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Structure and herbicidal activity relationships of the 2,3-dihydro-2,3,4,6,7-penta-methylbenzofuran-5-yl substituents in 5-benzofuryl-2-[1-(alkoxyimine) alkyl]-3-hydroxycyclohex-2-en-1-ones (5-Benzofuryl-2-[1-(alkoxyimine) alkyl]-3-hydroxycyclohex-2-en-1-one 유도체의 구조-활성관계 2,3-dihydro-2,3,4,6,7-pentamethylben-zofuran-5-yl 치환체들의 구조와 제초 활성과의 관계)

  • Sung, Nack-Do;Song, Jong-Hwan;Jeon, Dong-Ju
    • The Korean Journal of Pesticide Science
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    • v.5 no.3
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    • pp.12-17
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    • 2001
  • A new 2,3-dihydro-2,3,4,6,7-pentamethylbenzofuran-5-yl substituents in 5-benzofuryl-2-[1-(alkoxyimine) alkyl]-3-hydroxycyclohex-2-en-1-ones were found to have herbicidal activity against rice plant (Oryza sativa L.) and barnyard grass (Echinochloa crus-galli) under submerged conditions. The structure activity. relationships (SARs) on the herbicidal activity of $R_1\;and\;R_2$ on the azomethine bond of 2,3-dihydro-2,3,4,6,7-pentamethylbenzofuran-5-yl subsituents were analysized. The conditions of the selective herbicide activity between rice plant (seed) and barnyard grass from the basis on the analysized SARs are assumed that the $R_2$ group of ethyl substituent ($R_1$ ) should have optimal asymmetry parameter, $(L/B_1)_{opt.}=3.96{\AA}$. And also, the $R_2$ groups consist of $C_1{\sim}C_3$ and unsaturated group such as 3-chloro-2-propenyl group was contribution to the herbicide activity.

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Inter-comparison between ultrasonic interferometer manometer and medium vacuum standards by static expansion method (초음파간섭 수은주압력계와 정적법 중진공 국가표준기 상호비교)

  • Hong S. S.;Lim I. T.;Shin Y. H.;Chung K. H.
    • Journal of the Korean Vacuum Society
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    • v.14 no.3
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    • pp.103-109
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    • 2005
  • A new medium vacuum primary standard using the static expansion method was developed in KRISS. In order to evaluate the performance of the equipment, we compared the medium vacuum standard with an ultrasonic interferometer manometer using two capacitance diaphragm gauges, the measuring ranges of which were 133 Pa and 1,333 Pa respectively. The result, Error normalized values, showed that the two standards are coincident each other within the range of combined uncertainty at calibrated pressure of $3pa\;\sim\;100pa$.

Classification of Reaction-to-Fire's Performances on Sandwich Panel Systems by Applying to ISO 13784-1 Fire Tests (실대규모 화재시험(ISO 13784-1)을 적용한 샌드위치 패널 시스템의 연소성능 분류)

  • Park, Kye-Won;Im, Hong-Soon;Jeong, Jae-Gun;Lee, Gil-Yong;Kim, Jeong-Uk;Jeong, Jeong-Ho;Lee, Woo-Seok;Kim, Woon-Hyung
    • Fire Science and Engineering
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    • v.23 no.2
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    • pp.20-26
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    • 2009
  • Reaction-to-Fire's performances such as combustion properties of sandwich panels were tested according to ISO 13784-1 (room corner test for sandwich panel building systems) method which is made for the purpose of supplementing ISO 9705 room corner test, and analyzed comparatively. Several variables including heat release rate, smoke production rate, FIGRA, SMOGRA, thermal configuration, visual check lists and so on, were analyzed for specific four materials on sandwich panel systems. Finally, Reaction-to-Fire's performances of test results on each material by ISO 13784-1 are categorized by applying to the classification systems of both EN 13501-1 and Eurefic Research Program.

