp.119-133
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• 2013

This study aims to provide power generating plants with eco-efficiency information. To implement the purposes, of study, both DEA(Data, Envelopment Analysis) model and interview were incorporated in terms of methodologies. To analyze the managerial efficiency, total labor cost and number of employees were considered as input factors. CO2, NOx, and water also were considered as input factors to analyze eco-efficiency. Both annual total power product and annual total revenue were used as output factors. CRS(Constant Return to Scale) and VRS(Variable Return to) model were facilitated in this analysis. According to the findings, most of the power plants were evaluated as 'Efficient'' taking into consideration of average value, both 0.928 from CCR model and 0.969 from VRS model. 7 DMUs including DMU3 and DMU12 are efficient out of 35 DMUs relatively, other DMUs are inefficient. For results of inefficient output factors distribution, it was found that inefficiency for NOx was marked relatively higher than CO2. In order to improve the eco-efficiency in the power plants in the long term, the target amount of Co2 as well as NOx reduction needs to be properly proposed in consideration of particularity of power plants. In the long run, renewable energy, alternative fuels should be adapted to reduce the eco-inefficient.

• Korean Chemical Engineering Research
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• v.49 no.5
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• pp.577-581
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• 2011

Silicon nanoparticles have attracted a great deal of scientific interests due to its intense photoluminescence in the visible spectral region and its potential applications in biological fluorescence maker, RGB (red, green, blue) display, photonics and photovoltaics etc. Practical applications making use of optical and physicochemical properties of Si nanoparticles requires an efficient synthetic method which allows easy modulation of their size, size distribution as well as surface functionalities etc. In this study, a one-pot solution reduction scheme is attempted to prepare alkyl-terminated Si nanoparticles (<10 nm) with Si precursors, (Octyl)$SiCl_3$ or mixture of (Octyl)$SiCl_3$ and $SiCl_4$, containing alkyl-groups using Na(naphthalide) as reducing agent. The surface capping of Si nanoparticles with octyl-groups as well as Si nanoparticle formation was achieved in one-pot reaction. The hexane soluble Si nanoparticles with octyl-termination were in the range of 2-10 nm by TEM and some oxide groups (Si-O-Si) was present on the surface by EDS/FTIR analyses. The optical properties of Si nanoparticles measured by UV-vis and PL evidenced that photoluminescent Si nanoparticles with alkyl-termination was successfully synthesized by solution reduction of alkyl-containing Si precursors in one-pot reaction.

• Korean Chemical Engineering Research
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• v.52 no.6
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• pp.807-813
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• 2014

The Ag-impregnated activated carbon was produced from bamboo activated carbon by soaking method of silver nitrate solution. The carbonization and activation of raw material was conducted at $900^{\circ}C$. Soaking conditions are the variation of silver nitrate solution concentration (0.002~0.1 mol/L) and soaking time (maximum 24 h). The specific surface area and pore size distribution of the prepared activated carbons were measured. Also, NO and activated carbon reaction were conducted in a thermogravimetric analyzer in order to use for de-NOx agents of used activated carbon. Carbon-NO reactions were carried out with respect to reaction temperature ($20{\sim}850^{\circ}C$) and NO gas partial pressure (0.1~1.8 kPa). As results, Ag amounts are saturated within 2h, Ag amounts increased 1.95 mg Ag/g (0.2%)~ 88.70 mg Ag/g (8.87%) with the concentration of silver nitrate solution in the range of 0.002~0.1 mol/L. The specific volume and surface area of bamboo activated carbon of impregnated with 0.2% silver were maximum, but decreased with increasing Ag amounts of activated carbon due to pore blocking. In NO reaction, the reaction rate of impregnated bamboo activated carbon was retarded as compare with that of bamboo activated carbon. Measured reaction orders of NO concentration and activation energy were 0.63[BA], 0.69l[BA(Ag)] and 80.5 kJ/mol[BA], 66.4 kJ/mol[BA(Ag)], respectively.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.16 no.9 s.100
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• pp.917-925
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• 2005

