• 제목/요약/키워드: Emission Gas Analyses

검색결과 54건 처리시간 0.03초

Effects of Hydrogen Plasma Treatment of the Underlying TaSiN Film Surface on the Copper Nucleation in Copper MOCVD

  • Park, Hyun-Ah;Lim, Jong-Min;Lee, Chong-Mu
    • 한국세라믹학회지
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    • 제41권6호
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    • pp.435-438
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    • 2004
  • MOCVD is one of the major deposition techniques for Cu thin films and Ta-Si-N is one of promising barrier metal candidates for Cu with high thermal stability. Effects of hydrogen plasma pretreatment of the underlying Ta-Si-N film surface on the Cu nucleation in Cu MOCVD were investigated using scanning electron microscopy, X-ray photoelectron spectroscopy and Auger electron emission spectrometry analyses. Cu nucleation in MOCVD is enhanced as the rf-power and the plasma exposure time are increased in the hydrogen plasma pretreatment. The optimal plasma treatment process condition is the rf-power of 40 Wand the plasma exposure time of 2 min. The hydrogen gas flow rate in the hydrogen plasma pretreatment process does not affect Cu nucleation much. The mechanism through which Cu nucleation is enhanced by the hydrogen plasma pretreatment of the Ta-Si-N film surface is that the nitrogen and oxygen atoms at the Ta-Si-N film surface are effectively removed by the plasma treatment. Consequently the chemical composition was changed from Ta-Si-N(O) into Ta-Si at the Ta-Si-N film surface, which is favorable for Cu nucleation.

Thermal Stability of $MnOx-WO_3-TiO_2$ Catalysts Prepared by the Sol-gel Method for Low-temperature Selective Catalytic Reduction

  • 신병길;이희수
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2011년도 추계학술발표대회
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    • pp.28.2-28.2
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    • 2011
  • The selective catalytic reduction (SCR) of NOx by $NH_3$ is well known as one of the most convenient, efficient, and economical method to prevent NOx emission in flue gas from stationary sources. The degradation of the reactivity is the obstacle for its real application, since high concentrations of sulfur dioxide and thermal factor would deactivate the catalyst. It is necessary to develop high stability of catalysts for low-temperature SCR. Among the transition metal oxides, $WO_3$ is known to exhibit high SCR activity and good thermal stability. The $MnOx-WO_3-TiO_2$ catalysts prepared by sol-gel method with various $WO_3$ contents were investigated for low-temperature SCR. These catalysts were observed in terms of micro-structure and spectroscopy analyses. The $WO_3$ catalyst as a promoter is used to enhance the thermal stability of catalyst since it increases the phase transition temperature of $TiO_2$ support. It was found that the addition of tungsten oxides not only maintained the temperature window of NO conversion but also increased the acid sites of catalyst.

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도시지역 에너지 공급체계 개선방안 검토 연구 (A Study on the Planning of Urban Energy Supply Systems Including Co-generation System)

  • 우남섭;이태원;김용기
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2009년도 하계학술발표대회 논문집
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    • pp.177-182
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    • 2009
  • The purpose of this study is to investigate planning of urban energy supply systems configuration and operating conditions for the district heating and cooling system using combined heat and power system. Generally the district heating and cooling system has been known to one of the effective way for energy saving, cost reduction and demand side management of energy. Economical analyses were carried out and operating characteristics for some systems were examined in terms of GER factor which represents to the ratio of gas and electricity costs. Rates of the energy consumption and the $CO_2$ emission were compared from the system configuration of the energy supply system with new district cooling system with the conventional one.

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다공 세라믹 연소기 속에서의 예혼합연소에 대한 민감도 해석의 적용 (Application of sensitivity analyses in premixed combustion within a porous ceramic burner)

  • 임인권
    • 대한기계학회논문집B
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    • 제22권2호
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    • pp.162-172
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    • 1998
  • A numerical study of premixed combustion within a porous ceramic burner (PCB) is performed to understand flame behavior with respect to various model parameters. Basic flame structure within the porous ceramic burner and species profiles such as NO and CO are examined. Sensitivity analysis of flame speed, gas and solid temperature, NO and CO emission from the burner with respect to reaction steps and various physical properties of the ceramic material is applied to find the most significant parameters in selection of porous materials for the porous ceramic burner. Effects of thermal conductivity, extinction coefficient and scattering albedo on the burner characteristics are studied through the sensitivity analysis. The results of sensitivity study reveal the order of importance in ceramic material properties to get suitable burner performance. Scattering albedo, which governs the ratio of absorbed energy by the ceramic material to total radiative energy transferred, is one of the most important parameters in the material properties since it affects the actual absorbed radiation rate and thus it largely affects the flame structure. Through the study, it is found that the sensitivity study can be used to estimate the flame behavior within the porous ceramic burner more effectively.

