• Title/Summary/Keyword: Emission potential

Search Result 975, Processing Time 0.029 seconds

Preparation of Novel Fused Ring Spiro[benzotetraphene-fluorene] Derivatives and Application for Deep-Blue Host Materials

  • Kim, Min-Ji;Lee, Chil-Won;Gong, Myoung-Seon
    • Bulletin of the Korean Chemical Society
    • /
    • v.35 no.6
    • /
    • pp.1639-1646
    • /
    • 2014
  • A series of novel fused-ring spiro compounds, spiro[benzo[ij]tetraphene-7,9'-fluorene] (SBTF) derivatives containing an end-capping aryl substituent at both the C3 and C10-positions hasbeen designed and synthesized via multi-step Suzuki coupling reactions. 3-(1-Naphthyl)-10-phenylSBTF (1N-PSBTF), 3-(2-naphthyl)-10-phenylSBTF (2N-PSBTF) and 3-[4-(1-naphthyl)phenyl]-10-phenylSBTF (NP-PSBTF) showed improved glass transition temperatures ($T_g$) with good thermal stability. Their photophysical, electrochemical, and electroluminescent properties were investigated and were used to construct blue organic light emission diodes (OLEDs). The typical OLED devices showed excellent performance; the NP-PSBTF-based device exhibited highly efficient deep blue-light emission with a maximum efficiency of 5.27 cd/A (EQE, 4.63%) with CIE (x = 0.133, y = 0.144). According to these characteristics, these deep-blue light emitting materials have sufficient potential for fluorescent OLED applications.

Computer Simulation of Pt-GaAs Schottky Barrier Diode (Pt-GaAs Schottky Barrier Diode의 Computer Simulation)

  • Yoon, Hyun-Ro;Hong, Bong-Sik
    • Journal of the Korean Institute of Telematics and Electronics
    • /
    • v.27 no.3
    • /
    • pp.101-107
    • /
    • 1990
  • In this work, one-dimensional simulation is carried out for PT-GaAs Schottky barrier diodes with finite difference method. Shockley's semiconductor governing equations: Poisson equation and current continuity equation are discertized, and linearized by Newton-Raphson method. The linear system of equation is solved by Gaussian elimination method until convergence is achieved. The boundary condition for this equation is taken from thermionic emission-diffusion theory. Simulation is done for PT-GaAs epitaxial-layer Schottky barrier diodes. The claculated results of electron and potential distribution are shown. Simulation results show exellent agreement with experiments.

  • PDF

Synthesis and Biodistribution of Cat's Eye-shaped [57Co]CoO@SiO2 Nanoshell Aqueous Colloids for Single Photon Emission Computed Tomography (SPECT) Imaging Agent

  • Kwon, Minjae;Park, Jeong Hoon;Jang, Beom-Su;Jung, Hyun
    • Bulletin of the Korean Chemical Society
    • /
    • v.35 no.8
    • /
    • pp.2367-2370
    • /
    • 2014
  • "Cat's eye"-shaped $[^{57}Co]CoO@SiO_2$ core-shell nanostructure was prepared by the reverse microemulsion method combined with radioisotope technique to investigate a potential imaging agent for a single photon emission computed tomography (SPECT) in nuclear medicine. The core cobalt oxide nanorods were obtained by thermal decomposition of $Co-(oleate)_2$ precursor from radio isotope Co-57 containing cobalt chloride and sodium oleate. The $SiO_2$ coating on the surface of the core cobalt oxide nanorods was produced by hydrolysis and a condensation reaction of tetraethylorthosilicate (TEOS) in the water phase of the reverse microemulsion system. In vivo test, micro SPECT image was acquired with nude mice after 30 min of intravenous injection of $[^{57}Co]CoO@SiO_2$ core-shell nanostructure.