On the Aquation of Dichloro Bis-(Ethylenediamine)-Chromium (III) Cation (Dichloro Bis-(Ethylenediamine)-Chromium (III) 양이온의 수화반응)

  • Jung-Ui Hwang;Jong-Jae Chung;Soung-Oh Bek
    • Journal of the Korean Chemical Society
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    • v.28 no.2
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    • pp.95-101
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    • 1984
  • Aquation reaction kinetics of $[Cr(en)_2Cl_2]^+$complex was carried by the electric conductivity method. Its temperature range was $15^{\circ}C$ to $30^{\circ}C$ and pressure was varied up to 2,000 bars. The reaction rate was increased with increasing temperature, but was reversed to increasing pressure. The activation volume(${\Delta}V^{\neq}$) was increased with increasing temperature and decreased with increasing pressure. At $25^{\circ}C$ and 1 bar it was fairly small positive value, $1.82cm^2/mole$. Activation entropy change(${\Delta}S^{\neq}$) $was calculated as small negative value,-9.019 eu, at $25^{\circ}C$ and 1bar. Referring to the thermodynamic parameters, it was estimated that aquation reaction was proceeded by the interchange-dissociation(Id) mechanism.

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An Adaptive Threshold Determining Method in Senor Networks using Fuzzy Logic (통계적 여과기법에서 퍼지 규칙을 이용한 적응적 보안 경계 값 결정 방법)

  • Sun, Chung-Il;Cho, Tae-Ho
    • 한국정보통신설비학회:학술대회논문집
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    • 2008.08a
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    • pp.177-180
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    • 2008
  • There are many application areas of sensor networks, such as surveillance, hospital monitoring, and home network. These are dependent on the secure operation of networks, and will have serious outcome if the networks is injured. An adversary can inject false data into the network through the compromising node. Ye et al. proposed a statistical en-route filtering scheme (SEF) to detect such false data during forwarding process. In this scheme, it is important that the choice of the threshold value since it trades off security and overhead. This paper presents an adaptive threshold value determining method in the SEF using fuzzy logic. The fuzzy logic determines a security distance value by considering the situation of the network. The Sensor network is divided into several areas by the security distance value, it can each area to uses the different threshold value. The fuzzy based threshold value can reduce the energy consumption in transmitting.

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Solvent Effect on the Aquation of $trans-[Cr(en)_2Br_2]^+$ Ion and its Mechanism ($trans-[Cr(en)_2Br_2]^+$ 착이온의 수화반응에 미치는 용매효과와 그 반응메카니즘)

  • Jeong, Jong Jae;Lee, Seong Ho;Baek, Seong O
    • Journal of the Korean Chemical Society
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    • v.34 no.2
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    • pp.123-129
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    • 1990
  • The rate constants for the solvolysis of $trans-[Cr(en)_2Br_2]^+$ ion were determined by the spectrophotometric method in methanol-, ethanol-, acetone-, and acetonitrile-water mixtures, at 20, 25, 30, and 35$^{\circ}C$, respectively. The rate constants increased with increasing co-solvent compositions. The rate constant did not show any relation with the reciprocal of dielectric constant of the solvent-mixtures. The m values of Grunwald-Winstein equation for methanol-, ethanol-, acetonitrile-, and acetone-water mixtures are 0.109, 0.103, 0.101, and 0.095, respectively. A free energy cycle for the process from the initial state to the transition state in water and water + co-solvent mixtures shows that the change in solvation at the transition state has a dominant effect on the rate. From the above results, it is believed that the mechanism for the aquation of this complex is the Id mechanism.

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Cytotoxicity of Various Calcium Silicate-based Materials with Stem Cells from Deciduous Teeth (유치 줄기세포에 대한 다양한 규산칼슘계 재료의 세포독성)

  • Yun, Jihye;You, Yong-Ouk;Ahn, Eunsuk;Lee, Jun;An, So-Youn
    • Journal of the korean academy of Pediatric Dentistry
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    • v.46 no.1
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    • pp.85-92
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    • 2019
  • The purpose of this study was to compare and evaluate the cytotoxicity of 3 calcium silicate-based materials (CSMs) on stem cells from human exfoliated deciduous teeth (SHEDs). The powder of Retro $MTA^{(R)}$ (RM), $EZ-Seal^{TM}$ (EZ) and ENDOCEM $Zr^{(R)}$ (EN) was eluted with SHED culture media and then filtered. The SHEDs were cultured in the presence of the various concentrations of the eluate. To investigate the effect of the 3 CSMs on SHED proliferation, the MTS (3-(4,5-dimethylthiazol-2-yl)-5-(3-carboxymethoxyphenyl)-2-(4-sulfophenyl)-2H-tetrazolium) assay was performed. Flow cytometry analysis was also performed to identify any changes in the cellular phenotype. The absorbance values of the SHEDs cultured in the eluate of samples at a 10% concentration showed the following relation: RM > EN > EZ (p = 0.0439). However, the SHEDs maintained their mesenchymal phenotype regardless of product exposure. Although the 3 CSMs did not alter the SHED stem cell markers, EZ may be a less cytocompatible than RM and EN.

