• Elastomers and Composites
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• 제50권4호
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• pp.304-313
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• 2015

In this study, the anionic emulsified asphalt was prepared by dispersing asphalt particles evenly into water with combination of anionic and nonionic surfactants. Effects of NaOH and $CaCl_2$ on the phase stability of the emulsified asphalt were also investigated through zeta potential value and rheology behavior; the emulsified asphalt added with NaOH and $CaCl_2$ showed higher zeta potential value than that the asphalt with addition of only anionic and nonionic surfactants. In addition, with regard to shear thinning behaviors, it was found that pH of the emulsified anionic asphalt and $Ca^{2+}$, counter ion, affected the phase stability. SBR (styrene-butadiene-rubber) latex, EPD (water dispersed Epoxy), PU (polyurethane) and RI-10S, SBS (styrene-butadiene-styrene)-based property improvement additive, were used and studied to enhance the adhesion properties with the aggregates. RI-10S, however, was found to be only compatible with the anionic emulsified asphalt; the coating rate, adhesion and compression strength were increased with the RI-10S content.

• Elastomers and Composites
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• 제50권4호
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• pp.265-273
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• 2015

In this work, the emulsified asphalt with high phase stability and storage stability was prepared by using phase inversion emulsification and the surfactant mixed with cationic and nonionic surfactants. It was found that the asphalt together with Span 20, nonionic surfactant and DDA (Dimethyl Dodecyl Amine), cationic surfactant showed the most stable phase. The phase stability of the emulsified asphalt, therefore, was investigated through the particle size with mixed surfactant content, rheology behavior and Zeta potential value; the particle size decreased with the increase of the mixed surfactant content but the viscosity increased. The shear thinning behaviors and the Zeta potential value with 50 mV~60 mV were shown, which was found to be considered stable. In addition, SBR latex(Styrene-butadiene-rubber) and water dispersed Epoxy (EPD) were used to enhance the physical properties of the emulsified asphalt. The swelling and adhesion features of the emulsified asphalt were also studied with $CaCO_3$, Silica, and Montmorillonite (MMT). It was shown that the addition of SBR latex and MMT can be another way to improve the physical properties of the emulsified asphalt in that the lowest swelling feature was found.

• 한국도로학회논문집
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• 제20권1호
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• pp.47-58
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• 2018

PURPOSES : The purpose of this study is to evaluate the mechanical properties of a cold-recycling asphalt mixture used as a base layer and to determine the optimum emulsified-asphalt content for ensuring the mixture's performance. METHODS : The physical properties (storage stability, mixability, and workability) of three types of asphalt emulsion (CMS-1h, CSS-1h, and CSS-1hp) were evaluated using the rotational viscosity test. Asphalt emulsion residues, prepared according to the ASTM D 7497-09 standard, were evaluated for their rheological properties, including the $G*/sin{\delta}$and the dynamic shear modulus (${\mid}G*{\mid}$). In addition, the Marshall stability, indirect tensile strength, and tensile-strength ratio (TSR) were evaluated for the cold-recycling asphalt mixtures fabricated according to the type and contents of the emulsified asphalt. RESULTS : The CSS-1hp was found to be superior to the other two types in terms of storage stability, mixability, and workability, and its $G*/sin{\delta}$ value at high temperatures was higher than that of the other two types. From the dynamic shear modulus test, the CSS-1hp was also found to be superior to the other two types, with respect to low-temperature cracking and rutting resistance. The mixture test indicated that the indirect tensile strength and TSR increased with the increasing emulsified-asphalt content. However, the mixtures with one-percent emulsified-asphalt content did not meet the national specification in terms of the aggregate coverage (over 50%) and the indirect tensile strength (more than 0.4 MPa). CONCLUSIONS : The emulsified-asphalt performance varied greatly, depending on the type of base material and modifying additives; therefore, it is considered that this will have a great effect on the performance of the cold-recycling asphalt pavement. As the emulsified-asphalt content increased, the strength change was significant. Therefore, it is desirable to apply the strength properties as a factor for determining the optimum emulsified-asphalt content in the mix design. The 1% emulsified-asphalt content did not satisfy the strength and aggregate coverage criteria suggested by national standards. Therefore, the minimum emulsified-asphalt content should be specified to secure the performance.

