• Title/Summary/Keyword: Emission Spectrum

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Physical modeling of dust polarization spectrum by RAT alignment and disruption

  • Lee, Hyeseung;Hoang, Thiem
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.2
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    • pp.38.1-38.1
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    • 2021
  • Dust polarization depends on the physical and mechanical properties of dust, as well as the properties of local environments. To understand how dust polarization varies with grain mechanical properties and the local environment, in this paper, we model the wavelength-dependence polarization of starlight and polarized dust emission by aligned grains by simultaneously taking into account grain alignment and rotational disruption by radiative torques (RATs). We explore a wide range of the local radiation field and grain mechanical properties characterized by tensile strength. We find that the maximum polarization and the peak wavelength shift to shorter wavelengths as the radiation strength U increases due to the enhanced alignment of small grains. Grain rotational disruption by RATs tends to decrease the optical-near infrared polarization but increases the ultraviolet polarization of starlight due to the conversion of large grains into smaller ones. In particular, we find that the submillimeter (submm) polarization degree at 850㎛(P850) does not increase monotonically with the radiation strength or grain temperature (Td), but it depends on the tensile strength of grain materials. Our physical model of dust polarization can be tested with observations toward star-forming regions or molecular clouds irradiated by a nearby star, which have higher radiation intensity than the average interstellar radiation field. Finally, we compare our predictions of the P850-Td relationship with Planck data and find that the observed decrease of P850 with Td can be explained when grain disruption by RATs is accounted for, suggesting that interstellar grains unlikely to have a compact structure but perhaps a composite one. The variation of the submm polarization with U (or Td)can provide a valuable constraint on the internal structures of cosmic dust

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Long-term simultaneous monitoring observations of SiO and H2O masers toward Mira variable WX Serpentis

  • Lim, Jang Ho;Kim, Jaeheon;Son, Seong Min;Suh, Kyung-Won;Cho, Se-Hyung;Yang, Haneul;Yoon, Dong-Hwan
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.2
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    • pp.49.1-49.1
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    • 2021
  • We carried out simultaneous monitoring observations of five maser lines, H2O (22 GHz), SiO 𝝊 =1, 2, J =1-0 (43.1, 42.8 GHz), and SiO 𝝊 =1, J=2-1, J =3-2 (86.2, 129.3 GHz), toward the Mira variable star WX Serpentis with the 21-m antennas of the Korean VLBI Network (KVN) in 2009-2021 (~12 years). Most spectra of the H2O maser are well separated into two parts of two blue- and one redshifted features within ± 10 km s-1 of the stellar velocity. All detected SiO masers are generally concentrated within ± 5 km s-1 of the stellar velocity, and sometimes appear split into two components. Overall, the profiles of SiO and H2O masers detected in WX Serpentis illustrate typical characteristics of the Mira variable. In addition, flux variations of both SiO and H2O masers are well correlated with the optical light curve of the central star, showing a phase lag of ~ 0.1 for SiO masers and ~ 0.2 for H2O maser. This phenomenon is considered to be the direct effect of propagating shock waves generated by the stellar pulsation, because SiO and H2O masers are sequentially distributed at different positions with respect to the central star. In addition, we analyzed long-term trends and characteristics of maser velocities, maser ratio, and the velocity extents (the full width at zero power; FWZP). We also investigated a spectral energy distribution (SED) ranging from 1.2 to 240 ㎛ obtained using several infrared data: 2MASS, WISE, IRAS, ISO, COBE DIBRE, RAFGL, and AKARI (IRC and FIS). From the IRAS LRS and ISO SWS spectra of this star, we identified 9.7 and 12 ㎛ silicate emission features consistent with the SE6 spectrum model, corresponding to the typical AGB phase.

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High-resolution optical and near-infrared spectroscopic study of 2MASS J06593158-0405277