In this paper, the quad-band antenna for mobile handsets is proposed and developed. The operating frequency bands include GSM(880 MHz${\~}$960 MHz), GPS(1,575 MHz$\pm$10 MHz), DCS(1,710 MHz${\~}$l,880MHz), and PCS(1,850 MHz${\~}$l,990 MHz). The proposed antenna consists of a feed line, a shorting post, and a radiating element of the feed loop. The multi-band operation is achieved by using the fundamental and higher resonant modes of the radiating element. Based on analysis of the current distribution on the radiator, the resonant frequency of each mode can be adjusted by adding the different sizes of slots on the radiator. The radiator of the feed loop is designed to be symmetrical so that the energy is symmetrically distributed on the radiator, which results in omni-directional radiation pattern. The ground plane under the radiator is removed in order to improve the bandwidth. The measured impedance bandwidths are $10.1\%$ in GSM band(VSWR<2.5), $26.8\%$ in GPS band, and DCS/US-PCS bands(VSWR<2.5), respectively. The maximum gains on the H-plane of the fabricated antenna are measured about -0.37 dBi${\~}$2.55 dBi for all operating frequency bands.

• Progress in Medical Physics
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• v.11 no.2
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• pp.117-122
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• 2000

The IP(imaging plate) has been widely used to measure the two-dimensional distribution of incident radiation since it has a high sensitivity, reusability, a wide dynamic range, a high position resolution. Particularly, the easiness of acquiring digitized image using IP poses a strong merit because recent trend of data handling prefers image digitization. In order to test its usefulness in photon beam dosimetry, we measured the off-axis ratio(OAR) on portal planes and percent depth dose(PDD) within a phantom using IP, and compared the results with the data based on EGS4 Monte Carlo particle transport code, ion-chambers, conventional films. For the measurement, we used 6 MV X-rays, various field sizes. As a result, IP showed significant deviation from ion-chamber measurement: a significant overresponse, 100% greater than that of ion-chamber measurement at deep part of the phantom. Filtration of low-energy scattered photons at deep part of the phantom using 0.5 mm thick lead sheets did improve the result, only to the unacceptable extent. However, portal dose measurement showed possibilities of If as a dosimeter by showing errors less than 5%, as compared with film measurement.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.3
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• pp.277-284
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• 2012

In this study, a heat-transfer performance analysis is carried out for a multi-channel volumetric air receiver for a solar power tower. On the basis of a series of reviews regarding the relevant literature, a calculation process is proposed for the prediction of the wall- and air- temperature distributions of a single channel at given geometric and input conditions. Furthermore, a unique mathematical model of the receiver effectiveness is presented through analysis of the temperature profile. The receiver is made of silicon carbide. A total of 225 square straight channels per module are molded to induce the air flow, and each channel has the dimensions of $2mm(W){\times}2mm(H){\times}0.2mm(t){\times}320mm(L)$. The heat-transfer rate, temperature distribution and effectiveness are presented according to the variation of the channel and module number under uniform irradiation and mass flow rate. The available air outlet temperature applied to the solar power tower should be over $700^{\circ}C$. This numerical model was actually used in the design of a 200 kW-level commercial solar air receiver, and the required number of modules satisfying the thermal performance could be obtained for the specified geometric and input conditions.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.38 no.8
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• pp.695-700
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• 2014