• 한국방재학회:학술대회논문집
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• 한국방재학회 2007년도 정기총회 및 학술발표대회
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• pp.117-120
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• 2007

The main purpose of this paper is to introduce the early traffic opening-capable continuous multi-layer asphalt pavement maintenance method using electric arc furnace slag aggregate and emulsified asphalt to the actual construction sites. As well known, the previous surface treatment method of emulsified asphalt mixture have various shortcomings such as long work-time, traffic congestions, plastic deformation and poor evenness. Thus, the proposed method has enabled tile early traffic opening by utilizing the optimized emulsified asphalt after consideration of the climate and road conditions in Korea. The application of the electric furnace slag with $6\;{\sim}\;18\;mm$ thickness is helpful to become a environment-friendly construction method. And also, it has been improved enough to accommodate night-time works of mechanized construction activities for wearing course and control course.

• 한국도로학회논문집
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• 제12권1호
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• pp.79-86
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• 2010

일반적으로 유화 아스팔트와 폼드 아스팔트를 사용한 현장 상온 재생 아스팔트 포장은 노후한 아스팔트 포장을 재생하는데 가장 경제적이며 친환경적인 재활용 공법이다. 최근, 현장 상온 재생 아스팔트 혼합물의 코팅, 라벨링, 잔류안정도, 양생조건을 향상시켜주는 고점착 유화 아스팔트가 개발되었다. 본 연구의 목적은 현장 상온 재생 아스팔트 포장을 위한 고점착 유화 아스팔트 혼합물과 폼드 아스팔트 혼합물의 실내시험에 대한 반응특성을 비교하는 것이다. 고점착 유화 아스팔트 혼합물은 폼드 아스팔트 혼합물과 비교하여 재활용 골재를 균일하게 코팅시켜주는 것으로 육안 관찰되었다. 현장 상온 재생 아스팔트 포장을 위한 고점착 유화 아스팔트 혼합물과 폼드 아스팔트 혼합물의 마샬안정도와 간접인장강도는 유사한 반응을 보여주었다. 하지만 진공으로 포화된 습윤상태의 고점착 유화 아스팔트 혼합물의 마샬안정도와 간접인장강도는 폼드 아스팔트 혼합물보다 우수한 것으로 나타났다. 4시간 양생 후 고점착 유화 아스팔트 혼합물의 라벨링 현상은 폼드 아스팔트 혼합물보다 적게 발생하였다. 본 실내시험에 대한 반응특성으로부터 현장 상온 재생 아스팔트 포장을 위한 고점착 유화 아스팔트 혼합물은 폼드 아스팔트 혼합물보다 우수한 저항성과 라벨링 저항성을 발휘하는 것으로 평가되었다.

• 한국도로학회논문집
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• 제19권2호
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• pp.97-102
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• 2017

PURPOSES : Emulsified asphalt is critical for road construction. The objective of applying asphalt emulsion as an adhesive is to prevent the phenomenon of debonding between the upper and lower layers. The quantity and veriety of bituminous material can be varied according to the type of pavement and site conditions. The objective of this study is to reveal the optimum application rates of the emulsified asphalt materials by types of tack-coats using Interface Shear Strength(ISS). METHODS : In the research, emulsified asphalt was paved on the surface of the divided mixture. The specimens of paving asphalt emulsion were utilized to evaluate the bond strength of tack-coat materials. In the evaluation process, NCHRP Report 712 was utilized to investigate the Interface Shear Strength, which reflects the bond capacity of asphalt emulsion. Then, the optimum residual application rates by tack-coat types were determined using regression analysis. RESULTS :As a consequence of squared R values investigated from 0.7 to 1 as part of the regression analysis, the tendency of predicted ISS values was compared with the results. The optimum residual application rates of AP-3, RS(C)-4, QRS-4, and BD-Coat were determined to be $0.78{\ell}/m^2$, $0.51{\ell}/m^2$, $0.53{\ell}/m^2$, and $0.73{\ell}/m^2$, respectively, utilizing 4th regression analysis. CONCLUSIONS :Based on the result of this study, it was not feasible to conclude whether higher residual application of tack-coat material leads to improved bond capacity. Rather, the shearing strength varies depending on the type of pavement.