The Potential of Building Information Modeling in Application Process of G-SEED

  • Chen, De Jian;Yoon, Heakyung
    • Architectural research
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    • 제20권4호
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    • pp.121-128
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    • 2018
  • Given the barriers to implement green building rating systems, Building Information Modeling (BIM) was suggested as an effective solution integrating information into one model and saving substantial time to facilitate certification process. Synergies between BIM and Leadership in Energy and Environment Design (LEED), the most widely used rating system, have been researched for a few decades. This paper demonstrates literature review about the development of integration between BIM and LEED. The research focuses on synergies between BIM and Green Standard for Energy & Environmental Design (G-SEED) in Korea, as one of important strategies to mitigate greenhouse gas emission. The research compares LEED and G-SEED related items based on evaluation contents. The result manifests G-SEED and LEED share many common items in different degrees. Therefore, it is entirely possible for G-SEED and BIM to adapt same developing mode of LEED and BIM. Moreover, the study measures the potential of BIM in application process of G-SEED certification by investigation of credits in LEED and G-SEED can be earned by BIM. The results of paper indicate the documentation support LEED and G-SEED may be prepared directly, semi-directly and indirectly via sustainability analyses software in BIM.

심야전력제도의 문제점과 개선 방향 : 경제성·환경성·형평성 및 에너지 안보 (A Study on the Night Thermal-storage Power Service : Sustainability and Energy Security)

  • 조영탁;김창섭
    • 자원ㆍ환경경제연구
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    • 제17권2호
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    • pp.419-455
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    • 2008
  • 이 논문은 심야전력제도의 경제성 환경성 형평성을 평가하고, 이를 토대로 심야전력제도가 전력 및 가스수급계획 등 국가 에너지정책에 미치는 작용을 분석하였다. 분석 결과에 따르면, 심야전기난방은 등유난방에 비해 연간 약 6~8억 달러의 연료낭비, 약 2배의 온실가스 배출, 1.4조 원의 소비자 부담증가를 유발하고 있다. 뿐만 아니라 심야전력제도는 동절기 LNG 수급교란을 유발함과 동시에 장기전원계획, 가스수급계획, 온실가스감축 등 국가에너지정책에도 부정적인 효과를 야기한다. 요컨대 심야전력제도는 우리나라 에너지정책의 두 가지 기본축인 지속가능한 에너지체제와 에너지안보에 정면으로 위배되며, 문제해결을 위해서는 등유세제와 심야건기요금의 통합조정에 기초한 신규수요의 억제조치와 기존 수용가의 등유전환 프로그램을 병행하는 것이 바람직하다.

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목재 펠릿 연료전환 사업의 온실가스 감축 효과 및 경제성 분석 (Analyses of GHG Reduction Effectiveness and Economic Feasibility in the Wood Pellet Fuel Switching Project)

  • 이진철;강규영
    • Journal of the Korean Wood Science and Technology
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    • 제41권6호
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    • pp.594-605
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    • 2013
  • 목질계 바이오매스는 폐기물 다음으로 가장 경제적이고 온실가스 감축 잠재력이 높은 것으로 알려진 신재생에너지원으로서 이를 이용해 개발된 바이오에너지 중에서 수송과 이용이 편리하고 발열량이 높은 목재 펠릿은 아직 가격이 다소 높지만 유럽과 일본에서는 이미 높은 보급률의 신재생에너지로 활용되고 있다. 기존 화석연료의 목재 펠릿 등 목질 바이오매스로의 연료전환을 통하여 온실가스 감축사업으로 활용하는 경우는 일본의 JCDM에서 활성화되어 있으나, 우리나라는 아직 그 기준 및 방법론 등이 정립되어 있지 않아 현재 LNG로 전환되는 사업이 활성화 되어있고 목질바이오매스 전환 사업은 등록되지 못하고 있는 실정이다. 본 연구를 통해 JCDM에 등록된 목질 바이오매스 연료전환 사업을 분석하고, 2012년 KVER에 등록된 중소기업의 LNG 연료전환 사업을 기본 데이터로 하여 시나리오로 가정한 목재 펠릿으로의 연료전환 사업과 JCDM 사업, KVER의 LNG 연료전환 사업과의 비교 분석을 통하여 펠릿 연료 전환시 투자비 대비 연간 온실가스 감축효과, 연료 단가 차익으로 인한 수익과 온실가스 감축 이득 등의 수익을 비교 분석함과 동시에 온실가스 감축효과와 경제성을 분석하였다.