Physiochemical Properties of Functional Oils Produced Using Red Yeast-Rice Ethanol Extracts and Diacylglycerol Oil (홍국쌀 에탄올 추출물과 Diacylglycerol Oil을 이용하여 제조한 기능성 유지의 이화학적 특성 연구)

  • Kim, Nam-Sook;Lee, Ki-Teak
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.36 no.2
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    • pp.201-208
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    • 2007
  • Functional oils (FOs) were produced from commercial diacylglycerol oil and red yeast rice extracts from 80% ethanol for 1 hr in a shaking water bath at $35^{\circ}C$ and 175 rpm. FOs contained (A) 600, (B) 1200, (C) 1800, and (D) 2280 ppm of red yeast-rice extracts, respectively. The Hunter a value and b value were risen whereas L value was reduced along with the increase of extract concentration. Content of monacolin K and total phenolic compounds in FOs significantly increased according to the increase of extract concentration. The oxidation stability of FOs was observed by Rancimat at $98^{\circ}C$. Induction time decreased according to the increase of extract concentration. The major volatile compounds of FOs were compared using the electronic nose (EN) system and solid phase microextraction (SPME) method combined with gas chromatograph/mass spectrometry (GC/MS). EN was composed of 12 different metal oxide sensors. Sensitivities (Rgas/Rair) of sensors from EN were analyzed by principal component analysis (PCA), whose proportion was 99.66%. For qualitative or quantitative analysis of volatile compounds by SPME-GC/MS, the divinylbenzene/carboxene/polydimethyl-siloxane fiber and sampling temperature of $50^{\circ}C$ were applied.

Estimation of Sediment Concentration Factor based on Entropy Theory (엔트로피 이론 기반의 유사농도 인자 산정)

  • Kim, Yeong-Sik;Nam, Yoon-Chang;Jeon, Hae-Sung;Jeon, Kun-Hak;Choo, Yeon-Moon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.10
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    • pp.325-333
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    • 2020
  • Current methods of measuring the sediment concentration of natural streams can be affected by weather conditions and have lower reliability in bed-load sections due to mechanical limits. Theoretical methods have to be used to solve this problem, but they have low reliability compared to the measured values and diverse results for the bed-load sediment concentration. This study proposes a new way to reliably determine the bed-load sediment concentration from the relation with theoretical depth-integrated concentration based on the informational entropy concept. Sediment distribution shows a uniform probability distribution under maximized entropy conditions under some constraints, so a function can be calculated for the sediment distribution and depth-integrated concentration. The parameters of a stream were estimated by a nonlinear regression method using the concentration data from a past experiment. Equilibrium N (EN) was estimated using the relation between two different formulas proposed in this study, which can ease the estimation of both the total sediment distribution and depth-integrated sediment concentration with high reliable results with an average R2 of 0.924.

Accuracy Improvement Methode of Step Count Detection Using Variable Amplitude Threshold (가변 진폭 임계값을 이용한 걸음수 검출 정확도 향상 기법)

  • Ryu, Uk Jae;Kim, En Tae;An, Kyung Ho;Chang, Yun Seok
    • KIPS Transactions on Computer and Communication Systems
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    • v.2 no.6
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    • pp.257-264
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    • 2013
  • In this study, we have designed the variable amplitude threshold algorithm that can enhance the accuracy of step count using variable amplitude. This algorithm converts the x, y, z sensor values into a single energy value($E_t$) by using SVM(Signal Vector Magnitude) algorithm and can pick step count out over 99% of accuracy through the peak data detection algorithm and fixed peak threshold. To prove the results, We made the noise filtering with the fixed amplitude threshold from the amplitude of energy value that found out the detection error was increasing, and it's the key idea of the variable amplitude threshold that can be adapted on the continuous data evaluation. The experiment results shows that the variable amplitude threshold algorithm can improve the average step count accuracy up to 98.9% at 10 Hz sampling rate and 99.6% at 20Hz sampling rate.