• Advances in concrete construction
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• 제10권6호
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• pp.515-526
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• 2020

Cold-mixed asphalt mixture is a widely recommended asphalt pavement materials with potentially economic and environmental benefits. Due to the reduction of natural non-renewable mineral resources, powder minerals with similar properties are considered as new mineral fillers in asphalt mixtures. This study explored the feasibility of using cement to replace natural limestone powder (LP) in emulsified asphalt concrete modified by styrene-butadiene styrene copolymer. The experimental tests, including compressive strength, Marshall stability as well as moisture susceptibility test, were used to investigate the mechanical properties, the Marshall stability, flow value, as well as the moisture damage. In addition, the influence of material composition on the performance of asphalt concrete is explained by the microstructure evolution of the pore structure, the interface transition zone (ITZ), and the micromorphology. Due to mineralogical reactivity of cement, its replacement part of LP improved the mechanical properties, Marshall stability, but it will reduce the moisture susceptibility and flow value. This is because with the increase of the cement substitution rate, the pore structure of the asphalt concrete is refined, the width of ITZ becomes smaller, and the microstructure is more compact. In addition, asphalt concrete with a larger nominal particle size (AC-16) has relatively better performance.

• Elastomers and Composites
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• 제54권4호
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• pp.335-344
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• 2019

In this work, styrene butadiene rubber (SBR) and styrene butadiene styrene (SBS) were used to modify asphalt, resulting in SBR- and SBS-modified asphalt, respectively. The two modified asphalts were emulsified with a nonionic emulsifier (Span 60) and cationic emulsifiers (ID, DDA) and their phase stabilization was investigated via particle size, Zeta potential, and flow behavior analysis. With increasing amount of the mixed emulsifier, the particle size decreased, leading to an increase in viscosity. The shear thinning behaviors and Zeta potential values ranging from 35-65 mV were determined and remained considerably stable. In addition, the adhesion strength and compression strength of the SBR-and SBS-modified asphalt emulsion were evaluated via surface free energy examination. The remarkable adhesion and compression strengths were estimated when 5 phr ID and 6 phr DDA were added to the emulsified asphalt modified with SBR and SBS. Therefore ID and DDA, the two cationic surfactants, played significant roles in improving the dispersion and interfacial adhesion strength, resulting in the improved adhesion and compression strength of the emulsified asphalts modified with SBR and SBS.

• 한국산학기술학회논문지
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• 제2권2호
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• pp.65-71
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• 2001

폐아스팔트혼합물의 배출은 좁은 도로와 늘어나는 교통량에 의해 해마다 그 양이 증가하고 있으며 건설폐기물 중에 그 오염도가 다른 폐기물에 비하여 매우 심각하다고 할 수 있다. 특히 폐아스팔트혼합물의 경우 단순히 환경오염 차원을 넘어 무단 투기되므로 국민의 식수원을 오염시켜 사회적 문제로 대두되고 있는 실정으로 국내의 실정을 감안할 때 천연자원의 보존, 막대한 처리비용 절감 및 환경보전이라는 측면에서도 막대한 양의 폐아스팔트혼합물에 대하여 가열 및 상온 아스팔트재활용과 처리에 대한 중요성을 실감할 수가 있다. 본 연구에서는 가열의 공정을 생략하고 이러한 단점들을 제거하여 폐아스팔트혼합물의 재활용 취지에 좀더 가까운 결과를 유도할 수 있는 상온 아스팔트 재활용에 관하여 상온재활용 및 처리기술의 개발 및 상온재생 방법의 실험적인 연구를 통하여 그 적용성 및 적합성을 검토하고자 한다.

• 공업화학
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• 제25권4호
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• pp.409-413
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• 2014

폐아스팔트를 적정 처리하여 KS F 2572 규격을 만족하는 아스팔트용 순환골재를 회수한 후 신골재와 결합재(수분+유화아스팔트+에멀젼계 재생첨가제)의 최적의 혼합비율을 설계하여 현장 시공규격에 맞는 재활용 상온아스콘 혼합물을 생산하고자 하였다. 결합재의 최적 혼합비율 결정을 위한 실험 결과 수분함량이 증가함에 따라 전단강도는 감소하였으며, 수분함량이 3.0 wt%일 때 마샬안정도가 최대값을 보였다. 두 결과를 토대로 최적 수분함량은 3.0 wt%로 설정하였다. 또한 유화아스팔트의 함량에 따른 마샬안정도와 흐름치는 첨가량 0.5~2.5 wt%의 범위에서 모두 기준에 만족하였고, 공극률은 0.7~2.5 wt%의 범위에서 만족하였으므로 최적 첨가량은 공통으로 만족된 범위인 0.7~2.5 wt%의 가운데 지점인 1.6 wt%로 설정하였다. 재활용 상온아스콘 혼합물용 결합재의 최적 에멀젼계 첨가제 함량은 재활용 상온아스콘 혼합물의 마샬안정도와 포화도를 고려하여 0.1 wt%로 설정하였다.