Mechanism of improving quality of dry-aged pork loins in scoria-containing onggi, Korean earthenware as a storage container

  • Sung-Su Kim;Dong-Jin Shin;Dong-Gyun Yim;Hye-Jin Kim;Doo Yeon Jung;Hyun-Jun Kim;Cheorun Jo
    • Animal Bioscience
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    • 제36권5호
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    • pp.797-809
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    • 2023
  • Objective: Many scientists have investigated solutions to reduce microbiological risks in dry-aged meat after the dry-aging technology was revived for high quality and value-added premium meat product in the market. This study aimed to investigate the effect of scoria powder in onggi (Korean earthenware) on the meat quality of pork loins during 21 days of dry aging and to elucidate its mechanism of action. Methods: The pork loins were randomly divided into three groups: aged in vacuum-packaging, onggi containing red clay only (OR), and onggi containing 30% red clay and 70% scoria powder (OS). Microbial analyses (total plate count and Lactobacillus spp.) and physicochemical analyses (pH, shear force, volatile basic nitrogen [VBN], water activity, 2-thiobarbituric acid reactive substances, water content, water holding capacity, cooking loss, and color analysis) of aged meat were conducted. Far-infrared ray emission, quantification of immobilized L. sakei and microstructure of onggi were investigated to understand the mechanism. Results: On day 21, the meat aged in OS exhibited lower pH, shear force, VBN, and water activity than those aged in OR, along with an increase in the number of Lactobacillus spp. OS had a smaller pore diameter than OR, implying lower gas permeability, which could promote the growth of L. sakei. Conclusion: OS improved the microbiological safety and storage stability of pork loin during dry aging by increasing number of Lactobacillus spp. possibly due to low permeability of OS.

코크스제조공정에서 탄화시간과 시료채취방법에 따른 다핵방향족탄화수소 발생에 관한 연구 (A Study on Polynuclear Aromatic Hydrocarbons Emitted by Coking Time and Sampling Method in a Coke Oven Plant)

  • 윤충식;백남원
    • 한국산업보건학회지
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    • 제3권1호
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    • pp.37-53
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    • 1993
  • The polynuclear hydrocarbons (PAHs) emitted from coke oven standpipe were sampled using three sampling systems, including glass fiber filter+silver membrane filter, glass fiber filter+silver membrane filter+XAD-2 adsorbent tube, PTFE membrane filter+XAD-2 adsorbent tube, extracted by methylene chloride and analysed by gas chromathography using flame ionization detector. The results of this study were as follows. 1. Because the amounts of coke oven emissions(COE) were large, the analyses of PAHs were simple and possible without evaporation and concentration. Although the generation of COE was high during early stage of coking, the airborne concentration of PAHs was low and increased during late coking. 2. The contents of PAHs in COE were 1.35-2.81%. 3. The index components of PAHs were fluoranthene and pyrene. Their correlation coefficient to total PAHs were 0.96, 0.95, respectively. 4. The particulate PAHs were sampled by filter and gaseous PAHs by adsorbent tube. The collection efficiency of glass fiber filter+silver membrane filter was 20% of total amount sampled by filters+adsorbent and PTFE membrane filter 50%. Adsorbent tube must be attached to the filter to collect light and small PAH components. 5. The generation of acenaphthene and indeno (1,2,3-cd) pyrene were low and concentrations of fluorene and anthracene were $20-40ug/m^3$ throughout coking time. Other PAH eoncentrations were sometimes high. The generation of PAHs was low at 4-6 hours of coking time. The gaseous PAHs were generated earlier than particulate PAHs.

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호밀 조사료 가공방법이 한우의 반추위 내 발효특성과 온실가스 발생량에 미치는 영향 (Effects of the Processing Methods of Forage Rye (Secale cereale) on Rumen Fermentation Characteristics and Greenhouse Gas Emissions In Vitro of Hanwoo)

  • 김지윤;정승민;주영호;백창현;최부길;애린다;김삼철
    • 한국초지조사료학회지
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    • 제44권2호
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    • pp.99-105
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    • 2024
  • 본 연구에서는 국내에서 이용되는 호밀의 조사료 가공방법에 따른 영양소 함량, 반추위 내 소화율, 발효특성 및 온실가스 발생량을 평가하기 위해 수행되었다. 출수기에 수확한 호밀은 청초, 건초 및 사일리지로 제조하여 시험에 이용하였다. 조단백질, 조회분 및 ADF 함량은 사일리지에서 가장 높았고, 청초에서 가장 낮았다. NFC 함량과 RFV는 청초에서 가장 높았고, 사일리지에서는 가장 낮았다. 한편 호밀 조사료를 72시간 동안 한우의 반추위 내에서 in vitro 발효하였을 때, IVDMD는 청초가 건초와 사일리지에 비해 높았으나, IVNDFD 소화율은 시험구간 차이가 없었다. 반추위 내 propionate 함량이 사일리지에서 가장 높았으며, 이로 인해 A:P ratio는 가장 낮았다. IVDMD 기준 total gas와 CH4 발생량은 사일리지가 가장 낮았으며, CO2 발생량은 생초가 낮았다. 한편 IVNDFD 기준 total gas, CO2 및 CH4 발생량은 사일리지가 가장 낮았다. 이상의 결과에서, 호밀은 사일리지로 제조하는 것이 온실가스 저감에서 유리할 것으로 사료된다.