  • Park, Sunkyung;Lee, Jeong-Eun;Pyo, Tae-Soo;Sung, Hyun-Il;Lee, Sang-Gak;Kang, Wonseok;Oh, Hyung-Il;Yoon, Tae Seog;Mace, Gregory N.;Jaffe, Daniel T.;Yoon, Sung-Yong;Green, Joel D.
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.2
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    • pp.50.2-50.2
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    • 2019
  • We present the results of high-resolution (R ≥ 30,000) optical and near-infrared spectroscopic monitoring observations of a FU Orionis-type object, 2MASS J06593158-0405277. We have monitored 2MASS J06593158-0405277 with the Bohyunsan Optical Echelle Spectrograph (BOES) and the Immersion GRating INfrared Spectrograph (IGRINS) since December 2014. Various features produced by wind, disk, and outflow/jet were detected. The wind features varied over time and disappeared about a year after the outburst occurred. The double-peaked line profiles were detected in the optical and near-infrared, and the line widths decrease with increasing wavelength. The disk features in the optical spectra are fit well with G2-type or G5-type stellar spectra convolved with a disk rotational profile of about 45 km s-1, which corresponds to a disk radius of about 71 Rfor a central mass of 0.75 M. Disk features in near-infrared spectra are fit well with a K1-type stellar spectrum convolved with a disk rotational profile of about 35 km s-1, which corresponds to a disk radius of about 117 R for a central mass of 0.75 M. We also detected [S II] and H2 emission lines, which are rarely found in FUors but are usually found in the earlier stage of young stellar objects. Therefore, we suggest that 2MASS J06593158-0405277 is in the relatively earlier part of Class II stage.

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Comparing building performance of supermarkets under future climate change: UK case study

  • Agha Usama Hasan;Ali Bahadori-Jahromi;Anastasia Mylona;Marco Ferri;Hexin Zhang
    • Advances in Energy Research
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    • v.8 no.1
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    • pp.73-93
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    • 2022
  • Focus on climate change and extreme weather conditions has received considerable attention in recent years. Civil engineers are now focusing on designing buildings that are more eco-friendly in the face of climate change. This paper describes the research conducted to assess the impact of future climate change on energy usage and carbon emissions in a typical supermarket at multiple locations across the UK. Locations that were included in the study were London, Manchester, and Southampton. These three cities were compared against their building performance based on their respective climatic conditions. Based on the UK Climatic Projections (UKCP09), a series of energy modelling simulations which were provided by the Chartered Institute of Building Service Engineers (CIBSE) were conducted on future weather years for this investigation. This investigation ascertains and quantifies the annual energy consumption, carbon emissions, cooling, and heating demand of the selected supermarkets at the three locations under various climatic projections and emission scenarios, which further validates annual temperature rise as a result of climatic variation. The data showed a trend of increasing variations across the UK as one moves southwards, with London and Southampton at the higher side of the spectrum followed by Manchester which has the least variability amongst these three cities. This is the first study which investigates impact of the climate change on the UK supermarkets across different regions by using the real case scenarios.

Excimer-Based White Phosphorescent OLEDs with High Efficiency

  • Yang, Xiaohui;Wang, Zixing;Madakuni, Sijesh;Li, Jian;Jabbour, Ghassan E.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.1520-1521
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    • 2008
  • There are several ways to demonstrate white organic light emitting diodes (OLEDs) for displays and solid state lighting applications. Among these approaches are the stacked three primary or two complementary colors light-emitting layers, multiple-doped emissive layer, and excimer and exciplex emission [1-10]. We report on white phosphorescent excimer devices by using two light emitting materials based on platinum complexes. These devices showed a peak EQE of 15.7%, with an EQE of 14.5% (17 lm/W) at $500\;cd/m^2$, and a noticeable improvement in both the CIE coordinates (0.381, 0.401) and CRI (81). Devices with the structure ITO/PEDOT:PSS/TCTA (30 nm)/26 mCPy: 12% FPt (10 nm) /26 mCPy: 2% Pt-4 (15 nm)/BCP (40 nm)/CsF/Al [device 1], ITO/PEDOT:PSS/TCTA (30 nm)/26 mCPy: 2% Pt-4 (15 nm)/26 mCPy: 12% FPt (10 nm)/BCP (40 nm)/CsF/Al [device 2], and ITO/PEDOT:PSS/TCTA (30 nm)/26 mCPy: 2% Pt-4: 12% FPt (25 nm)/BCP (40 nm)/CsF/Al [device 3] were fabricated. In these cases, the emissive layer was either the double-layer of 26 mCPy:12% FPt and 15 nm 26 mCPy: 2% Pt-4, or the single layer of 26mCPy with simultaneous doping of Pt-4 and FPt. Device characterization indicates that the CIE coordinates/CRI of device 2 were (0.341, 0.394)/75, (0.295, 0.365)/70 at 5 V and 7 V, respectively. Significant change in EL spectra with the drive voltage was observed for device 2 indicating a shift in the carrier recombination zone, while relatively stable EL spectra was observed for device 1. This indicates a better charge trapping in Pt-4 doped layers [10]. On the other hand, device 3 having a single light-emitting layer (doped simultaneously) emitted a board spectrum combining emission from the Pt-4 monomer and FPt excimer. Moreover, excellent color stability independent of the drive voltage was observed in this case. The CIE coordinates/CRI at 4 V ($40\;cd/m^2$) and 7 V ($7100\;cd/m^2$) were (0.441, 0.421)/83 and (0.440, 0.427)/81, respectively. A balance in the EL spectra can be further obtained by lowering the doping ratio of FPt. In this regard, devices with FPt concentration of 8% (denoted as device 4) were fabricated and characterized. A shift in the CIE coordinates of device 4 from (0.441, 0.421) to (0.382, 0.401) was observed due to an increase in the emission intensity ratio of Pt-4 monomer to FPt excimer. It is worth noting that the CRI values remained above 80 for such device structure. Moreover, a noticeable stability in the EL spectra with respect to changing bias voltage was measured indicating a uniform region for exciton formation. A summary of device characteristics for all cases discussed above is shown in table 1. The forward light output in each case is approximately $500\;cd/m^2$. Other parameters listed are driving voltage (Bias), current density (J), external quantum efficiency (EQE), power efficiency (P.E.), luminous efficiency (cd/A), and CIE coordinates. To conclude, a highly efficient white phosphorescent excimer-based OLEDs made with two light-emitting platinum complexes and having a simple structure showed improved EL characteristics and color properties. The EQE of these devices at $500\;cd/m^2$ is 14.5% with a corresponding power efficiency of 17 lm/W, CIE coordinates of (0.382, 0.401), and CRI of 81.

