• Title/Summary/Keyword: Emission Color

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Fluorescent White OLEDs with a High Color-rendering Index Using a Silicon-Cored Anthracene Derivative as a Blue Host

  • Kwak, Jeong-Hun;Lyu, Yi-Yeol;Lee, Hyun-Koo;Char, Kook-Heon;Lee, Chang-Hee
    • Journal of Information Display
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    • v.11 no.3
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    • pp.123-127
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    • 2010
  • Fluorescent white organic light-emitting diodes showing high color-rendering indices (CRIs) of up to 81 was demonstrated, with a silicon-cored anthracene derivative (PATSPA) doped with DPAVBi utilized as the deep-blue host and dye materials, and the commercial dyes rubrene and DCM2 utilized as the orange- and red-light-emitting dyes. The devices, consisting of three emissive layers, showed bright-white-light emission, but the ratio of the blue peak to the orange and red peaks changed with the current density and the thickness of the blue emissive layer. A high CRI was achieved with the use of a deep-blue emitter doped in a novel host and by optimizing the blue-layer thickness. The device with a blue-layer thickness of 10 nm showed the Commission Internationale de l'Eclairage (CIE) color coordinate of (0.33, 0.35), a high CRI of 81, and a moderate external quantum efficiency of 2% at a current density of $2.5\;mA/cm^2$.

What Makes Red Quasars Red?

  • Kim, Dohyeong;Im, Myungshin
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.66.2-66.2
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    • 2016
  • Red quasars have been suspected to be an intermediate population between merger-driven star-forming galaxies and normal quasars. In this scenario, red quasars are expected to have dusty red color coming from the dust extinction by dust and gas in their host galaxy. However, several studies have proposed different explanation of the red color of red quasars, which are i) a moderate viewing angle between type 1 and 2 quasars, ii) an unusual covering factor of dust torus, and iii) an anomalous synchrotron emission with a peak at NIR wavelength. In this study, we investigate the factor leading to the red color of red quasars by using the line luminosity ratios of the hydrogen Balmer to Paschen series of 11 red quasars. We find the Pb/Hb luminosity ratios of the red quasars are significantly higher than those of normal quasars. Moreover, we compare the Pb/Hb luminosity ratios of the red quasars to the theoretically expected line luminosity ratios computed from the CLOUDY code. We find the line luminosity ratios of the red quasars cannot be explained by the theoretical line luminosity ratios with any physical conditions. We conclude that red color of red quasars comes from dust extinction by their host galaxy. This result is consistent with the picture that red quasars are an intermediate population between the merger-driven star-forming galaxies and normal quasars.

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Synthesis and Luminescence of Sr2Si5N8:Eu2+ Red Phosphor for High Color-Rendering White LED (고연색 LED용 적색 Sr2Si5N8:Eu2+ 형광체의 합성 및 발광특성 연구)

  • Lee, Sung Hoon;Kim, Jong Su;Kang, Tae Wook;Ryu, Jong Ho;Lee, Sang Nam
    • Journal of the Semiconductor & Display Technology
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    • v.16 no.4
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    • pp.11-15
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    • 2017
  • Red phosphors, $Sr_2Si_5N_8:Eu^{2+}$, were synthesized as a single-phase crystal structure by optimizing carbon and $Eu^{2+}$ contents in a carbothermal reduction nitridation method. With increasing $Eu^{2+}$ contents, the photoluminescence spectra were red-shifted from 600 nm peak for 1 mol% for to 700 nm for 7 mol%. It was suggested that this red shift is attributed to the energy transfer from one low-energy sited $Eu^{2+}$ (1) to other high-energy sited $Eu^{2+}$ (2). Finally, the best red sample (620 nm emission peak and 80 nm half width for 3 mole% of $Eu^{2+}$) was packaged on a Blue LED together with two additional green and yellow phosphors, the fabricated White LED showed a high color-rendering index of 90 and white color coordinates of x= 0.321 and y = 0.305.

