• 제목/요약/키워드: Emission Spectrum

검색결과 711건 처리시간 0.024초

ZnS:Cu의 청색 발광 특성과 염료 혼합비 의존성 (Blue Electroluminescent Properties and Dependent of Dye Mixed ratio of ZnS:Cu)

  • 이종찬;박대희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 추계학술대회 논문집
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    • pp.528-531
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    • 2000
  • ZnS:Cu phosphor used on powder electroluminescent device has a green emission in low frequency and a blue emission in high frequency. In this paper, to obtain the powder electroluminescent device of the blue emission in low frequency, the emission properties with mixed the ratio between phosphor and dye was investigated. The mixed ratio of the dye was from 0 to 5 weight percent. To inquire into the blue emission, the emission spectrum, the CIE coordinate system and the brightness were measured.

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유비퀴틴 단백질의 부분적으로 폴딩된 구조에 대한 분광학적 분석 (Spectroscopic Analysis of Partially Folded State of Ubiquitin)

  • 박순호
    • Applied Biological Chemistry
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    • 제46권4호
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    • pp.305-310
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    • 2003
  • Hydrophobic core가 변이된 유비퀴틴 단백질이 pH 2 용액에서 보이는 구조적인 특성을 여러 분광학적 방법으로 측정하였다. 낮은 pH값을 갖는 용액에서 이 변이 유비퀴틴의 intrinsic tryptophan fluorescence emission spectrum은 unfolded 상태보다 약간 blue shift되어 있고 또한 그 intensity도 상당히 낮게 나타났다. 이는 이 용액 조건에서 이 변이 유비퀴틴의 삼차구조가 약간 남아 있는 것을 의미한다. 같은 용액에서 이 변이 유비쥐틴의 far-UV circular dichroic spectrum은 native 상태나 unfolded 상태의 spectrum과 현저히 달랐으며 220 nm 에서의 molar ellipticity 값을 통하여 볼 때 pH 2인 용액에서 상당량의 이차구조를 지니고 있었다. 또한 같은 용액에서 이 변이 유비퀴틴은 hydrophobic dye인 8-anilinonaphthalene-1-sulfonic acid(ANS)외 fluorescence emission intensity를 증가시키고 fluorescence emission maximum이 짧은 파장에서 나타나게 하였다(blue shift). 이러한 현상은 pH 2 용액에서 이 변이 유비퀴틴의 hydrophobic core가 느슨하여져서 hydrophobic dye인 ANS가 결합할 수 있는 구조를 띠고 있음을 나타낸다. 이러한 분광학적인 관찰은 이 변이 유비귀틴이 pH 2인 용액에서 상당량의 이차구조를 지니고 있지만 hydrophobic core는 느슨하게 형성된 molten globule과 같은 형태를 지니고 있음을 나타낸다. 이 변이 유비퀴틴의 molten 히obule 형태는 단백질 폴딩 반응의 경로를 연구할 수 있는 좋은 모델이 될 수 있을 것으로 생각된다.

우리은하 중심의 초거대 질량 블랙홀에 대한 구형 항성풍 부착 (SPHERICAL WIND ACCRETION ONTO SUPERMASSIVE BLACK HOLE)

  • 임수연;박명구
    • 천문학논총
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    • 제10권1호
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    • pp.79-90
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    • 1995
  • The unique compact radio source, Sgr $A^*$, at the Galactic center show many observational signs that it is powered by supermassive black hole. Recent observations also imply that it is surrounded by winds from nearby IR sources. So we explore the model in which multiwavelength spectrum from Sgr $A^*$ is due to the spherical accretion of these winds onto the central supermassive black hole. Improving upon the previous work, we allowed the possibility that ions and electrons have different temperatures, included the Compton effects and pair processes. Electrons radiate via cyclosynchrotron and bresstrahlung with comptoniztion. We find that ion approaches the virial temperature ${\sim}10^{13}K$ while electron temperature saturates at ${\sim}10^{10}K$. However, decoupling between ion and electron does not greatly affect the shape of the emission spectrum. When the mass of the black hole is ${\sim}10^6M_{\odot}$, radio, IR, X-ray, $\gamma$-ray band spectrum is reasonably explained by the model. Yet Compton effect which is neglected in previous works produces significant emission in IR band, which is marginally compatible with observations. Pair production is negligible and annihilation lines cannot be observed.

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저선회 연소기에서 합성천연가스(SNG) 연료의 수소함량에 따른 연소 특성 연구 (A Study on the Combustion Characteristics with Hydrogen Contents of SNG Fuel in Low-Swirl Combustor)

  • 정황희;강기중;이기만
    • 한국수소및신에너지학회논문집
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    • 제28권2호
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    • pp.181-189
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    • 2017
  • This paper describes experimental results on combustion characteristics with hydrogen contents of synthetic natural gas (SNG) in low swirl combustor. To investigate the effect of hydrogen contents for premixed SNG flame, stability map, CH chemiluminescence images, flame spectrum analysis and emission performances were measured. In the results, as the hydrogen content was increased, the lean flammable limit was expanded and the flame length was decreased. The hydrogen contents affected the flame liftoff height, and it has different tendency according to the equivalence ratio and flame shape. The change of height and length of flame according to hydrogen contents is caused by the fast burning velocity of hydrogen, which can be confirmed by GRI 3.0 reaction mechanism in PREMIX code. The intensity of $OH^*$, $CH^*$ and $C_2^*$ was confirmed by spectrum analysis of flame. As a result, the $CH^*$ intensity was not significantly different according to hydrogen content. The increase of hydrogen contents influenced positively CO and NOx emission performances.

