• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.30 no.2
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• pp.71-77
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• 2016

The dielectric barrier discharge (DBD) has low efficiency due to about 70% input power is consumed as thermal energy in the discharge space. However, because of the usage of DBD ozone generator is easier than other methods. The DBD ozone generator has been widely applied for high concentration ozone generation in the industrial application. But, the low-capacity compact DBD ozone generator is not applied so far. Therefore, the DBD ozone generator is necessary to improve ozone production efficiency and reduce the capacity. In this paper, the stainless steel pipe inner electrode was designed with hall type and screw type to improve the ozone production yield. The manufactured two inner electrodes were experimented with normal type for comparison of the discharge characteristics and the ozone generating characteristics. As the experimental results, the discharge current effective value of designed inner electrodes with hall type and screw type are higher than the normal type, due to unequal electric field is formed at the boundary. However, the difference of designed and original electrodes is less than 0.1mA that has no effect on the discharge characteristic. On the other hand, the screw type inner electrode increased higher than original model about 7 times when the flow rate of the oxygen source gas was increased from $0.6{\ell}/min$ to $1.0{\ell}/min$ The reason was assumed by the flow rate of the raw gas through the inner electrode was became fast that has a cooling effect. The designed hall type and screw type inner electrodes have shown good performances in ozone generation and ozone production that better than normal type in the same electrode surface area.

• BMB Reports
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• v.47 no.9
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• pp.494-499
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• 2014

NADH:quinone oxidoreductase 1 (NQO1) is known to be involved in the regulation of energy synthesis and metabolism, and the functional studies of NQO1 have largely focused on metabolic disorders. Here, we show for the first time that compared to NQO1-WT mice, NQO1-KO mice exhibited a marked increase of permeability and spontaneous inflammation in the gut. In the DSS-induced colitis model, NQO1-KO mice showed more severe inflammatory responses than NQO1-WT mice. Interestingly, the transcript levels of claudin and occludin, the major tight junction molecules of gut epithelial cells, were significantly decreased in NQO1-KO mice. The colons of NQO1-KO mice also showed high levels of reactive oxygen species (ROS) and histone deacetylase (HDAC) activity, which are known to affect transcriptional regulation. Taken together, these novel findings indicate that NQO1 contributes to the barrier function of gut epithelial cells by regulating the transcription of tight junction molecules.

• Polymer(Korea)
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• v.34 no.1
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• pp.69-73
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• 2010

Effects of reaction time and temperature on the isomerization and dehydrobromination reactions of brominated butyl rubber were investigated. The structural composition of brominated butyl rubber was determined by Fourier transform infrared spectroscopy (FT-IR) and proton nuclear magnetic resonance spectroscopy($^1H$-NMR), Density functional theory (DFT) was used to study on the isomerization and dehydrobromination mechanisms of model compounds. The geometries for model compounds of 3-bromo-5,5,7,7-tetramethyl-2(2',2',4',4'-tetramethyl)pentyl-1-octylene (3BrOE), 1-bromo-5,5,7,7-tetramethyl-2(2',2',4',4'-tetramethyl)pentyl-2-octylene (1Br2OE) and 5,5,7,7-tetramethyl-2(2',2', 4',4'-tetramethyl)pentyl-1,3-octadiene (CD) had been optimized by using density functional theory at B3LYP/3-21G and B3LYP/6-31G levels. The predicted energy of 3BrOE lies higher than that of 1Br2OE which suggests that 1Br2OE configuration is more stable than the 3BrOE configuration. Compared with the energy barrier, the pathway of dehydrobromination is less competitive than that of isomerization. This is qualitatively consistent with the experimental results.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.08a
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• pp.234-234
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• 2010

The PR transitions in asymmetric dot-in-double-quantum-well (DdWELL) photodetector is identified by bias-dependent spectral behaviors. Discrete n-i-n infrared photodetectors were fabricated on a 30-period asymmetric InAs-QD/[InGaAs/GaAs]/AlGaAs DdWELL wafer that was prepared by MBE technique. A 2.0-monolayer (ML) InAs QD ensemble was embedded in upper combined well of InGaAs/GaAs and each stack is separated by a 50-nm AlGaAs barrier. Each pixel has circular aperture of 300 um in diameter, and the mesa cell ($410{\times}410\;{\mu}m^2$) was defined by shallow etching. PR measurements were performed in the spectral range of $3{\sim}13\;{\mu}m$ (~ 100-400 meV) by using a Fourier-transform infrared (FTIR) spectrometer and a low-noise preamplifier. The asymmetric photodetector exhibits unique transition behaviors that near-/far-infrared (NIR/FIR) photoresponse (PR) bands are blue/red shifted by the electric field, contrasted to mid-infrared (MIR) with no dependence. In addition, the MIR-FIR dual-band spectra change into single-band feature by the polarity. A four-level energy band model is proposed for the transition scheme, and the field dependence of FIR bands numerically calculated by a simplified DdWELL structure is in good agreement with that of the PR spectra. The wavelength shift by the field strength and the spectral change by the polarity are discussed on the basis of four-level transition.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.5 no.4
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• pp.273-281
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• 2007

Hyperalkaline groundwater formed by groundwater-cement components and its reaction with bedrock in a nuclear waste repository were simulated by geochemical modeling. The result of groundwater-cement components reaction showed that the pH of water was 13.3 and the precipitated minerals were Brucite, Katoite, Calcium Silicate Hydrate(CSH1.1), Ettringite, Hematite, and Portlandite. The result of interaction between such minerals and groundwater sampled in Gyeongju area also showed that the pH of groundwater reached 12.4. Interaction between such hyperalkaline groundwater and granite was simulated by kinetic model during $10^3$ years. This result showed that the final pH of groundwater reached 11.2 and the variation of pH was controlled by dissolution/precipitation of silicate and CSH minerals. Groundwater quality was also determined by dissolution/precipitation of silicate, CSH, oxide minerals. Our results show that geochemical modeling of long-term hyperalkaline groundwater and rock interaction can contribute to the safety assessment of engineered barrier by predicting geochemical condition in repository site.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.17 no.3
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• pp.329-338
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• 2019