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Preparation and Properties of Organic Electroluminescent Devices (유기 전계발광소자의 제작과 특성 연구)

  • 노준서;장호정
    • Journal of the Microelectronics and Packaging Society
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    • v.9 no.1
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    • pp.9-13
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    • 2002
  • Recently, Organic electroluminescent devices (OELDs) have been demonstrated the medium sized full color display with effective multi-layer thin films. In this study, the multi-layer OELDs were prepared on the patterened ITO (indium tin oxide)/glass substrates by the vacuum thermal evaporation method. The low molecule compounds such as $Alq_3$(trim-(8-hydroxyquinoline)aluminum) and CTM (carrier transfer material) as the electron transport and injection layers as well as TPD (triphenyl-diamine) and CuPc (copper phthalocyanine) as the hole transport and injection layers were used. The luminance was rapidly increased above the threshold voltage of 10 V. The luminance and emission spectrum for the OELDs samples with $A1/CTM/Alq_3$/TPD/1TO structures were found to be 430 cd/$m^2$and 512 nm at 17 V showing green color emission. In contrast, the samples with $Li-A1/Alq_3$/TPD/CuPC/1TO multi-structures showed 508 nm in emission spectrum and 650 cd/$m^2$at 17 V in the luminance. The increment of luminance may be ascribed to the improved efficiency of recombination in the region of the emission layers by the deposition of CuPc as hole injection layer and the low work function of the Li-Al electrode compared to the Al electrode.

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Development of Acoustic Emission Training Technique and Localization Method using Q-switched Laser and Multiple Sensors/Single Channel Acquisition (Q-switched 레이저와 다중센서/단일채널 신호수집을 이용한 복합재 구조 음향방출 트레이닝 및 위치탐지 기법 개발)

  • Choi, Yunshil;Lee, Jung-Ryul
    • Composites Research
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    • v.31 no.4
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    • pp.145-150
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    • 2018
  • Various structural health monitoring (SHM) systems have been suggested for aerospace industry in order to increase its life-cycle and economic efficiency. In the case of aircraft structure madden with metal, a major concern was hot spots, such as notches, bolts holes, and where corrosion or stress concentration occurs due to moisture or salinity. However, with the increasing use of composites in the aerospace industry, further advanced SHM systems have been being required to be applied to composite structures, which have much complex damage mechanism. In this paper, a method of acoustic emission localization for composite structures using Q-switched laser and multiple Amplifier-integrated PZTs have been proposed. The presented technique aims at localization of the AE with an error in distance of less than 10 mm. Acoustic emission simulation and the localization attempt were conducted in the composite structure to validate the suggested method. Localization results, which are coordinates of detected regions, grid plots and color intensity map have been presented together to show reliability of the method.

Optimization of VUV Characteristics of M3MgSi2O8:Eu2+ (M=Ca, Sr, Ba) Phosphor by Spray Pyrolysis (분무열분해법을 이용하여 M3MgSi2O8:Eu2+ (M=Ca, Sr, Ba) 형광체 분말의 VUV 특성 최적화)

  • Jung, You-Ri;Jung, Kyeong-Youl
    • Journal of Powder Materials
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    • v.15 no.5
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    • pp.399-404
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    • 2008
  • Spray pyrolysis was applied to prepare $M_{3}MgSi_{2}O_{8}:Eu^{2+}$ (M=Ca, Sr, Ba) blue phosphor powder. The library of a Ca-Sr-Ba ternary system was obtained by a combinatorial method combined with the spray pyrolysis in order to optimize the luminescent property under vacuum ultraviolet (VUV) excitation. 10 potential compositions were chosen from the first screening. The emission shifted to longer wavelength as Ca became a dominant element and the emission intensity was greatly reduced in the composition region at which Ba is dominant element. On the base of the first screening result, the second fine tuning was carried out in order to optimize the luminescence intensity under VUV excitation. The optimal composition for the highest luminescence intensity was $(Ca_{1.7},\;Sr_{0.3},\;Ba_{1.0})Si_{2}O_{8}:Eu^{2+}$ which had the color coordinate of (0.152, 0.072) and about 64% emission intensity of $BaMgAl_{10}O_{17}$ (BAM) phosphor.

