• Title/Summary/Keyword: Energy Materials

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Experimental research on 2 stage GM-type pulse tube refrigerator for cryopump

  • Park, Seong-Je;Ko, Jun-Seok;Hong, Yong-Ju;Kim, Hyo-Bong;Yeom, Han-Kil;Koh, Deuk-Yong
    • Progress in Superconductivity and Cryogenics
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    • v.12 no.2
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    • pp.29-33
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    • 2010
  • The experimental results of the 2 stage Gifford-McMahon(GM) type pulse tube refrigerator (PTR) or cryopump are presented in this paper. The objectives of his study are to develop design technology of the integral type 2 stage PTR which rotary valve is directly connected to he hot end of the regenerator and acquire its improved performance. Design of the 2 stage PTR is conducted by FZKPTR(Forschungs Zentrum Karlsruhe Pulse Tube Refrigerator) program for the design of pulse tube refrigerators. The fabricated PTR has U-type configuration and incorporates orifice valve, double-inlet valve and reservoir as phase control mechanism. Rotary valve is used to make pulsating pressure and is directly connected to inlet of $1^{st}$ stage regenerator. From experiments, cooling performance map and pressure waveform at each point were measured for different operating frequencies. Experimental results show the best cooling performance with 2 Hz operation in spite of small pressure amplitude. The lowest temperatures of the 2 stage PTR were 16.9 K at the second stage and 58.0 K at the first stage. The cooling capacities achieved were 14.4 W at 79 K, the first stage and 3.6 W at 29 K, the second stage.

Mechanism of Surface Corrosion in the Continuous Casting Guide Rolls

  • Fazlollah Sadeghi;Tahereh Zargar;Yoon-Uk Heo;Jae Sang Lee;Dong-Yong Park;NamKyu Park;Dae Geun Hong;Chang Hee Yim
    • Journal of Korea Foundry Society
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    • v.43 no.2
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    • pp.55-63
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    • 2023
  • Due to the importance of the surface on the final slab quality, it is essential to maintain a smooth segment roll surface that is in touch with the thin solid shell during solidification. In this paper, the surface of the used continuous casting guide roll was analyzed to realize the mechanism of its surface deterioration. Surface analysis has revealed severe corrosion at two distinct areas leading to deep roughness occurring on the guide roll. Firstly, the severe corrosion follows prior austenite grain boundary due to exposure with acidic environment. Also, in heat affected zone (HAZ) where two cladding beads overlap, more severe corrosion takes place. The overheat input results in local ferritization without full melting which increases retained δ-ferrite content almost 10 times higher than surrounding area. Corrosion was observed to happen at the δ-γ interface where Cr depletion takes place.

Residual stress distribution analysis in a J-groove dissimilar metal welded component of a reactor vessel bottom head using simulation and experiment

  • Dong-Hyun Ahn;Jong Yeon Lee;Min-Jae Choi;Jong Min Kim;Sung-Woo Kim;Wanchuck Woo
    • Nuclear Engineering and Technology
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    • v.56 no.2
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    • pp.506-519
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    • 2024
  • To simulate the verification process using materials from a decommissioned reactor, a mock-up of the bottom-mounted instrument nozzle in the Kori 1 reactor, where the nozzle was attached to a plate by J-groove dissimilar metal welding, was fabricated. The mock-up distortion was quantified by measuring the plate surface displacement after welding. The residual stresses formed on the support plate surface and the inner surface of the nozzle were then analyzed using the hole-drilling method, contour method, and neutron diffraction. Welding simulations were performed using a 3D finite element method to validate the measured results. The measured and computed stress distributions on the support plate exhibited reasonable agreement. Conversely, the stresses on the inside of the nozzle were found to have an indisputable difference in the contour method and neutron diffraction measurements, which demonstrated strong tensile and compressive hoop stresses, respectively. The possible origins of such differences were investigated and we have provided some suggestions for a precise evaluation in the simulation. This study is expected to be useful in future research on decommissioned reactors.

