• Prospectives of Industrial Chemistry
• /
• v.23 no.1
• /
• pp.3-17
• /
• 2020

리튬이온전지(LIB)는 기존의 다른 이차전지와 다른 확실한 몇 가지 장점이 있다. 높은 작동 전압과 높은 에너지 밀도, 긴 수명, 그리고 낮은 자체 방전 속도이다. 이러한 장점으로 모바일 제품에서부터 전기 자동차(battery electric vehicle, BEV), 최근에는 전기저장장치(energy storage system, ESS)까지 다양한 분야에서 사용되고 있다. 하지만 사용 범위가 증가함에 따라 높은 안정성을 가지며 더 큰 에너지 용량을 나타내는 리튬이온전지에 대한 요구가 점점 더 커지게 되었다. 리튬이온전지의 용량 증가는 전지의 설계보다는 양극 및 음극 재료, 분리막 및 전해질과 같은 주요 전지 재료의 기술적 진보에 달려 있다. 주요 전지 소재 중에 전지의 성능에 가장 큰 영향을 미치는 것은 전지 반응에 의한 과전압과 가격이 가장 비싼 양극이다. 본 기획 특집에서는 리튬이차전지의 성능에 가장 큰 영향을 미치는 양극 물질의 종류와 향후 연구동향에 대해서 소개하고자 한다. 양극 물질의 발전 방향, 안정성과 용량 증대를 위해서 최근 연구되고 있는 방향에 대해서 자세하게 소개한다.

• Journal of Environmental Impact Assessment
• /
• v.26 no.4
• /
• pp.217-226
• /
• 2017

Although the effects of climate change are universal, Small Island Developing States (SIDS) are considered to be most vulnerable. SIDS heavily rely on imported oil and fossil fuels for electricity generation and transportation, which makes them economically vulnerable and exposed to fluctuating oil price. Among the reasons SIDS highly depend on diesel fuel is due to the dispersed population living in remote islands which means, providing electricity through on on-grid system is difficult. Fiji as one of the SIDS, has actively promoted renewable sourced energy through a national plan to mitigate the impacts of climate change. In order to determine how feasible implementing a renewable energy (RE) system will be in Fiji, this study chose a remote island called Mavuva Island to test application of a hybrid RE system using HOMER. A combination of energy storage system (ESS), solar photovoltaic (PV) and diesel generator turns out to be the most cost effective and optimal configuration, resulting in effective greenhouse gas reduction for the given region.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.21 no.12
• /
• pp.77-86
• /
• 2020

Power quality problems caused by feeder voltage drop and extension construction cost problems can occur with the increasing utilization rates of the existing fixed-type EV (electric vehicle) charger. Moreover, EV users might not be able to access the EV charger due to a lack of EV charging facilities. Therefore, this paper proposes an MPSD (movable power supply device) for EVs to overcome user inconvenience caused by the insufficient number of chargers and extension cost issues. The proposed MPSD was mainly composed of a PV (photovoltaic) system, ESS (energy storage system), EV charging system, and monitoring and control system. Furthermore, there are three operation modes available to enhance the flexibility of the MPSD application, depending on the situation. This paper also presents an economical evaluation modeling using the present worth method to consider the cost and benefit elements. The simulation results based on proposed modeling showed that MPSD is more economical than the existing EV charger. Moreover, its profit can be increased significantly depending on the distance to the installation point.