Fabrication of GaN Ring Structure with Broad-band Emission Using MOCVD and Wet Etching Techniques

  • Sim, Young-Chul;Lim, Seung-Hyuk;Cho, Yong-Hoon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.243.1-243.1
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    • 2016
  • Recently, many groups have attempted to fabricate 3-dimensional (3D) structures of GaN such as pyramids, rods, stripes and annulars. Since quantum structures on non-polar and semi-polar planes of 3D structures have less influence of internal electric filed, multi quantum wells (MQWs) formed on those planes have high quantum efficiency. Especially, pyramidal and annular structures consist of various crystal planes with different emission wavelength, providing a possibillity of phosphor-free white light emtting diodes (WLEDs).[1] However, it still has problem to obtain high color rendering index (CRI) number because of narrow-band emission and poor indium composition caused by the formation of few number of facets during metal-organic chemical vapor deposition growth.[2] If we can fabricate 3D structure having more various facets, we can make broad-band emittied WLEDs and improve CRI number. In this study, we suggest a simple method to fabricate 3D structures having various facet and containing high indium composition by means of a combination of metal-organic chemical vapor deposition and wet chemical etching techniques.

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A study on the powder synthesis of the amorphous calcium carbonate precursor for phosphors by wet chemical method (습식법에 의한 형광체 제조용 비정질 탄산칼슘 전구체 분말의 합성에 관한 연구)

  • 최종건;김판채;이충효
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.4
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    • pp.302-308
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    • 2000
  • Stable amorphous calcium carbonate were synthesized from the serial work for the synthetic conditions such as concentration of solution, reaction temperature, aging time and pH of mother liquor. By using this as a precusor, calcite, aragonite and vaterite crystal particles were obtained in the water from adequate crystallization conditions. Furthermore, characterization for flourescence were performed by using crystals which were crystallized from the Sn dopped amorphous calcium carbonate. Calcite showed the most intensive emission and the center of emission wavelength was 464 nm with pure blue color. Calcite is expected to be used as phosphor for flourescent lamp because the maximum emission intensity was obtained from the excitation with 255 nm wavelength.

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Organic Electroluminescence using Hyperbranched Poly(Phenylene Vinylene) (하이퍼브랜치 PPV를 이용한 유기 EL 소자의 제작)

  • In, In-Sik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.2
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    • pp.163-168
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    • 2009
  • Hyperbranched conjugated polymers (p-HPPV and m-HPPV) with para and meta linkages were synthesized from $A_2$ and $B_4$ type monomers through Wittig polycondensation. The synthesized p-HPPV and m-HPPV were completely soluble in common organic solvents such as chloroform, tetrahydrofuran, 1,2-dichloroethane, etc. and thermal gravimetric analyses showed that p-HPPV and m-HPPV are stable up to $350^{\circ}C$. The molecular weights (from GPC), UV-visible, and photoluminescence maximum peaks of p-HPPV and m-HPPV are characterized in detail. The fabricated EL devices using the synthesized hyperbranched polymers, (ITO/(p-HPPV or m-HPPV)/Al), showed EL emission at about 507 nm and 481 nm (681 nm), respectively. Especially, EL device from m-HPPV were found to exhibit nearly white emission with approximate CIE coordinates of (0.31, 0.34) compared with (0.310, 0.316) of NTSC white color at $100\;cd/m^2$. The good photophysical properties combine with good film-form ability could make these hyperbranched polymers to be a potential candidate for the EL materials.

Luminance Characteristics of Organic Electroluminescent Devices Based on Znq12 by Heating (열처리된 Znq2에 기초한 유기 EL소자의 발광특성)

  • Jo, Seong-Ryeol;Jeong, Eun-Sil;Park, Su-Gil;Jeong, Pyeong-Jin
    • Korean Journal of Materials Research
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    • v.9 no.6
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    • pp.564-568
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    • 1999
  • The 8-hydroxyquinoline Zinc(Znq2) were prepared successfully from zinc chloride and zinc acetate as two kinds of starting material. The organic electroluminescent devices(ELDs) were fabricated by the structure of ITO/TPD/Znq2/Al with N-N'-diphenyl-N-N'-bis(3-methylphenyl)-1,1'-biphenyl-4,4'-diamine(TPD) which acts hole trasporting layer and bis(8-oxyquinolino) zinc(II)(Znq2) which acts as emission and electron transporting layer. EL efficiency of Znq2 prepared by heating was investigated. The 570nm of main emission peak which is yellowich green was investigated by photo luminesence(PL) and this results shows that electro luminescence(EL) is from Znq2. The V-J curve shows that carrier injection were investigated from 4V. Maximum luminance and luminance efficiency were 1600cd/$\m^2$, 0.9lm/W. From this results, the Znq2 can be one of the useful organic EL material.

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