Fabrication and Ion Irradiation Characteristics of SiC-Based Ceramics for Advanced Nuclear Energy Systems (차세대 원자력 시스템용 탄화규소계 세라믹스의 제조와 이온조사 특성 평가)

  • Kim, Weon-Ju;Kang, Seok-Min;Park, Kyeong-Hwan;Kohyama Akira;Ryu, Woo-Seog;Park, Ji-Yeon
    • Journal of the Korean Ceramic Society
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    • v.42 no.8 s.279
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    • pp.575-581
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    • 2005
  • SiC-based ceramics are considered as candidate materials for the advanced nuclear energy systems such as the generation IV reactors and the fusion reactors due to their excellent high-temperature strength and irradiation resistance. The advanced nuclear energy systems and their main components adopting ceramic composites were briefly reviewed. A novel fabrication method of $SiC_f/SiC$ composites by introducing SiC whiskers was also described. In addition, the charged-particle irradiation ($Si^{2+}$ and $H^{+}$ ion) into CVD SiC was carried out to simulate the severe environments of the advanced nuclear reactors. SiC whiskers grown in the fiber preform increased the matrix infiltration rate by more than $60\%$ compared to the conventional CVI process. The highly crystalline and pure SiC showed little degradation in hardness and elastic modulus up to a damage level of 10 dpa at $1000^{\circ}C$.

SiC Contaminations in Polycrystalline-Silicon Wafer Directly Grown from Si Melt for Photovoltaic Applications (실리콘 용탕으로부터 직접 제조된 태양광용 다결정 실리콘의 SiC 오염 연구)

  • Lee, Ye-Neung;Jang, Bo-Yun;Lee, Jin-Seok;Kim, Joon-Soo;Ahn, Young-Soo;Yoon, Woo-Young
    • Journal of Korea Foundry Society
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    • v.33 no.2
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    • pp.69-74
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    • 2013
  • Silicon (Si) wafer was grown by using direct growth from Si melt and contaminations of wafer during the process were investigated. In our process, BN was coated inside of all graphite parts including crucible in system to prevent carbon contamination. In addition, coated BN layer enhance the wettability, which ensures the favorable shape of grown wafer by proper flow of Si melt in casting mold. As a result, polycrystalline silicon wafer with dimension of $156{\times}156$ mm and thickness of $300{\pm}20$ um was successively obtained. There were, however, severe contaminations such as BN and SiC on surface of the as-grown wafer. While BN powders were easily removed by brushing surface, SiC could not be eliminated. As a result of BN analysis, C source for SiC was from binder contained in BN slurry. Therefore, to eliminate those C sources, additional flushing process was carried out before Si was melted. By adding 3-times flushing processes, SiC was not detected on the surface of as-grown Si wafer. Polycrystalline Si wafer directly grown from Si melt in this study can be applied for the cost-effective Si solar cells.

Effect of Processing Parameters on Direct Fabrication of Polycrystalline Silicon Wafer (다결정 실리콘 웨이퍼 직접제조에 대한 공정변수 영향)

  • Wi, Sung-Min;Lee, Jin-Seok;Jang, Bo-Yun;Kim, Joon-Soo;Ahn, Young-Soo;Yoon, Woo-Young
    • Journal of Korea Foundry Society
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    • v.33 no.4
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    • pp.157-161
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    • 2013
  • A ribbon-type polycrystalline silicon wafer was directly fabricated from liquid silicon via a novel technique for both a fast growth rate and large grain size by exploiting gas pressure. Effects of processing parameters such as moving speed of a dummy bar and the length of the solidification zone on continuous casting of the silicon wafer were investigated. Silicon melt extruded from the growth region in the case of a solidification zone with a length of 1cm due to incomplete solidification. In case of a solidification zone wieh a length of 2 cm, on the other hand, continuous casting of the wafer was impossible due to the volume expansion of silicon derived from the liquid-solid transformation in solidification zone. Consequently, the optimal length of the solidification zone was 1.5 cm for maintaining the position of the solid-liquid interface in the solidification zone. The silicon wafer could be continuously casted when the moving speed of the dummy bar was 6 cm/min, but liquid silicon extruded from the growth region without solidification when the moving speed of the dummy bar was ${\geq}$ 9 cm/min. This was due to a shift of the position of the solid-liquid interface from the solidification zone to the moving area. The present study reports experimental findings on a new direct growth system for obtaining silicon wafers with both high quality and productivity, as a candidate for an alternate route for the fabrication of ribbon-type silicon wafers.