부분방전에 의한 음향신호의 검출과 위치추정에 관한 연구 (A Study on the Detection of Acoustic Signal Produced by Partial Discharges in Insulation Oil and its Positioning)

  • 길경석;박대원;김일권;최수연;박찬용
    • 한국전기전자재료학회논문지
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    • 제20권10호
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    • pp.907-911
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    • 2007
  • This paper dealt with the frequency spectrum analysis of acoustic signal produced by partial discharge (PD) in insulation oil and the positioning of PD occurrence to apply in diagnosis of oil insulated transformers. Three types of electrode system ; the needle-plane, the plane-plane, and the wire-wire structure were assembled to simulate partial discharges in oil insulated transformers. A low-noise amplifier and a decoupling circuit were designed to detect acoustic signal with high sensitivity The frequency spectrum of the acoustic signal were 50 kHz ${\sim}$ 260 kHz in the needle-plane, 50 kHz ${\sim}$ 250 kHz in the plane-plane, and 45 kHz${\sim}$195 kHz in the wire-wire electrode system. Their peak frequencies were 145 kHz, 130 kHz and 114 kHz, respectively The position of PD occurrence was calculated by the time difference of arrival (TOA) using three acoustic emission (AE) sensors, and we could find the position within the error of 1 % in the experimental apparatus.

선형예측부호화 스펙트럼을 이용한 유발이음향 방사파 잠시의 측정 (Measurement of Evoked Otoacoustic Emission Latency Using Linear prediction Coding Spectrum)

  • 안정일;최진영;조진호;이건일
    • 대한의용생체공학회:학술대회논문집
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    • 대한의용생체공학회 1991년도 춘계학술대회
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    • pp.47-50
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    • 1991
  • An automatized latency calculation method of evoked otoacoustic emission is proposed. Averaged e-OAE signal is measured from normal adult and it is processed by IBM-AT computer for latency calculation. After partition of stimulated and emitted signal on the time axis by converted linear prediction coding spectrum, latency is calculated by cross correlation method. The output is also compared with those of conventional autocorrelation and pure cross correlation methods. The result show that proposed method has better performance than those of conventional ones.

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Vibronic Emission Spectrum of Jet-Cooled o-Tolunitrile in a Corona Excited Supersonic Expansion

  • Park, Chan-Ho;Lee, Gi-Woo;Lee, Sang-Kuk
    • Bulletin of the Korean Chemical Society
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    • 제27권6호
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    • pp.881-885
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    • 2006
  • We have employed a technique of corona excited supersonic expansion to generate electronically excited but jet-cooled o-tolunitrile. The vibronically well-resolved emission spectrum of the jet-cooled o-tolunitrile in the $S_{1}\rightarrow S_{0}$ transition was recorded in the uv region using a Fourier transform spectrometer equipped with a Quartz-uv beam splitter. The electronic transition and vibrational mode frequencies in the ground electronic state were accurately determined from the analysis of the spectra observed.

Assignment of Vibronic Emission Spectra of Jet-Cooled m-Tolunitrile

  • Park, Chan Ho;Lee, Sang-Kuk
    • Bulletin of the Korean Chemical Society
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    • 제27권9호
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    • pp.1377-1380
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    • 2006
  • The technique of corona-excited supersonic expansion was applied to produce electronically excited but rovibrationally cooled m-tolunitrile. The well-resolved vibronic emission spectrum of the jet-cooled m-tolunitrile in the $S_1\;\rightarrow \;S_0$ transition was recorded in the uv region using a Fourier transform spectrometer equipped with a Quartz-uv beam splitter. From an analysis of the spectrum observed, it was confirmed that the electronic transition and vibrational mode frequencies in the ground electronic state were accurately determined.

Formation of Difluorobenzyl Radicals from 2,3,4-Trifluorotoluene in Corona Excitation

  • Yoon, Young-Wook;Lee, Gi-Woo;Lee, Sang-Kuk
    • Bulletin of the Korean Chemical Society
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    • 제32권6호
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    • pp.1993-1996
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    • 2011
  • The vibronically well-resolved emission spectrum was recorded from the corona discharge of precursor 2,3,4-trifluorotoluene in a corona excited supersonic expansion with a pinhole-type glass nozzle using a long-path monochromator in the visible region. From the analysis of the observed spectrum, we found the evidence of the presence of the difluorobenzyl radicals in the corona discharge of the precursor. A possible mechanism is proposed for the formation of difluorobenzyl radicals in the gas phase on the basis of the observed emission intensity of the difluorobenzyl radicals produced.

GaN분말을 이용한 $Ga_{2}O_{3}$fiber-wool의 합성과 특성 (Synthesis of $\beta$-$Ga_{2}O_{3}$Fiber-Wool from GaN Powder and its Characteristics)

  • 조성룡;여운용;이종원;박인용;김선태
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.848-850
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    • 2001
  • In this work, we investigated on the white-colored ribbon fiber synthesized from GaN powder. We convinced the formation of monoclinic phase $\beta$-Ga$_2$O$_3$from the X-ray diffraction pattern on ribbon fiber. The 10 K PL spectrum consisted with the strong emission band caused by self-activated optical center at 3.464 eV with the full-width at half maximum of 48 meV and the impurity related emission bands. Through this work, the optical properties and the electrical conductivity of $\beta$-Ga$_2$O$_3$, it will be useful for the fabrication of optoelctronic devices operating in visible spectrum region.

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