• Title/Summary/Keyword: Energy density

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ReaxFF and Density Functional Theory Studies of Structural and Electronic Properties of Copper Oxide Clusters

  • Baek, Joo-Hyeon;Bae, Gyun-Tack
    • Journal of the Korean Chemical Society
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    • v.64 no.2
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    • pp.61-66
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    • 2020
  • In this study, we investigate the structural and electronic properties of copper oxide clusters, CunOn (n = 9 - 15). To find the lowest energy structures of copper oxide clusters, we use ReaxFF and density functional theory calculations. We calculate many initial copper oxide clusters using ReaxFF quickly. Then we calculate the lowest energy structures of copper oxide clusters using B3LYP/LANL2DZ model chemistry. We examine the atomization energies per atom, average bond angles, Bader charges, ionization potentials, and electronic affinities of copper oxide clusters. In addition, the second difference in energies is investigated for relative energies of copper oxide clusters.

A Study on the Reactor Design of Solid-Solid-Gas Chemical Heat Pump System (고체-고체-기체 화학 열펌프 시스템의 반응기 설계에 관한 연구)

  • Kim, S.J.;Lee, T.H.;Neveu, P.;Choi, H.K.;Lee, J.H.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.6 no.4
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    • pp.406-416
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    • 1994
  • In this study the reactor design procedure and method of solid-solid-gas chemical heat pump system using STELF technology were investigated. For manufacturing IMPEX block which is the kernel of reactor, proper salt pair should be selected, and equilibrium temperature drop and COP should be examined for selected salt pair. Moreover, apparent density, residual porosity, and graphite ratio should be calculated to give minimum block volume and mass, and maximum energy density without causing heat and mass transfer problems. Since heat exchange area can be changed with operating condition, reactor diameter, length, and stainless steel thickness should be decided for desired specifications. These procedure and method were applied to the case study of 6kW cold production and 8 hours storage capacity reactor.

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Grid를 이용한 고밀도 플라즈마 소스의 이온 특성 연구

  • Byeon, Tae-Jun;Gwon, A-Ram;Kim, Seung-Jin;Kim, Jeong-Hyo;Park, Min-Seok;Jeong, U-Chang
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.497-497
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    • 2012
  • 산업의 발전함에 따라 고기능성 박막의 수요가 증가하고 있으며, magnetron sputtering, e-beam evaporation, ion beam 등을 이용한 박막 증착에 대한 연구가 많이 진행되고 있다. 그러나 기존 방법만으로는 박막 접착계면의 불균일로 인해 고기능성 박막 성장이 어렵다는 단점을 가지고 있다. 이러한 문제를 해결하기 위하여 박막 공정 중 고밀도 플라즈마 소스(high density plasma source)를 통해 추가적인 에너지를 인가하여 박막의 밀도를 bulk 수준으로 증가시키고 내부 응력을 조절하는 연구에 대한 관심이 커지고 있다. 특히 grid를 이용하여 플라즈마 내 이온의 입사에너지를 증가시킴으로써, 기존 공정보다 고기능성 박막을 구현할 수 있다. 본 연구에서는 RF power를 이용한 inductively coupled plasma를 통해 플라즈마를 생성시킨 후 grid에 DC power를 인가하는 플라즈마 소스를 개발하였으며, 시뮬레이션을 통해 plasma density와 ion current density, ion energy 분석 및 grid 디자인을 하였다. 개발된 플라즈마 소스는 ion energy analyzer를 통해 RF power 및 grid에 인가하는 power의 세기에 따라 이온화 정도 및 이온의 입사에너지를 측정하였다.

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Simultaneous Consolidation of Titanium Diboride with Self-Propagating High-Temperature Synthesis, Direct Contact-Heating, and Pressure: Modeling of Temperature Distribution and the Relationship between Applied Energy and Densification ($TiB_2$ SHS 및 직접 접촉가열에 의한 동시 가압법 : 온도분포 모델링 및 공급에너지와 치밀화 관계)

  • Chung, G.K.;Cho, K.;Lee, H.B.
    • Journal of the Korean Ceramic Society
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    • v.32 no.7
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    • pp.817-824
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    • 1995
  • TiB2 was simultaneously synthesized and densified with concurrent self-propagating high-temperature synthesis and direct contact-heating by electrcial power input and pressure. Density of TiB2 synthesized by self-propagating high-temperature synthesis and consolidated simultaneously by direct contact-heating and pressure was maximum 80% of the theoretical density (4.52g/㎤). Temperature profile was analyzed by solving heat balance equation with numerical method (FTCS method). The temperature of the sample was sufficiently raised to that temperature sufficient to be densified. It was ascertained that the density of the SHS synthesized TiB2 is exponentially proportinal to the input thermal energy per mass.

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A Study on Characteristic of the 14/50/50 PLZT Thin Film for DRAM Capacitor (고집적 DRAM소자용 14/50/50 PLZT 박막의 특성에 관한 연구)

  • 박용범;장낙원;백동수;마석범;최형욱;박창엽
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.118-121
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    • 1999
  • PLZT thin films were fabricated with different energy density by pulsed laser deposition. PLZT films deposited on Pt/Ti/SiO$_2$/Sr substrate. This PLZT thin films of 5000$\AA$ thickness were crystallized at $600^{\circ}C$, 200mTorr $O_2$ pressure for 2 J/$\textrm{cm}^2$ laser energy density. 14/50/50 PLZT thin film showed a maximum dielectric constant value of $\varepsilon$$_{r}$=1289.9 P-E hysteresis loop of 14/ 50/50 PLZT thin film was slim ferroelectric. Leakage current density of 14/50/50 PLZT thin film was 10/ sup -7/=A/$\textrm{cm}^2$.>.