• KEPCO Journal on Electric Power and Energy
• /
• v.5 no.3
• /
• pp.209-213
• /
• 2019

Recently, demand for high energy density and long cycling stability of energy storage system has increased for application using with frequency regulation (F/R) in power grid. Supercapacitor have long lifetime and high charge and discharge rate, it is very adaptable to apply a frequency regulation in power grid. Supercapacitor can complement batteries to reduce the size and installation of batteries. Because their utilization in a system can potentially eliminate the need for short-term frequent replacement as required by batteries, hence, saving the resources invested in the upkeep of the whole system or extension of lifecycle of batteries in the long run of power grid. However, low energy density in supercapacitor is critical weakness to utilization for huge energy storage system of power grid. So, it is still far from being able to replace batteries and struggle in meeting the demand for a high energy density. But, today, LIC (Lithium Ion Capacitor) considered as an attractive structure to improve energy density much more than EDLC (Electric double layer capacitor) because LIC has high voltage range up to 3.8 V. But, many aspects of the electrochemical performance of LIC still need to be examined closely in order to apply for commercial use. In this study, in order to improve the capacitance of LIC related with energy density, we designed new method of pre-doping in anode electrode. The electrode in cathode were fabricated in dry room which has a relative humidity under 0.1% and constant electrode thickness over $100{\mu}m$ was manufactured for stable mechanical strength and anode doping. To minimize of contact resistance, fabricated electrode was conducted hot compression process from room temperature to $65^{\circ}C$. We designed various pre-doping method for LIC structure and analyzing the doping mechanism issues. Finally, we suggest new pre-doping method to improve the capacitance and electrochemical stability for LIC.

• Journal of Electrical Engineering and Technology
• /
• v.11 no.6
• /
• pp.1664-1673
• /
• 2016

Lithium rechargeable cells are used in many industrial applications, because they have high energy density and high power density. For an effective use of these lithium cells, it is essential to build a reliable battery management system (BMS). Therefore, the state of charge (SOC) estimation is one of the most important techniques used in the BMS. An appropriate modeling of the battery characteristics and an accurate algorithm to correct the modeling errors in accordance with the simplified model are required for practical SOC estimation. In order to implement these issues, this approach presents the comparative analysis of the SOC estimation performance using equivalent electrical circuit modeling (EECM) and noise suppression technique (NST) in three representative $LiCoO_2/LiFePO_4/LiNiMnCoO_2$ cells extensively applied in electric vehicles (EVs), hybrid electric vehicles (HEVs) and energy storage system (ESS) applications. Depending on the difference between some EECMs according to the number of RC-ladders and NST, the SOC estimation performances based on the extended Kalman filter (EKF) algorithm are compared. Additionally, in order to increase the accuracy of the EECM of the $LiFePO_4$ cell, a minor loop trajectory for proper OCV parameterization is applied to the SOC estimation for the comparison of the performances among the compared to SOC estimation performance.

• Journal of the Korean Electrochemical Society
• /
• v.22 no.4
• /
• pp.139-147
• /
• 2019

Lithium-ion battery (LiB) with high energy density and efficiency has been utilized for the electric vehicle (EV) and energy storage system (ESS) as well as portable devices. However, as explosion accidents have frequently happened till lately, all-solid-state lithium secondary battery (ALSB) began to get in a spotlight because it can secure a very high safety and energy density by substituting flammable organic liquid electrolyte to nonflammable inorganic solid electrolyte. In spite of ALSB's certain merits, it has shown much poorer performance of cells than one of LiB due to some challenges, which have been small or never dealt with in the LiB system. Hence, although plenty of studies made progress to solve them, an approach about design of all-solid-state electrode (ASSE) has been limited on account of difficulty of ALSB's experiments. That is why the virtual 3D structure of an all-solid-state electrode has to be built and used for the prediction of cell performance. In this study, we elucidate how to form the 3D ASSE structure and what to be needed for the simulation of characteristics on ALSB. Furthermore, the ultimate orientation of 3D modeling and simulation for the study of ALSB are briefly suggested.