Suction of unsaturated bentonite buffers is a very important input parameter for hydro-mechanical performance assessment and design of an engineered barrier system. This study analyzed suction measurement techniques and constitutive models of unsaturated porous media reported in the literature, and suggested suction measurement techniques and constitutive models suitable for bentonite buffer in an HLW repository. The literature review showed the suction of bentonite buffer to be much higher than that of soil, as measured by total suction including matric suction and osmotic suction. The measurement methods (RH-Cell, RH-Cell/Sensor) using a relative humidity sensor were suitable for suction measurement of the bentonite buffer; the RH-Cell /Sensor method was more preferred in consideration of the temperature change due to radioactive decay heat and measurement time. Various water retention models of bentonite buffers have been proposed through experiments, but the van Genuchten model is mainly used as a constitutive model of hydro-mechanical performance assessment of unsaturated buffers. The water characteristic curve of bentonite buffers showed different tendencies according to bentonite type, dry density, temperature, salinity, sample state and hysteresis. Selection of water retention models and determination of model input parameters should consider the effects of these controlling factors so as to improve overall reliability.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.4 no.2
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• pp.197-207
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• 2006

The engineering performance of a high level waste repository is significantly dependent upon the T-H-M behavior in the engineered barrier system. An engineering-scale test facility (KENTEX) was set up to validate the T-H-M behaviors in the buffer of a reference disposal system developed in the 2002. The validation tests started on May 31, 2005 and is now in progress. The KENTEX facility and validation test programme are introduced, and pre-operation calculations are also presented to give information on the sensitive location of sensors and operational conditions. This test will provide information (e.g., large-scale apparatus, sensors, monitoring system etc.) needed for 'in-situ' tests, make the validation of a T-H-M model for the T-H-M performance assessment of the reference disposal system, and demonstrate the engineering feasibility of fabricating and emplacing the buffer of a repository.

• Journal of the Microelectronics and Packaging Society
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• v.26 no.4
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• pp.95-100
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• 2019

Nanoindentation has been widely used for evaluating mechanical properties of nano-devices, from MEMS to packaging modules. Residual stress is also estimated from indentation tests, especially the Knoop indenter which is used for the determination of residual stress directionality. According to previous researches, the ratio of the two stress conversion factors of Knoop indentation is a constant at approximately 0.34. However, the ratio is supported by insufficient quantitative analyses, and only a few experimental results with indentation depth variation. Hence, a barrier for in-field application exists. In this research, the ratio of two conversion factors with variation in indentation depth using finite elements method has been attempted at. The magnitudes of each conversion factors were computed at uniaxial stress state from the modelled theoretical Knoop indenter and specimen. A model to estimate two stress conversion factor of the long and short axis of Knoop indenter at various indentation depths is proposed and analyzed.

• Tunnel and Underground Space
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• v.31 no.5
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• pp.309-332
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• 2021

Natural barrier systems surrounding the geological repository for the high-level radioactive waste should guarantee the hydraulic performance for preventing or delaying the leakage of radionuclide. In the case of the behavior of a crystalline rock, the hydraulic performance tends to be decided by the existence of discontinuities, so the coupled hydro-mechanical(HM) processes on the discontinuities should be characterized. The discontinuum modelling can describe the complicated behavior of discontinuities including creation, propagation, deformation and slip, so it is appropriate to model the behavior of a crystalline rock. This paper investigated the coupled HM processes in discontinuum modelling such as UDEC, 3DEC, PFC, DDA, FRACOD and TOUGH-UDEC. Block-based discontinuum methods tend to describe the HM processes based on the fluid flow through the discontinuities, and some methods are combined with another numerical tool specialized in hydraulic analysis. Particle-based discontinuum modelling describes the overall HM processes based on the fluid flow among the particles. The discontinuum methods that are currently available have limitations: exclusive simulations for two-dimension, low hydraulic simulation efficiency, fracture-dominated fluid flow and simplified hydraulic analysis, so it could be improper to the modelling the geological repository. Based on the concepts of various discontinuum modelling compiled in this paper, the advanced numerical tools for describing the accurate coupled HM processes of the deep geological repository should be developed.

• Tunnel and Underground Space
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• v.33 no.4
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• pp.228-243
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• 2023

Bentonite is widely recognized and utilized as a buffer material in high-level radioactive waste repositories, mainly due to its favorable characteristics such as swelling capability and low permeability. Bentonite buffers play an important role in ensuring the safe disposal of radioactive waste by providing a low permeability barrier and effectively preventing the migration of radionuclides into the surrounding rock. However, the long-term performance of bentonite buffers still remains a subject of ongoing research, and one of the main concerns is the erosion of the buffer induced by swelling and groundwater flow. The erosion of the bentonite buffer can significantly impact repository safety by compromising the integrity of buffer and leading to the formation of colloids that may facilitate the transport of radionuclides through groundwater, consequently elevating the risk of radionuclide migration. Therefore, it is very important to numerically quantify the erosion of bentonite buffer to evaluate the long-term performance of bentonite buffer, which is crucial for the safety assessment of high-level radioactive waste disposal. In this technical note, Two-region model is introduced, a proposed model to simulate the erosion behavior of bentonite based on a dynamic bentonite diffusion model, and quantitative evaluation is conducted for the bentonite buffer erosion with this model.