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Spatio-temporal Charge Distribution in Electric Double Layer Capacitors observed by pulsed Electro Acoustic Method

  • Sung, Youl-Moon
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.4
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    • pp.182-187
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    • 2007
  • The use of the pulsed electro acoustic (PEA) method allowed us to perform the direct observations of spatio-temporal charge distributions in Electric double layer capacitors (EDLCs) based on polarizable nanoporous carbonaceous electrode. The negative charge density became the maximum, about $205C/m^3$ at the region where was near to collector layer in EDLCs for case $V_{DC}=2.5V$, while the positively charged density became the maximum, about $61.1C/m^3$ at the region where it was located around the cathode layer. The performance of the best sample was found to be better in terms of the charge density (Cs) and specific energy ($E_s$) with a maximum value of ${\sim}8.4F/g$ and 26 Wh/kg. The $C_s$ obtained from the PEA method agreed well with that from the energy conversion method. The PEA measurement used here is a very useful method to quantitively investigates the spatio-temporal charge distribution in EDLCs.

An Analysis of Effects through Improved Insulation Performance for High-Density Residential Area on West High East Low Type (서고동저형 경사지 주거 밀집지역의 단열성능 개선 효과분석)

  • Lee, Seong-Hwa;Yoon, Seong-Hwan
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.34 no.1
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    • pp.69-78
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    • 2018
  • The purpose of this study is propose eco-friendly remodeling while protecting the living environment of existing residents and preserving the living in pleasant by considering the characteristic of high density sloped residential area. And then, the optimum insulation condition is analyzed based on the energy efficiency, economic analysis and environmental effect. It will be possible as the basic information for remodeling of each housing in sloped area. The energy demanding, cost and the carbon emission reduction is analyzed with the residential area in Seo-gu, Busan by eco-remodelling.

Analysis of First Wafer Effect for Si Etch Rate with Plasma Information Based Virtual Metrology (플라즈마 정보인자 기반 가상계측을 통한 Si 식각률의 첫 장 효과 분석)

  • Ryu, Sangwon;Kwon, Ji-Won
    • Journal of the Semiconductor & Display Technology
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    • v.20 no.4
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    • pp.146-150
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    • 2021
  • Plasma information based virtual metrology (PI-VM) that predicts wafer-to-wafer etch rate variation after wet cleaning of plasma facing parts was developed. As input parameters, plasma information (PI) variables such as electron temperature, fluorine density and hydrogen density were extracted from optical emission spectroscopy (OES) data for etch plasma. The PI-VM model was trained by stepwise variable selection method and multi-linear regression method. The expected etch rate by PI-VM showed high correlation coefficient with measured etch rate from SEM image analysis. The PI-VM model revealed that the root cause of etch rate variation after the wet cleaning was desorption of hydrogen from the cleaned parts as hydrogen combined with fluorine and decreased etchant density and etch rate.

A Study on the Construction of High Density Concrete for Radiation Shield (방사선 차폐용 고밀도 콘크리트 시공에 관한 연구)

  • 이제방;조용복;변형균;유건철;임병대
    • Proceedings of the Korea Concrete Institute Conference
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    • 1994.10a
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    • pp.399-404
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    • 1994
  • Heavyweight(or High density) concrete, which is generally for shiedling structures, differs from normal weight concrete by having a higher density and special compositions to improve its attenuation properties. There are setting 7 Beam Ports around the reactor of the KMRR Project(Korea Multi-purpose Research Reactor) conducted by the KAERI(Korea Atomic Energy Research Institute). High density(p=5.0t/$\textrm{m}^3$) and Heavyweight(p=3.5t/$\textrm{m}^3$) concrete were placed around the Beam Ports in order to shield radiation. This paper was discussed about construction of High density concrete. High density concrete was placed with method of Preplace Aggregate. Coarse metallic aggregate(steel shot) was used. Boron, boron carbide(B4C), was used to capture effctively the neutrom. The mock-up test was carried out. And the consturction of High density concrete was performed successfully.

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Analysis of Biomass Energy Potential and Density in Korea (국내(國內) 바이오매스 에너지 잠재량(潛在量) 및 밀집도(密集度) 분석(分析))

  • Kook, Jin Woo;Shin, Ji Hoon;Yoo, Ho Seong;Lee, See-Hoon
    • Resources Recycling
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    • v.22 no.5
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    • pp.56-62
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    • 2013
  • The biomass resources is one of promising ways to solve energy exhaustion issues and global warming issues at the same time. To evaluate domestic biomass resources potential such as agricultural wastes, forestry wastes, livestock wastes and municipal solid wastes, statistics data from various organizations were collected and analyzed in this study. Also, space energy densities of each districts in Korea were calculated and analyzed. The results from the evaluation of biomass energy potential and space energy densities in Korea might be useful to estimate the availability of biomass energy conversion processes and to choice a appropriate process to convert domestic biomass into energy.