Emission Patterns of Carbon Dioxide & Methane by Liquid Pig Manure Treatments in Paddy Soil (논토양에서 돈분액비 시용에 따른 CH4 및 CO2 발생양상)

  • Oh, Seung-Ka;Yoon, Dong-Kyung;Lee, Eun-Jung;Lee, Byung-Jin;Jeon, Seung-Ho;Cho, Young-Son
    • Korean Journal of Organic Agriculture
    • /
    • v.23 no.4
    • /
    • pp.923-938
    • /
    • 2015
  • This study was conducted to serve as the basis for establishing a standard cultivation, which enhances the alternative utilization of pig manure, a major cause of environmental pollution, by finding a means for reducing greenhouse gas emissions for eco-friendly cultivation. In a laboratory, $CH_4$ and $CO_2$ emission patterns were investigated corresponding to incremental pig manure treatments in paddy soil. The emissions peaked 12 to 27 days after manure application in the 100~400% applications. It was found that increasing applications of pig manure resulted an increase in $CH_4$ and $CO_2$ emissions. Additionally, application of more than 150% emitted a larger amount of these gasses than applying chemical fertilizer. However, the test application of 100% pig manure emitted a smaller amount of $CH_4$ and hence Global Warming Potential (GWP) than those emitted by chemical fertilizer. If appropriate amount of fertilization is applied in compliance with the standard application rate, the pig manure may be effective in reducing greenhouse gas emissions and the soil environment made more favorable than with the use of chemical fertilizer.

Preparation and Luminescence Properties of Y(P,V)O4:Eu3+ Phosphor using Impregnation Method (함침법에 의한 Y(P,V)O4:Eu3+ 형광체의 합성 및 발광특성)

  • Han, Cheong-Hwa;Kim, Soo-Jong
    • Journal of the Korean Ceramic Society
    • /
    • v.48 no.6
    • /
    • pp.565-570
    • /
    • 2011
  • The $Eu^{3+}$ doped $Y(P_x,V_{1-x})O_4$ (0 ${\leq}$ x ${\leq}$ 1) phosphors were synthesized by solid-state and impregnation method and investigated as potential red-emitting phosphors for a plasma display panel(PDP). The optimal substitution proportion of P for V was determined to be 60 mol%, for $Y(P_x,V_{1-x})O_4$ doped with 8 mol% $Eu^{3+}$. The VUV PL spectra and SEM for the synthesized phosphors were measured and compared against those of a commercial red-emission phosphor. The $Y(P_x,V_{1-x})O_4$:$Eu^{3+}$ phosphors exhibited strong red at around 592, 618 and 698 nm. The emission intensity and particle size of the phosphors were controlled by preparation conditions.

Hybrid Imaging in Oncology

  • Fatima, Nosheen;uz Zaman, Maseeh;Gnanasegaran, Gopinath;Zaman, Unaiza;Shahid, Wajeeha;Zaman, Areeba;Tahseen, Rabia
    • Asian Pacific Journal of Cancer Prevention
    • /
    • v.16 no.14
    • /
    • pp.5599-5605
    • /
    • 2015
  • In oncology various imaging modalities play a crucial role in diagnosis, staging, restaging, treatment monitoring and follow up of various cancers. Stand-alone morphological imaging like computerized tomography (CT) and magnetic resonance imaging (MRI) provide a high magnitude of anatomical details about the tumor but are relatively dumb about tumor physiology. Stand-alone functional imaging like positron emission tomography (PET) and single photon emission tomography (SPECT) are rich in functional information but provide little insight into tumor morphology. Introduction of first hybrid modality PET/CT is the one of the most successful stories of current century which has revolutionized patient care in oncology due to its high diagnostic accuracy. Spurred on by this success, more hybrid imaging modalities like SPECT/CT and PET/MR were introduced. It is the time to explore the potential applications of the existing hybrid modalities, developing and implementing standardized imaging protocols and train users in nuclear medicine and radiology. In this review we discuss three existing hybrid modalities with emphasis on their technical aspects and clinical applications in oncology.