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Radiolabeling of 11C-sertraline by fast and easy loop method with [11C]CH3OTf

  • Lee, Hak Jeong;Jeong, Jae Min;Lee, Sang-Yoon;Ido, Tatsuo
    • Journal of Radiopharmaceuticals and Molecular Probes
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    • v.3 no.1
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    • pp.32-37
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    • 2017
  • Cis-(1S,4S)-4-(3,4-dichlorophenyl)-1,2,3,4-tertrahydro-N-methyl-1-naphthalenamine (sertraline) hydrochloride from among selective serotonin reuptake inhibitors (SSRIs) is a treatment of major depression. For the differential diagnosis by metabolizing serotonin in a patient with neurological disorders, the radiolabeled $^{11}C$-sertraline was developed for non-invasive positron emission tomography in living brain and use the evaluation of new drug for SSRIs. We release the results of a fast and easy radiolabeling method applied a one-step loop method with $[^{11}C]CH_3OTf$ for routine clinical applications of $^{11}C$-sertraline. 1 mg of a precursor for $^{11}C$-sertraline in 0.1 mL DMF and $5{\mu}L$ of 1N NaOH, were injected into the loop of semi-prep high-performance liquid chromatography (HPLC). $[^{11}C]CH_3OTf$ was passed through the loop at room temperature (RT). The $^{11}C$-sertraline was separated by the semi-preparative HPLC. $^{11}C$-sertraline was eluted at 28.0 min was collected and evaluated by analytical HPLC and mass spectrometer. The total radiolabeling efficiency of $^{11}C$-sertraline was $30.7{\pm}8.7%$. The specific activity was $64.8{\pm}51.4GBq/{\mu}mol$. The radiochemical and chemical purities were higher than 99%. The mass spectrum of the product showed m/z peaks at 307.1 (M+1), indicating the mass of sertraline. By the one-step loop method with $[^{11}C]CH_3OTf$, $^{11}C$-sertraline could be quickly and easily prepared for clinical application.

Feasibility of Analyzing Soil Organic Carbon Fractions using Mid-Infrared Spectroscopy (중적외선분광분석법을 이용한 토양 유기 탄소 분획 분석)

  • Hong, Seung-Gil;Shin, JoungDu;Park, Kwang-Lai;Lee, Sang-Beom;Kim, Jinho;Kim, Seok-Cheol;Shiedung, Henning;Amelung, Wulf
    • Journal of the Korea Organic Resources Recycling Association
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    • v.23 no.3
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    • pp.85-92
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    • 2015
  • For concerning the climate change issues, the carbon sequestration and importance of soil organic matter are receiving high attention. To evaluate carbon sequestration in soil is important to determine the soil organic carbon (SOC) fractions such as WESOC (Water extractable soil organic carbon), and $CO_2$ emission by soil microbial respiration. However, the analyses for those contents are time-consuming procedure. There were studied the feasibility of MIRS (Mid-Infrared Spectroscopy), which has short analysis time for determining the WESOC and an incubated carbon in this study. Oven-dried soils at $100^{\circ}C$ and $350^{\circ}C$ were scanned with MIRS and compared with the chemically analyzed WESOC and cumulative carbon dioxide generated during 30, 60, 90, and 120 days of incubation periods, respectively. It was observed that an optimized determination coefficient was 0.6937 between WESOC and untreated soil processed by spectrum vector normalization (SNV) and 0.8933 between cumulative $CO_2$ from 30 days incubation and soil dried at $350^{\circ}C$ after subtracting air-dried soil processed by 1st derivatives. Therefore, it was shown that Quantification of soil organic carbon fractions was possibility to be analyzed by using MIRS.

