• Title/Summary/Keyword: Energy Materials

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Fabrication and Mechanical Properties of High-strength Porous Supports for High Temperature Oxygen Transport Membrane (고온 산소분리막용 고강도 다공성 지지체 제조 및 기계적 특성 연구)

  • Park, Geum Sook;Seong, Young-Hoon;Yu, Ji Haeng;Woo, Sang Kuk;Han, Moon Hee
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.423-428
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    • 2013
  • Porous YSZ ceramics are fabricated using 3 mol% yittria-stabilized zirconia (3YSZ) and NiO with different particlesizes (0.6 and 7 ${\mu}m$). Nickel oxide (NiO) is added to the YSZ powder as a pore former with different amounts(40, 50, and 60 vol%) and at different sintering temperatures (1350 and $1400^{\circ}C$) are applied in order to evaluate the temperature effects on the pore and mechanical properties. Heat treatment is conducted after sintering at $700^{\circ}C$ in $H_2$ for the NiO reduction process; then, Ni is removed using a $HNO_3$ etchant solution. According to the NiO contentand sintering temperatures, 41-67% porous YSZ ceramic is obtained and the flexural strength increases, while the porosity decreases with an increasing sintering temperature. The optimum flexural strength ($136.5{\pm}13.4MPa$) and porosity (47%) for oxygen transport porous YSZ membrane can be obtained with 40 vol% of 7 ${\mu}m$ NiO particle at a sintering temperature of $1350^{\circ}C$.

Combined seismic and energy upgrading of existing reinforced concrete buildings using TRM jacketing and thermal insulation

  • Gkournelos, Panagiotis D.;Bournas, Dionysios A.;Triantafillou, Thanasis C.
    • Earthquakes and Structures
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    • v.16 no.5
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    • pp.625-639
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    • 2019
  • The concept of the combined seismic and energy retrofitting of existing reinforced concrete (RC) buildings was examined in this paper through a number of case studies conducted on model buildings (simulating buildings of the '60s-'80s in southern Europe) constructed according to outdated design standards. Specifically, seismic and thermal analyses have been conducted prior to and after the application of selected retrofitting schemes, in order to quantify the positive effect that retrofitting could provide to RC buildings both in terms of their structural and energy performance. Advanced materials, namely the textile reinforced mortars (TRM), were used for providing seismic retrofitting by means of jacketing of masonry infills in RC frames. Moreover, following the application of the TRM jackets, thermal insulation materials were simultaneously provided to the RC building envelope, exploiting the fresh mortar used to bind the TRM jackets. In addition to the externally applied insulation material, all the fenestration elements (windows and doors) were replaced with new high energy efficiency ones. Afterwards, an economic measure, namely the expected annual loss (EAL) was used to evaluate the efficiency of each retrofitting method, but also to assess whether the combined seismic and energy retrofitting is economically feasible. From the results of this preliminary study, it was concluded that the selected seismic retrofitting technique can indeed enhance significantly the structural behaviour of an existing RC building and lower its EAL related to earthquake risks. Finally, it was found that the combined seismic and energy upgrading is economically more efficient than a sole energy or seismic retrofitting scenario for seismic areas of south Europe.

Bandgap Engineering in CZTSSe Thin Films via Controlling S/(S+Se) Ratio

  • Vijay C. Karade;Jun Sung Jang;Kuldeep Singh, Gour;Yeonwoo Park;Hyeonwook, Park;Jin Hyeok Kim;Jae Ho Yun
    • Current Photovoltaic Research
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    • v.11 no.3
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    • pp.67-74
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    • 2023
  • The earth-abundant element-based Cu2ZnSn(S,Se)4 (CZTSSe) thin film solar cells (TFSCs) have attracted greater attention in the photovoltaic (PV) community due to their rapid development in device power conversion efficiency (PCE) >13%. In the present work, we demonstrated the fine-tuning of the bandgap in the CZTSSe TFSCs by altering the sulfur (S) to the selenium (Se) chalcogenide ratio. To achieve this, the CZTSSe absorber layers are fabricated with different S/(S+Se) ratios from 0.02 to 0.08 of their weight percentage. Further compositional, morphological, and optoelectronic properties are studied using various characterization techniques. It is observed that the change in the S/(S+Se) ratios has minimal impact on the overall Cu/(Zn+Sn) composition ratio. In contrast, the S and Se content within the CZTSSe absorber layer gets altered with a change in the S/(S+Se) ratio. It also influences the overall absorber quality and gets worse at higher S/(S+Se). Furthermore, the device performance evaluated for similar CZTSSe TFSCs showed a linear increase and decrease in the open circuit voltage (Voc) and short circuit current density (Jsc) of the device with an increasing S/(S+Se) ratio. The external quantum efficiency (EQE) measured also exhibited a linear blue shift in absorption edge, increasing the bandgap from 1.056 eV to 1.228 eV, respectively.

Influence of the Cooling Rate on the Phase Precipitation of Super Duplex Stainless Steel (슈퍼 듀플렉스 스테인리스강의 응고·냉각 시 상석출에 미치는 냉각속도의 영향)

  • Jang, Eun Seok;Kim, Ki Young;Kim, Suk Jun
    • Journal of Korea Foundry Society
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    • v.35 no.2
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    • pp.23-28
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    • 2015
  • This work presents the effect of the cooling rate on the precipitation of super duplex stainless steel. Specimens of super duplex stainless steel with a specific composition were cooled at various cooling rates after being melted at $1550^{\circ}C$ in a directional solidification furnace. Ferrite (${\delta}$), Austenite (${\gamma}$), Sigma (${\sigma}$), and Chi (${\chi}$) phases were precipitated when the cooling rate was lower than 0.22 K/s. When the cooling rate was 0.22 K/s or faster, ${\sigma}$ and ${\chi}$ phases were not precipitated.