In the present study, the melting temperature depression of Sn nanoparticles manufactured using the modified evaporation method was investigated. For this purpose, a modified evaporation method with mass productivity was developed. Using the manufacturing process, Sn nanoparticles of 10 nm size was manufactured in benzyl alcohol solution to prevent oxidation. To examine the morphology and size distribution of the nanonoparticles, a transmission electron microscope was used. The melting temperature of the Sn nanoparticles was measured using a Differential scanning calorimetry (DSC) which can calculate the endothermic energy during the phase changing process and an X-ray photoelectron spectroscopy (XPS) used for observing the manufactured Sn nanoparticle compound. The melting temperature of the Sn nanoparticles was observed to be $129^{\circ}C$, which is $44^{\circ}C$ lower than that of the bulk material. Finally, the melting temperature was compared with the Gibbs Thomson and Lai's equations, which can predict the melting temperature according to the particle size. Based on the experimental results, the melting temperature of the Sn nanoparticles was found to match well with those recommended by the Lai's equation.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.37 no.4
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• pp.313-322
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• 2013

Batteries, which are being used as energy sources in various applications, tend to degrade, and their capacity declines with repeated charging and discharging cycles. A battery is considered to fail when it reaches 80% of its initial capacity. To predict this, prognosis techniques are attracting attention in recent years in the battery community. In this study, a method is proposed for estimating the battery health and predicting its remaining useful life (RUL) based on the slope of the charge voltage curve. During this process, a Bayesian framework is employed to manage various uncertainties, and a Particle Filter (PF) algorithm is applied to estimate the degradation of the model parameters and to predict the RUL in the form of a probability distribution. Two sets of test data-one from the NASA Ames Research Center and another from our own experiment-for an Li-ion battery are used for illustrating this technique. As a result of the study, it is concluded that the slope can be a good indicator of the battery health and PF is a useful tool for the reliable prediction of RUL.

• Analytical Science and Technology
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• v.7 no.1
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• pp.103-114
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• 1994

The elution behaviors of Ni(II), Cu(II), Co(II), and Cr(II) in 1-phenyl-3-methyl-4(2-hydroxy-5-X-phenylazo)-5-pyrazolone, [Pm(2-OH)(5-X)PaPz](X=H, $CH_3$, $NO_2$, Cl) chelates have been studied by reversed phase HPLC. Thirteen metal-[Pm(2-OH)(5-X)PaPz] chelates were prepared and characterized by UV, IR, MS, and ICP spectroscopic methods. These metal-2-hydroxyarylazopyrazolone chelates were successfully separated on Novapak-$C_{18}$ column using methanol/water mixtures as a mobile phases. It was found that the chelates were eluted properly in an acceptable range of the capacity factor value($0{\leq}log\;k^{\prime}{\leq}1$). The dependence of the capacity factor(log k') on the volume fraction of water in the binary mobile phase showed a good linearity. Also, there was a good linear dependence of the capacity factor on the liquid-liquid extraction distribution ratio($D_c$) in methanol-water/n-pentadecane extraction system by the batch method. It suggested that the retention of the chelates in the reverse phase liquid chromatographic system be largely due to the solvophobic effect.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.10 no.12
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• pp.3740-3747
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• 2009

To protect the citizens' health of Gyeongju and to secure basic data for the assessment of health and environmental risk, distribution characteristics of meteorological elements were investigated and numerical simulation of wind field using RAMS model was carried out. In addition, measurement and analysis of air pollutants, forecasting the behavior air pollutants using ISC-AEROMOD view, and health and environmental risk-influenced zones were defined through managing air polluting materials to prevent health damage and property damage. According to the survey results of air pollution in Gyeongju and surroundings, average annual concentration of air pollutants in Gyeongju was slightly lower than that in Pohang and Ulsan areas, but concentration of particulate matters and nitrogen dioxide at Gyeongju Station Square and Yonggang Crossing were sometimes higher than that in Pohang and Ulsan areas. Results of the modeling of moving and diffusion of air pollutants that affect citizens' health showed that parts of the 1st through 4th industrial complexes together with POSCO were included in particulate matters and sulfur dioxide influenced areas in Pohang Steel Complex area, and that Haedo-dong, Sangdae-dong, Jecheol-dong and Jangheung-dong in Pohangnam-gu represented locally worsened air quality due to a quantity of air pollutant emission from dense steel industries and large scale industrial facilities.