Mn K-Edge XAS Analyses of $Zn_{2-x}Mn_xSiO_4$ Phosphors ($Zn_{2-x}Mn_xSiO_4$ 형광체의 망간 K 흡수단 엑스선 흡수 분광 분석)

  • Choi, Yong Gyu;Lim, Dong Sung;Kim, Kyong Hon;Sohn, Kee Sun;Park, Hee Dong
    • Journal of the Korean Chemical Society
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    • v.43 no.6
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    • pp.636-643
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    • 1999
  • Green-emission intensity of a $Zn_{2-x}Mn_xSiO_4$ phosphor, which is a potential candidate as a green component in PDP device, significantly increases provided that the compound is additionally heat treated at 900$^{\circ}C$ after solid state reaction at 1300$^{\circ}C$. In order to verify origin of such an intensity enhancement after the additional heat treatment in association with the electronic and local structural change at around Mn ions, the Mn K-edge X-ray absorption spectra were recorded. From the analyses of the preedge peak corresponding to $1s{\rightarrow}3d$ bound state transition and XANES spectrum, it is known that most Mn ions are in +2 oxidation state and substitute Zn ion site regardless of the thermal treatment. In addition, EXAFS analyses revealed that Mn ions formed $MnO_4$ tetrahedra with the Mn-O bond length shortened by 0.01${\AA}$ and with reduced Debye-Waller factor in the thermally treated sample.

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Thermoluminescene Properties of Li6Gd(BO3)3:Ce3+ Scintillation Single Crystal (리튬 가돌리늄 보레이트 섬광단결정의 열형광 특성)

  • Kim, Sunghwan;Lee, Joonil
    • Journal of the Korean Society of Radiology
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    • v.8 no.7
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    • pp.455-459
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    • 2014
  • We grew the $Li_6Gd(BO_3)_3:Ce^{3+}$ scintillator and determined the scintillation and thermoluminescence properties for X-rays. The emission spectrum of $Li_6Gd(BO_3)_3:Ce^{3+}$ is located in the range of 370~500 nm, peaking at 423 nm an 455 nm, due to the $4f{\rightarrow}5d$ transition of $Ce^{3+}$ ions. The fluorescence decay time of the crystal is composed three components. The fast component is 60 ns (25%), the intermediate component is 787 ns (29%) and the slow component is $5.9{\mu}s$ (46%) of the crystal. The after-glow is caused by the electron and hole traps in the crystal lattice. We determined physical parameters of the traps in the crystal. The thermoluminescence trap are composed two traps. The determined activation energy (E), kinetic order (m) and frequency factor (s) of the first trap are 0.65 eV, 1.01 and $6.9{\times}10^8s^{-1}$. And, the determined activation energy, kinetic order and frequency factor of the second trap are 0.96 eV, 1.79 and $3.1{\times}10^{12 }s^{-1}$, respectively.

Frequency stabilization of 1.5μm laser diode by using double resonance optical pumping (이중공명 광펌핑을 이용한 1.5μm 반도체 레이저 주파수 안정화)

  • Moon, Han-Sub;Lee, Won-Kyu;Lee, Rim;Kim, Joong-Bok
    • Korean Journal of Optics and Photonics
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    • v.15 no.3
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    • pp.193-199
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    • 2004
  • We present the double resonance optical pumping(DROP) spectra in the transition 5P$_{3}$2/-4D$_{3}$2/ and 5P$_{3}$2/-4D$_{5}$ 2/ of ($^{87}$ Rb) and the frequency stabilization in the $1.5mutextrm{m}$ region using those spectra. Those spectra have high signal-to-noise ratio and narrow spectral linewidth, which is about 10 MHz. We could account fur the relative intensities of the hyperfine states of those spectra by the spontaneous emission into the other state. When the frequency of the $1.5mutextrm{m}$ laser diode was stabilized to the DROP spectrum, the frequency fluctuation was about 0.2 MHz fDr sampling time of 0.1 s and the Allan deviation(or the square root of the Allan variance) was about 1${\times}$10$^{-11}$ for averaging time of l00s.