High-temperature ultrasonic thickness monitoring for pipe thinning in a flow-accelerated corrosion proof test facility

  • Cheong, Yong-Moo;Kim, Kyung-Mo;Kim, Dong-Jin
    • Nuclear Engineering and Technology
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    • v.49 no.7
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    • pp.1463-1471
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    • 2017
  • In order to monitor the pipe thinning caused by flow-accelerated corrosion (FAC) that occurs in coolant piping systems, a shear horizontal ultrasonic pitch-catch waveguide technique was developed for accurate pipe wall thickness monitoring. A clamping device for dry coupling contact between the end of the waveguide and pipe surface was designed and fabricated. A computer program for multi-channel on-line monitoring of the pipe thickness at high temperature was also developed. Both a four-channel buffer rod pulse-echo type and a shear horizontal ultrasonic waveguide type for high-temperature thickness monitoring system were successfully installed to the test section of the FAC proof test facility. The overall measurement error can be estimated as ${\pm}10{\mu}m$ during a cycle from room temperature to $200^{\circ}C$.

The Effect of Casting Conditions on Shrinkage and Porosity of A356.2 Alloys (A356.2 합금의 수축과 기공에 미치는 주조 조건의 영향)

  • Jeon, Gyu-Tae;Kim, Ki-Young;Kim, Suk-Jun
    • Journal of Korea Foundry Society
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    • v.37 no.6
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    • pp.193-198
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    • 2017
  • In this study, volumes of shrinkage and porosity of A356.2 alloys during casting were analyzed as a function of melt temperature, pouring diameter, mold temperature, and Sr content. The temperature of the melt barely affected the shrinkage and porosity formation. The pouring diameter determined the pouring rate, and it was proportional to the shrinkage, yet no relationships with the density of porosity were observed. When the mold was heated at $400^{\circ}C$, shrinkage and porosity in the alloy increased above the one in the mold without heating. However, the mold without heating experienced interior shrinkage and the porosity was mainly distributed near interior shrinkage. The addition of Sr to the melt resulted in more shrinkage and less porosity.

Technical Overview on the Electron Backscattered Diffraction Sample Preparation

  • Kim, Dong-Ik;Kim, Byung-Kyu;Kim, Ju-Heon
    • Applied Microscopy
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    • v.45 no.4
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    • pp.218-224
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    • 2015
  • A technical overview on the various sample preparation methods for electron backscattered diffraction (EBSD) analysis is carried out. The mechanical polishing with colloidal silica finish, electro-chemical polishing, dual layer coating and ion beam milling are introduced for the common sample preparation methods for EBSD observation and some issues that are frequently neglected by the common EBSD users but should be considered to get a reliable EBSD data are discussed. This overview would be especially helpful to the people who know what EBSD technique is but do not get a reliable EBSD data because of difficulties in sample preparation.

Effect of $Mg^{2+}$ co-doping on luminescent properties of $ZnGa_2O_4:Mn^{2+}$

  • Singh, Binod Kumar;Bartwal, Kunwar Singh;Ryu, Ho-Jin
    • Journal of the Semiconductor & Display Technology
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    • v.6 no.4
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    • pp.29-32
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    • 2007
  • Zinc gallate, $ZnGa_2O_4:Mn^{2+}$ co-doped with different concentrations of $Mg^{2+}$ (0.001- 0.5 mol%) was prepared by solid state synthesis method. These compositions were investigated for their photoluminescence and cathodoluminescence properties. The optimized composition $Zn_{0.990}Mg_{0.005}Ga_2O_4:Mn_{0.005}$ shows higher luminescence intensity compared to the parent phosphor. The intense green emission peak was found at 504 nm. The $Mg^{2+}$ doping does not affect much the decay time. It remains <10 ms for these compositions which make them potential candidate for application in TV screens.

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A Study on the Hydrogenation Properties of Mechanically Alloyed Ti0.7Mg0.3Ni (기계적합금화에 의해 제조된 Ti0.7Mg0.3Ni합금의 수소화학반응특성에 관한 연구)

  • Kim, Eul-Soo;Ahn, Hyo-Jun;Kim, Ki-Won
    • Transactions of the Korean hydrogen and new energy society
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    • v.8 no.4
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    • pp.173-180
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    • 1997
  • The Mechanically Alloyed $Ti_{0.7}Mg_{0.3}Ni$ was investigated as a function of milling time by X-ray diffraction, SEM(scanning electron microscope), EDS(energy dispersive spectrometer), P-C-Isotherm curves. After 10hrs milling, mixed $Ti_{0.7}Mg_{0.3}Ni$ powders were changed to amorphous phase. And amorphous $Ti_{0.7}Mg_{0.3}Ni$ alloys became TiNi phase crystalline after heat treatment at 873K in a vacuum for 1 hour. The hydrogen absorption capacity of the annealed $Ti_{0.7}Mg_{0.3}Ni$ alloy increased as a function of mechanical alloying time.

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Effect of Particle Size of Cathode Materials on Discharge Properties of Thermal Batteries (양극 활물질의 입도에 따른 열전지 출력 특성 연구)

  • Lee, Jungmin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.6
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    • pp.399-406
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    • 2014
  • Thermal batteries are used for military power sources that require robustness and long storage life such as missiles and torpedoes. $FeS_2$ powder is currently used for cathode materials because of its high specific energy density, environmental non-toxicity and low cost. However, large particle size of conventional $FeS_2$ has been deterred its possible application for higher power thermal batteries. In order to improve the power density, high energy ball milling of $FeS_2$ has been introduced to crush the micron-sized $FeS_2$. Discharge characteristics of the single cells fabricated with nano-materials and conventional $FeS_2$ powder were evaluated.