An Experimental Study on the Combustion and Emission Characteristics According to the Variation of Compression Ratio and Intake Temperature Using Stratified Charge Compression Ignition in a Gasoline Direct Injection Engine (SCCI 방법을 이용한 직분식 가솔린 엔진내의 압축비 및 흡기 온도 변화에 따른 연소 및 배기 특성에 관한 실험적 연구)

  • Lee Chang-Hee;Lee Ki-Hyung;Lim Kyoung-Bin
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.30 no.6 s.249
    • /
    • pp.538-545
    • /
    • 2006
  • Stratified charge compression ignition (SCCI) combustion, also known as HCCI(homogeneous charge compression ignition), offers the potential to improve fuel economy and reduce emission. In this study, SCCI combustion was studied in a single cylinder gasoline DI engine, with a direct injection system. We investigated the effects of air-fuel ratio, intake temperature and injection timing such as early injection and late injection on the attainable SCCI combustion region. Injection timing during the intake process was found to be an important parameter that affects the SCCI region width. We also find it. The effects of mixture stratification and fuel reformation can be utilized to reduce the required intake temperature for suitable SCCI combustion under each set of engine speed and compression ratio conditions.

Hot-filament 플라즈마화학기상증착법 이용한 패턴된 DLC층 위에 탄소나노튜브의 선택적 배열

  • Choe, Eun-Chang;Park, Yong-Seop;Hong, Byeong-Yu
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2010.08a
    • /
    • pp.293-293
    • /
    • 2010
  • Carbon nanotubes (CNTs) have attracted considerable attention as possible routes to device miniaturization due to their excellent mechanical, thermal, and electronic properties. These properties show great potential for devices such as field emission displays, CNT based transistors, and bio-sensors. The metals such as nickel, cobalt, gold, iron, platinum, and palladium are used as the catalysts for the CNT growth. In this study, diamond-like carbon (DLC) was used for CNT growth as a nonmetallic catalyst layer. DLC films were deposited by a radio frequency (RF) plasma-enhanced chemical vapor deposition (RF-PECVD) method with a mixture of methane and hydrogen gases. CNTs were synthesized by a hot filament plasma-enhanced chemical vapor deposition (HF-PECVD) method with ammonia (NH3) as a pretreatment gas and acetylene (C2H2) as a carbon source gas. The grown CNTs and the pretreated DLC filmswere observed using field emission scanning electron microscopy (FE-SEM) measurement, and the structure of the grown CNTs was analyzed by high resolution transmission scanning electron microscopy (HR-TEM). Also, using energy dispersive spectroscopy (EDS) measurement, we confirmed that only the carbon component remained on the substrate.

  • PDF

Cathode Luminescence Characteristics of $ZnGa_2O_4$ Phosphors with the doped activator (활성제 첨가에 따른 $ZnGa_2O_4$ 형광체의 발광특성)

  • Hong, Beom-Joo;Lee, Seung-Kyu;Kim, Kyung-Hwan;Park, Yong-Seo;Choi, Hyung-Wook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2005.11a
    • /
    • pp.301-302
    • /
    • 2005
  • The $ZnGa_2O_4$:Cr phosphor was synthesized through solid-state reactions at the various molar ratio of Cr from 0.002 % to 0.01 %. The XRD patterns show that the Cr-doped $ZnGa_2O_4$ has a (311) main peak and a spinel phase. Also the emission wavelength shills from 510 to 705 nm in comparison with $ZnGa_2O_4$:Mn when Cr is doped in $ZnGa_2O_4$. These results indicate that $ZnGa_2O_4$ phosphors hold promise for potential applications in field-emission display devices with high brightness operating in full color regions.

  • PDF

Research on the Combustion and Emission Characteristics of the DME/Diesel Dual-fuel Engine (DME/Diesel 듀얼 퓨얼 엔진의 연소 및 배출 특성에 관한 연구)

  • Lim, Ock-Taeck;Pyo, Young-Duck;Lee, Young-Jae
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.19 no.5
    • /
    • pp.29-34
    • /
    • 2011
  • This study investigates the potential of DME/Diesel dual fuel engine for reducing emissions with same power. Dual fuel engine controls the combustion using two different fuels, DME and diesel with different auto-ignition timings. In the previous work, the caracteristics of combustion and emissions under single cylinder engine and ignition is done by compression ignition. Pre-mixture is formed by injecting low-pressure DME into an intake manifold and high-pressure fuel (diesel or DME) is injected directly into the cylinder. Both direct diesel injection and port fuel injection reduced the significant amount of Smoke, CO and NOx in the homogeneous charge compression ignition engine due to present of oxygen in DME. In addition, when injecting DME directly in cylinder with port DME injection, there is no changes in emissions and energy consumption rate even operated by homogeneous charge compression ignition.