Processing Study for the Piezoelectric Energy Harvest of Composit Structure (복합구조의 압전 에너지 하베스터를 위한 공정연구)

  • Lee, Kyoung-Soo;Shin, Dong-Jin;Koh, Jung-Hyuk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.4
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    • pp.286-289
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    • 2012
  • In this paper, we have proposed piezoelectric energy harvester employing the pillar structure with the diameter size of 500 um. So we have selected the Su-8 photo-resist and modified lithography process to manufacture the pillar structure with height above the $500{\mu}m$. Simultaneously, we tried to make a comparative study to use ceramic bulk - polymer structure In this paper, we will report the process and properties of micro pillar structure based on the PMN-PZT ($Pb(Mg_{1/3}Nb_{2/3})O_3-PbZrTiO_3$) materials. Finally, We will propose a method for generating electrical energy with a piezoelectric element using vibration, an energy source can be obtained from the "clean" energy.

Effect of Crystal Shape on the Grain Growth during Liquid Phase Sintering of Ceramics

  • Jo, Wook;Hwang, Nong-Moon;Kim, Doh-Yeon
    • Journal of the Korean Ceramic Society
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    • v.43 no.11 s.294
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    • pp.728-733
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    • 2006
  • The equilibrium or growth shape of ceramic materials is classified largely into two categories according to the thermodynamic conditions imposed. One is a polyhedral shape where the surface free energy is anisotropic, and the other a spherical shape where the surface free energy is isotropic. In the case of grains with a polyhedral shape of anisotropic surface free energy, socalled abnormal grain growth usually takes place due to a significant energy barrier for a growth unit to be attached to the crystal surface. In the case of grains with a spherical shape of isotropic surface free energy, however, normal grain growth with a uniform size distribution takes place. In this contribution, the state-of-the-art of our current understanding of the relationship between the crystal shape and the microstructure evolution during the sintering of ceramic materials in the presence of a liquid phase was discussed.

Electrocatalytic Activity of Sulfamic Acid Doped Polyaniline Nanofiber Counter Electrode for Dye Sensitized Solar Cell

  • Jo, Chul-Gi;Ameen, Sadia;Akhtar, M.Shaheer;Kim, Young-Soon;Yang, O-Bong;Shin, Hyung-Shik
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.385-385
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    • 2009
  • Uniform polyaniline nanofibers (PANI NFs), and chemically doped sulfamic acid(SFA) PANI NFs, synthesized via template free interfacial polymerization process, were used as new counter electrodes materials for the fabrication of the highly-efficient dyesensitized solar cells (DSSCs). The PANI NFs based fabricated DSSCs exhibited a solarto-electricity conversion efficiency of ~ 4.02% while, the SFA doped PANI NFs based DSSC demonstrated ~ 27% improvement in the solar-to-electricity conversion efficiency. The obtained solar-to-electricity conversion efficiency for SFA doped PANI NFs based DSSC was 5.47% under 100mW/$cm^2$(AM1.5). The enhancement in the conversion efficiency was due to the incorporation of SFA into the PANI NFs which resulted to the higher electrocatalytic activity for the $I^{3-}/I^-$ redox reaction.

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