• Journal of Advanced Navigation Technology
• /
• v.19 no.5
• /
• pp.433-439
• /
• 2015

Recently, Interest in power the quality was increased because of increasing the use of sensitive load equipment into an electrical disturbance such as computer, Electricity, Electronics, Telecommunications and semiconductor device. In addition, To enhance power quality, the instantaneous voltage drop occurred in precision load equipment is a need for proper compensation. In order to solve the problem, The developed dynamic voltage restorer (DVR) using an electric double layer capacitor (EDLC) has been applied. In this paper, We will do study to apply hybrid capacitors that have high energy density to the same size compared to the EDLC to DVR. Also, As a emergency luminaires of emergency power supply that we can support more than 10 years of life was confirmed the applicability of hybrid capacitor.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.21 no.6
• /
• pp.662-671
• /
• 2020

Recently, for the purposes of reducing carbon dioxide(CO₂) emissions in the island area, countermeasures to decrease the operation rate of diesel generator(DG) and to increase one of renewable energy sources(RES) is being studied. In particular, the demonstration and installation of stand-alone micro-grid(MG) system which is composed of DG, RES and energy storage system(ESS) has been implemented in some island areas such as Gapa-do, Gasa-do and Ulleung-do island. However, many power quality(PQ) problems may be occurred due to an intermittent output of RES including photovoltaic(PV) system and wind power(WP) system in a normal operating of constant voltage & constant frequency(CVCF) inverter-based MG system. Therefore, this paper presents a modeling of the 30kW scale MG system using PSCAD/EMTDC, and also implements a 30kW scale CVCF inverter-based MG system as test devices to analyze normal operating characteristics of MG system. From the simulation and test results, it is confirmed that the proposed methods are useful and practical tools to improve PQ problems such as under-voltage, over-voltage and unbalanced load in CVCF inverter-based MG system.

• The Transactions of the Korean Institute of Power Electronics
• /
• v.22 no.4
• /
• pp.360-368
• /
• 2017

This paper proposes the 80-kW high-efficiency bidirectional hybrid SiC boost/buck converter using droop control for DC nano-grid. The proposed converter consists of four 20-kW modules to achieve fault tolerance, ease of thermal management, and reduced component stress. Each module is constructed as a cascaded structure of the two basic bi-directional converters, namely, interleaved boost and buck converters. A six-pack hybrid SiC intelligent power module (IPM) suitable for the proposed cascaded structure is adopted for high-efficiency and compactness. The proposed converter with hybrid switching method reduces the switching loss by minimizing switching of insulated gate bipolar transistor (IGBT). Each module control achieves smooth transfer from buck to boost operation and vice versa, since current controller switchover is not necessary. Furthermore, the proposed parallel control using DC droop with secondary control, enhances the current sharing accuracy while well regulating the DC bus voltage. A 20-kW prototype of the proposed converter has been developed and verified with experiments and indicates a 99.3% maximum efficiency and 98.8% rated efficiency.

• Korean Chemical Engineering Research
• /
• v.56 no.6
• /
• pp.871-877
• /
• 2018

Storing the surplus energy from renewable energy resource is one of the challenges related to intermittent and fluctuating nature of renewable energy electricity production. $CO_2$ methanation is well known reaction that as a renewable energy storage system. $CO_2$ methanation requires a catalyst to be active at relatively low temperatures ($250-500^{\circ}C$) and selectivity towards methane. In this study, the catalytic performance test was conducted using a pressurized bubbling fluidized bed reactor (Diameter: 0.025 m and Height: 0.35 m) with $Ni/{\gamma}-Al_2O_3$ (Ni70%, and ${\gamma}-Al_2O_3$30%) catalyst. The range of the reaction conditions were $H_2/CO_2$ mole ratio range of 4.0-6.0, temperature of $300-420^{\circ}C$, pressure of 1-9 bar, and gas velocity ($U_0/U_{mf}$) of 1-5. As the $H_2/CO_2$ mole ratio, temperature and pressure increased, $CO_2$ conversion increases at the experimental temperature range. However, $CO_2$ conversion decreases with increasing gas velocity due to poor mixing characteristics in the fluidized bed. The maximum $CO_2$ conversion of 99.6% was obtained with the operating condition as follows; $H_2/CO_2$ ratio of 5, temperature of $400^{\circ}C$, pressure of 9 bar, and $U_0/U_{mf}$ of 1.4-3.